Synthesis and Characterization of a Well-Defined Carbon Nanohorn-Supported Molybdenum Dioxo Catalyst by SMART-EM Imaging. Surface Structure at the Atomic Level

Kratish, Yosi; Nakamuro, Takayuki; Liu, Yiqi; Li, Jiaqi; Tomotsuka, Issei; Harano, Koji; Nakamura, Eiichi; Marks, Tobin J.

doi:10.1246/bcsj.20200299

Synthesis and Characterization of a Well-Defined Carbon Nanohorn-Supported Molybdenum Dioxo Catalyst by SMART-EM Imaging. Surface Structure at the Atomic Level

Journal Article · Thu Oct 22 00:00:00 EDT 2020 · Bulletin of the Chemical Society of Japan

DOI:https://doi.org/10.1246/bcsj.20200299· OSTI ID:2480921

Kratish, Yosi ^[1]; Nakamuro, Takayuki ^[2]; Liu, Yiqi ^[1]; Li, Jiaqi ^[1]; Tomotsuka, Issei ^[2]; Harano, Koji ^[2]; Nakamura, Eiichi ^[2]; Marks, Tobin J. ^[1]

Northwestern University, Evanston, IL (United States)
University of Tokyo (Japan)

The molybdenum dioxo catalyst CNH/MoO₂ is prepared via direct grafting of (dme)MoO₂Cl₂ (dme = 1,2-dimethoxyethane) onto the graphitic surfaces of carbon nanohorn (CNH) substrates. The structure of this heterogeneous catalyst was characterized by SMART-EM, XPS, and ICP, and is found to have single isolated MoO₂ species on the surface as well as a few multi-Mo species. Furthermore, the CNH/MoO₂ complex exhibits excellent catalytic activity for polyethylene terephthalate (PET) hydrogenolysis, N-oxide reductions, and reductive carbonyl coupling, representing an informative model catalyst for structural and mechanistic investigations.

View Accepted Manuscript (DOE)

Research Organization:: Northwestern University, Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); NASA Ames Research Center

Grant/Contract Number:: FG02-03ER15457

OSTI ID:: 2480921

Alternate ID(s):: OSTI ID: 1849450

Journal Information:: Bulletin of the Chemical Society of Japan, Journal Name: Bulletin of the Chemical Society of Japan Journal Issue: 2 Vol. 94; ISSN 0009-2673

Publisher:: Chemical Society of JapanCopyright Statement

Country of Publication:: United States

Language:: English

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