Efficient carbon-supported heterogeneous molybdenum-dioxo catalyst for chemoselective reductive carbonyl coupling

Liu, Shengsi; Li, Jiaqi; Jurca, Titel; Stair, Peter C.; Lohr, Tracy L.; Marks, Tobin J.

doi:10.1039/c7cy00336f

Efficient carbon-supported heterogeneous molybdenum-dioxo catalyst for chemoselective reductive carbonyl coupling

Journal Article · Mon May 08 00:00:00 EDT 2017 · Catalysis Science and Technology

DOI:https://doi.org/10.1039/c7cy00336f· OSTI ID:1871002

Liu, Shengsi ^[1]; Li, Jiaqi ^[2]; Jurca, Titel ^[2]; Stair, Peter C. ^[3]; ^[2]; ^[2]

Northwestern Univ., Evanston, IL (United States); Northwestern University
Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Reductive coupling of various carbonyl compounds to the corresponding symmetric ethers with dimethylphenylsilane is reported using a carbon-supported dioxo-molybdenum catalyst. The catalyst is air- and moisture-stable and can be easily separated from the reaction mixture for recycling. In addition, the catalyst is chemoselective, thus enabling the synthesis of functionalized ethers without requiring sacrificial ligands or protecting groups.

Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation

DOE Contract Number:: FG02-03ER15457

OSTI ID:: 1871002

Journal Information:: Catalysis Science and Technology, Journal Name: Catalysis Science and Technology Journal Issue: 11 Vol. 7; ISSN 2044-4753

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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