Effect of Bi substitution on the magnetic and magnetocaloric properties of Ni50Mn35In15-xBix Heusler alloys

Aryal, Anil; Quetz, Abdiel; Pandey, Sudip; Dubenko, Igor; Stadler, Shane; Ali, Naushad

doi:10.1063/1.5004694

Effect of Bi substitution on the magnetic and magnetocaloric properties of Ni₅₀Mn₃₅In_15-xBi_x Heusler alloys

Journal Article · Mon Dec 18 23:00:00 EST 2017 · AIP Advances

DOI:https://doi.org/10.1063/1.5004694· OSTI ID:1499381

Aryal, Anil ^[1]; ^[2]; ^[2]; Dubenko, Igor ^[2]; Stadler, Shane ^[3]; Ali, Naushad ^[2]

Southern Illinois Univ., Carbondale, IL (United States); Department of Physics, Southern Illinois University, Carbondale, IL 62901, USA
Southern Illinois Univ., Carbondale, IL (United States)
Louisiana State Univ., Baton Rouge, LA (United States)

The structural, magnetic, magnetocaloric, and transport properties of Ni₅₀Mn₃₅In_15-xBi_x (x = 0, 0.25, 0.5, 1, 1.5) compounds has been studied through X-ray diffraction (XRD), differential scanning calorimetry, and magnetization measurements. A mixture of high temperature austenite phase (AP) and low temperature martensitic phase (MP) was observed from the XRD at room temperature. The saturation magnetization M_S at 10 K was found to decrease with increasing Bi content. A shift in the martensitic transition temperature (T_M) relative to the parent compound was observed with a maximum shift of ~ 36 K for x = 1.5. Abnormal shifts in T_C and T_M to higher temperatures were observed at high field for x ≥ 0.5. Large magnetic entropy changes (ΔS_M) of about 40 J/kg K (x = 0) and 34 J/kg K (x = 0.25) were observed at T_M with H = 5 T, which reduced significantly for higher Bi concentrations. The doping of small amounts of Bi in the In sites increased the peak width of the ΔS_M curves at the second order transition, leading to larger values of relative cooling power. A significant magnetoresistance (-30%) was observed near T_M with ΔH = 5T for x = 0.5.

Research Organization:: Southern Illinois Univ., Carbondale, IL (United States); Louisiana State Univ., Baton Rouge, LA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: FG02-06ER46291; SC0010521; SC0010521

OSTI ID:: 1499381

Alternate ID(s):: OSTI ID: 1414031
OSTI ID: 1872887

Journal Information:: AIP Advances, Journal Name: AIP Advances Journal Issue: 5 Vol. 8; ISSN 2158-3226

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited By (1)

Magnetic field dependence of the martensitic transition and magnetocaloric effects in Ni ₄₉ BiMn ₃₅ In ₁₅ Aryal, Anil; Dubenko, Igor; Talapatra, Saikat AIP Advances, Vol. 10, Issue 1 https://doi.org/10.1063/1.5130405	journal	January 2020

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