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Compositional Effects of Additively Manufactured Refractory High-Entropy Alloys under High-Energy Helium Irradiation

Journal Article · · Nanomaterials
DOI:https://doi.org/10.3390/nano12122014· OSTI ID:1872238

High-Entropy Alloys (HEAs) are proposed as materials for a variety of extreme environments, including both fission and fusion radiation applications. To withstand these harsh environments, materials processing must be tailored to their given application, now achieved through additive manufacturing processes. However, radiation application opportunities remain limited due to an incomplete understanding of the effects of irradiation on HEA performance. In this letter, we investigate the response of additively manufactured refractory high-entropy alloys (RHEAs) to helium (He) ion bombardment. Through analytical microscopy studies, we show the interplay between the alloy composition and the He bubble size and density to demonstrate how increasing the compositional complexity can limit the He bubble effects, but care must be taken in selecting the appropriate constituent elements.

Sponsoring Organization:
USDOE
Grant/Contract Number:
NA0003525; 89233218CNA000001
OSTI ID:
1872238
Alternate ID(s):
OSTI ID: 1877124
Journal Information:
Nanomaterials, Journal Name: Nanomaterials Journal Issue: 12 Vol. 12; ISSN NANOKO; ISSN 2079-4991
Publisher:
MDPI AGCopyright Statement
Country of Publication:
Switzerland
Language:
English

References (44)

Die Konstitution der Mischkristalle und die Raumf�llung der Atome journal January 1921
Materials challenges in nuclear energy journal February 2013
Radiation-induced segregation on defect clusters in single-phase concentrated solid-solution alloys journal April 2017
A comparative study on the in situ helium irradiation behavior of tungsten: Coarse grain vs. nanocrystalline grain journal April 2018
Nanochannel structures in W enhance radiation tolerance journal July 2018
Helium irradiation-induced ultrahigh hardening in niobium journal March 2022
Characterization of the Fe-Co-1.5V soft ferromagnetic alloy processed by Laser Engineered Net Shaping (LENS) journal May 2018
High-throughput additive manufacturing and characterization of refractory high entropy alloys journal June 2020
Investigation of arcing on fiber-formed nanostructured tungsten by pulsed plasma during steady state plasma irradiation journal November 2016
Helium irradiation behavior of tungsten-niobium alloys under different ion energies journal July 2018
Defect structures and hardening mechanisms in high dose helium ion implanted Cu and Cu/Nb multilayer thin films journal May 2012
Comparative study of the microstructures and mechanical properties of laser metal deposited and vacuum arc melted refractory NbMoTa medium-entropy alloy journal April 2020
Mechanical properties of Nb25Mo25Ta25W25 and V20Nb20Mo20Ta20W20 refractory high entropy alloys journal May 2011
High He-ion irradiation resistance of CrMnFeCoNi high-entropy alloy revealed by comparison study with Ni and 304SS journal March 2019
Formation of helium induced nanostructure ‘fuzz’ on various tungsten grades journal September 2010
The response of polycrystalline tungsten to 30keV helium ion implantation at normal incidence and high temperatures journal June 2012
Microstructure of a 14Cr-ODS ferritic steel before and after helium ion implantation journal December 2014
The role of grain size in He bubble formation: Implications for swelling resistance journal February 2017
The effect of low energy helium ion irradiation on tungsten-tantalum (W-Ta) alloys under fusion relevant conditions journal August 2017
Effect of vanadium alloying on irradiation performance of tungsten under 60 keV helium irradiation journal December 2018
Influence of nanochannel structure on helium-vacancy cluster evolution and helium retention journal December 2019
Helium bubble formation in refractory single-phase concentrated solid solution alloys under MeV He ion irradiation journal July 2021
Effects of Fe concentration on helium bubble formation in NiFex single-phase concentrated solid solution alloys journal March 2019
SRIM – The stopping and range of ions in matter (2010)
  • Ziegler, James F.; Ziegler, M. D.; Biersack, J. P.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 268, Issue 11-12 https://doi.org/10.1016/j.nimb.2010.02.091
journal June 2010
Deuterium and helium ion irradiation of nanograined tungsten and tungsten–titanium alloys journal December 2019
Fracture properties of a refractory high-entropy alloy: In situ micro-cantilever and atom probe tomography studies journal February 2017
Effects of grain boundaries and nano-precipitates on helium bubble behaviors in lanthanum-doped nanocrystalline steel journal July 2021
Investigating Effects of Alloy Chemical Complexity on Helium Bubble Formation by Accurate Segregation Measurements Using Atom Probe Tomography journal August 2019
Atomic-Scale Hidden Point-Defect Complexes Induce Ultrahigh-Irradiation Hardening in Tungsten journal July 2021
High-entropy alloys journal June 2019
Powder Metallurgy Processing of a WxTaTiVCr High-Entropy Alloy and Its Derivative Alloys for Fusion Material Applications journal May 2017
Evidence of Inverse Hall-Petch Behavior and Low Friction and Wear in High Entropy Alloys journal June 2020
Recrystallization and grain growth induced by ELMs-like transient heat loads in deformed tungsten samples journal November 2014
Radiation Effects in Refractory Alloys
  • Zinkle, Steven J.
  • SPACE TECHNOLOGY AND APPLICATIONS INTERNAT.FORUM-STAIF 2004: Conf.on Thermophys.in Microgravity; Commercial/Civil Next Gen.Space Transp.; 21st Symp.Space Nuclear Power & Propulsion; Human Space Explor.; Space Colonization; New Frontiers & Future Concepts, AIP Conference Proceedings https://doi.org/10.1063/1.1649637
conference January 2004
The Energy Multiplier Module (EM 2 ): Status of Conceptual Design journal September 2017
Microstructure and mechanical properties of a novel refractory AlNbTiZr high-entropy alloy journal March 2018
Grain size threshold for enhanced irradiation resistance in nanocrystalline and ultrafine tungsten journal February 2017
Plasma-material interactions in current tokamaks and their implications for next step fusion reactors journal December 2001
Helium induced nanoscopic morphology on tungsten under fusion relevant plasma conditions journal January 2008
First-principles theory of the energetics of He defects in bcc transition metals journal October 2008
Solute stabilization of nanocrystalline tungsten against abnormal grain growth journal September 2017
Radiation-Induced Helium Bubbles in Metals journal March 2019
Helium Bubbles and Blistering in a Nanolayered Metal/Hydride Composite journal September 2021
The Role of Vanadium in Reduction of Helium Diffusion in Tungsten Based Alloys journal August 2014

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