Layered Double Perovskites

Evans, Hayden A.; Mao, Lingling; Seshadri, Ram; Cheetham, Anthony K.

doi:10.1146/annurev-matsci-092320-102133

Layered Double Perovskites

Journal Article · Wed May 05 00:00:00 EDT 2021 · Annual Review of Materials Research

DOI:https://doi.org/10.1146/annurev-matsci-092320-102133· OSTI ID:1870297

Evans, Hayden A. ^[1]; Mao, Lingling ^[2]; Seshadri, Ram ^[2]; Cheetham, Anthony K. ^[3]

National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); UC Santa Barbara
Univ. of California, Santa Barbara, CA (United States)
Univ. of California, Santa Barbara, CA (United States); National Univ. of Singapore (Singapore)

Successful strategies for the design of crystalline materials with useful function are frequently based on the systematic tuning of chemical composition within a given structural family. Perovskites with the formula ABX₃, perhaps the best-known example of such a family, have a vast range of elements on A, B, and X sites, which are associated with a similarly vast range of functionality. Layered double perovskites (LDPs), a subset of this family, are obtained by suitable slicing and restacking of the perovskite structure, with the additional design feature of ordered cations and/or anions. In addition to inorganic LDPs, we also discuss hybrid (organic-inorganic) LDPs here, where the A-site cation is a protonated organic amine. Several examples of inorganic LDPs are presented with a discussion of their ferroic, magnetic, and optical properties. The emerging area of hybrid LDPs is particularly rich and is leading to exciting discoveries of new compounds with unique structures and fascinating optoelectronic properties. Here, we provide context for what is important to consider when designing new materials and conclude with a discussion of future opportunities in the broad LDP area.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012541

OSTI ID:: 1870297

Alternate ID(s):: OSTI ID: 1851667

Journal Information:: Annual Review of Materials Research, Journal Name: Annual Review of Materials Research Journal Issue: 1 Vol. 51; ISSN 1531-7331

Publisher:: Annual ReviewsCopyright Statement

Country of Publication:: United States

Language:: English

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