Ce post-treatment for increased corrosion resistance of AA2024-T3 anodized in tartaric-sulfuric acid

Prada Ramirez, Oscar Mauricio; Tunes, Matheus Araujo; Mennucci, Marina Martins; Starykevich, Maksim; Neves, Cristina; Ferreira, Mário G.S.; Pogatscher, Stefan; De Melo, Hercílio Gomes

doi:10.1016/j.corsci.2022.110371

Ce post-treatment for increased corrosion resistance of AA2024-T3 anodized in tartaric-sulfuric acid

Journal Article · Fri May 13 00:00:00 EDT 2022 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2022.110371· OSTI ID:1869622

Prada Ramirez, Oscar Mauricio ^[1]; ^[2]; Mennucci, Marina Martins ^[3]; Starykevich, Maksim ^[3]; Neves, Cristina ^[3]; Ferreira, Mário G.S. ^[3]; Pogatscher, Stefan ^[4]; De Melo, Hercílio Gomes ^[1]

Univ. of Sao Paulo (Brazil)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Aveiro (Portugal)
Univ. of Leoben (Austria)

Here, the effect of a post-treatment for short time in 50 mM Ce(NO₃)₃ solution, with or without H₂O₂, on the corrosion of AA2024-T3 anodized in tartaric-sulfuric acid was investigated. Electrochemical (EIS, polarization curves) and corrosion (immersion) tests showed improved performance for samples post-treated at 50 °C in the H₂O₂ containing solution. Microstructural characterization (SEM, STEM, GDOES) evidenced the presence of Ce oxyhydroxides both at the surface and within the pores of the anodized layer, and their preferential interaction with defective sites both at micro and nanoscale. Important amounts of Ce-species were found near corrosion products, indicating active corrosion protection by Ce ions.

View Accepted Manuscript (DOE)

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program; Fundaçao de Amparo a Pesquisa do Estado de Sao Paulo; National Council for Scientific and Technological Development (CNPq); Coordenaçao de Aperfeiçoamento de Pessoal de Nível Superior (CAPES); Portuguese Foundation for Science and Technology/MCTES

Grant/Contract Number:: 89233218CNA000001

OSTI ID:: 1869622

Report Number(s):: LA-UR-22-20081

Journal Information:: Corrosion Science, Journal Name: Corrosion Science Vol. 204; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Ce post-treatment for increased corrosion resistance of AA2024-T3 anodized in tartaric-sulfuric acid

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