Effect of Bi substitution on the magnetic and magnetocaloric properties of Ni50Mn35In15-xBix Heusler alloys

Aryal, Anil; Quetz, Abdiel; Pandey, Sudip; Dubenko, Igor; Stadler, Shane; Ali, Naushad

doi:10.1063/1.5004694

Title: Effect of Bi substitution on the magnetic and magnetocaloric properties of Ni₅₀Mn₃₅In_15-xBi_x Heusler alloys

Journal Article · Tue Dec 19 00:00:00 EST 2017 · AIP Advances

DOI:https://doi.org/10.1063/1.5004694· OSTI ID:1499381

Aryal, Anil ^[1];

^[1];

^[1]; Dubenko, Igor ^[1]; Stadler, Shane ^[2]; Ali, Naushad ^[1]

Southern Illinois Univ., Carbondale, IL (United States)
Louisiana State Univ., Baton Rouge, LA (United States)

The structural, magnetic, magnetocaloric, and transport properties of Ni₅₀Mn₃₅In_15-xBi_x (x = 0, 0.25, 0.5, 1, 1.5) compounds has been studied through X-ray diffraction (XRD), differential scanning calorimetry, and magnetization measurements. A mixture of high temperature austenite phase (AP) and low temperature martensitic phase (MP) was observed from the XRD at room temperature. The saturation magnetization M_S at 10 K was found to decrease with increasing Bi content. A shift in the martensitic transition temperature (T_M) relative to the parent compound was observed with a maximum shift of ~ 36 K for x = 1.5. Abnormal shifts in T_C and T_M to higher temperatures were observed at high field for x ≥ 0.5. Large magnetic entropy changes (ΔS_M) of about 40 J/kg K (x = 0) and 34 J/kg K (x = 0.25) were observed at T_M with H = 5 T, which reduced significantly for higher Bi concentrations. The doping of small amounts of Bi in the In sites increased the peak width of the ΔS_M curves at the second order transition, leading to larger values of relative cooling power. A significant magnetoresistance (-30%) was observed near T_M with ΔH = 5T for x = 0.5.

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Research Organization:: Southern Illinois Univ., Carbondale, IL (United States); Louisiana State Univ., Baton Rouge, LA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-06ER46291; SC0010521; FG02-13ER46946

OSTI ID:: 1499381

Alternate ID(s):: OSTI ID: 1414031; OSTI ID: 1872887

Journal Information:: AIP Advances, Vol. 8, Issue 5; ISSN 2158-3226

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited By (1)

Magnetic field dependence of the martensitic transition and magnetocaloric effects in Ni ₄₉ BiMn ₃₅ In ₁₅ Aryal, Anil; Dubenko, Igor; Talapatra, Saikat AIP Advances, Vol. 10, Issue 1 https://doi.org/10.1063/1.5130405	journal	January 2020

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Title: Effect of Bi substitution on the magnetic and magnetocaloric properties of Ni50Mn35In15-xBix Heusler alloys

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