Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Etched-And-Regrown GaN P–N Diodes with Low-Defect Interfaces Prepared by In Situ TBCl Etching

Journal Article · · ACS Applied Materials and Interfaces

The ability to form pristine interfaces after etching and regrowth of GaN is a prerequisite for epitaxial selective area doping, which in turn is needed for the formation of lateral PN junctions and advanced device architectures. In this work, we report the electrical properties of etched-and-regrown GaN PN diodes using an in situ Cl-based precursor, tertiary butylchloride (TBCl). We demonstrated a regrowth diode with I–V characteristics approaching that from a continuously grown reference diode. The sources of unintentional contamination from the silicon (Si) impurity and the mediating effect of Si during the TBCl etching are also investigated in this study. Furthermore, this work points to the potential of in situ TBCl etching toward the realization of GaN lateral PN junctions.

Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
Grant/Contract Number:
NA0003525
OSTI ID:
1871969
Report Number(s):
SAND2022-5084J; 705361
Journal Information:
ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 44 Vol. 13; ISSN 1944-8244
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

References (35)

Interfacial Impurities and Their Electronic Signatures in High‐Voltage Regrown Nonpolar m‐ Plane GaN Vertical p–n Diodes journal December 2019
Crystallographic orientation dependence of dopant and impurity incorporation in GaN films grown by metalorganic chemical vapor deposition journal July 2009
Si impurity concentration in nominally undoped Al0.7Ga0.3N grown in a planetary MOVPE reactor journal February 2018
A study of damage-free in-situ etching of GaN in metalorganic chemical vapor deposition (MOCVD) by tertiarybutylchloride (TBCl) journal March 2020
Selective area regrowth and doping for vertical gallium nitride power devices: Materials challenges and recent progress journal October 2021
Influence of MOVPE growth conditions on carbon and silicon concentrations in GaN journal July 2002
The doping of GaN with Mg diffusion journal March 1999
Selective Area Regrowth Produces Nonuniform Mg Doping Profiles in Nonplanar GaN p–n Junctions journal February 2021
Nitride-based semiconductors for blue and green light-emitting devices journal March 1997
Inductively coupled plasma etching of GaN journal August 1996
Optically and thermally detected deep levels in n -type Schottky and p+-n GaN diodes journal May 2000
Experimental analysis and theoretical model for anomalously high ideality factors (n≫2.0) in AlGaN/GaN p-n junction diodes journal August 2003
AlGaN/GaN current aperture vertical electron transistors with regrown channels journal February 2004
Influence of deep traps on the measurement of free‐carrier distributions in semiconductors by junction capacitance techniques journal April 1974
High-temperature molecular beam epitaxial growth of AlGaN/GaN on GaN templates with reduced interface impurity levels journal February 2010
Step bunching process induced by the flow of steps at the sublimated crystal surface journal June 2012
Investigation of GaN-on-GaN vertical p - n diode with regrown p -GaN by metalorganic chemical vapor deposition journal December 2018
Investigation of dry-etch-induced defects in >600 V regrown, vertical, GaN, p-n diodes using deep-level optical spectroscopy journal October 2019
In situ and selective area etching of GaN by tertiarybutylchloride (TBCl) journal October 2019
Lateral and vertical growth of Mg-doped GaN on trench-patterned GaN films journal September 2020
High electron mobility recovery in AlGaN/GaN 2DEG channels regrown on etched surfaces journal April 2016
Yellow luminescence and related deep states in undoped GaN journal February 1997
Understanding Si adsorption on GaN(0001) surfaces using first-principles calculations journal May 2006
GaN-Based RF Power Devices and Amplifiers journal February 2008
Demonstration of 1.27 kV Etch-Then-Regrow GaN ${p}$ -${n}$ Junctions With Low Leakage for GaN Power Electronics journal November 2019
The influence of debye length on the C-V measurement of doping profiles journal October 1971
High-power 4H-SiC JBS rectifiers journal November 2002
Superjunction Power Devices, History, Development, and Future Prospects journal March 2017
GaN Vertical-Channel Junction Field-Effect Transistors With Regrown p-GaN by MOCVD journal October 2020
Inductively coupled plasma-induced etch damage of GaN p-n junctions journal July 2000
InGaN-Based Multi-Quantum-Well-Structure Laser Diodes journal January 1996
Symmetric Multicycle Rapid Thermal Annealing: Enhanced Activation of Implanted Dopants in GaN journal January 2015
Nitrogen vacancies as a common element of the green luminescence and nonradiative recombination centers in Mg-implanted GaN layers formed on a GaN substrate journal May 2017
Suppression of plasma-induced damage on GaN etched by a Cl 2 plasma at high temperatures journal June 2015
Investigation of effects of ion energies on both plasma-induced damage and surface morphologies and optimization of high-temperature Cl 2 plasma etching of GaN journal January 2017

Similar Records

Determination of electronic band structure by electron holography of etched-and-regrown interfaces in GaN p-i-n diodes
Journal Article · Sun Nov 10 23:00:00 EST 2019 · Applied Physics Letters · OSTI ID:1573873

In situ and selective area etching of GaN by tertiarybutylchloride (TBCl)
Journal Article · Mon Oct 14 00:00:00 EDT 2019 · Applied Physics Letters · OSTI ID:1799106