Ferroic phase transitions and magnetoelectric coupling in cobalt doped BaTiO3

Pradhan, Dhiren K.; Mohanty, Hari Sankar; Kumari, Shalini; Bhoi, Krishnamayee; Tang, Nan; Ravikant, none; Rahaman, M. M.; Pradhan, Dillip K.; Kumar, Ashok; Gilbert, Dustin A.; Rack, Philip D.

doi:10.1039/d1tc02961d

Ferroic phase transitions and magnetoelectric coupling in cobalt doped BaTiO₃

Journal Article · Thu Aug 05 00:00:00 EDT 2021 · Journal of Materials Chemistry C

DOI:https://doi.org/10.1039/d1tc02961d· OSTI ID:1867220

^[1]; ^[2]; ^[3]; Bhoi, Krishnamayee ^[2]; Tang, Nan ^[4]; Ravikant ^[5]; ^[6]; ^[2]; Kumar, Ashok ^[5]; Gilbert, Dustin A. ^[4]; ^[7]

Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS); Louisiana State University and A&M College
National Institute of Technology, Rourkela (India)
Pennsylvania State Univ., University Park, PA (United States)
Univ. of Tennessee, Knoxville, TN (United States)
National Physical Laboratory (CSIR), New Delhi (India)
Univ. of Rajshahi (Bangladesh)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Magnetoelectric (ME) materials exhibit interesting physics with cross coupling between ferroelectric and magnetic order parameters and thus strong potential to be utilized in memory, spintronics and other multifunctional electronic/magnetic devices. Doping of suitable transition metals in ferroelectrics can induce magnetism and ME coupling and modify the physical properties. Here, we report the structural, electronic, magnetic and ME coupling of 3.5, 5 and 7.5 mol% cobalt doped BaTiO₃ (BTO) ceramics. X-ray diffraction and Raman spectroscopy indicate that the samples are single phase having a tetragonal crystal structure with P4mm symmetry. The tetragonality ratio is found to decrease with increasing cobalt content. We observed a Fano-like asymmetric peak in the [A₁(LO₁)] Raman mode at ~173 cm^-1 in all the cobalt doped BTO samples. The cobalt dopants are shown to be uniformly distributed throughout the surface of the samples. We observed a lowering of the ferroelectric transition temperature and increasing diffusivity parameter with increasing cobalt concentration. The electrical properties of all the samples have been investigated in detail by impedance spectroscopy and ac conductivity studies before and after the ferroelectric phase transitions. All the samples show hysteretic ferroelectric behavior with a clear saturation state that decreases with increasing cobalt content. The observed ferroelectricity in these samples is intrinsic in nature. The 3.5% cobalt doped BTO sample exhibits paramagnetic behavior whereas the 5 and 7.5% cobalt doped BTO samples show ferromagnetic ordering below 43 K. The 7.5% cobalt doped BTO samples show significant ME coupling.

View Accepted Manuscript (DOE)

Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States); Univ. of Tennessee, Knoxville, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: SC0002136; SC0021344

OSTI ID:: 1867220

Alternate ID(s):: OSTI ID: 1814663
OSTI ID: 3013143

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 37 Vol. 9; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (82)

An Introduction to Surface Analysis by XPS and AES Watts, John F.; Wolstenholme, John Wiley https://doi.org/10.1002/0470867930	book	March 2003
Recent Progress in Multiferroic Magnetoelectric Composites: from Bulk to Thin Films Ma, Jing; Hu, Jiamian; Li, Zheng Advanced Materials, Vol. 23, Issue 9 https://doi.org/10.1002/adma.201003636	journal	February 2011
The Nature of Magnetoelectric Coupling in Pb(Zr,Ti)O ₃ -Pb(Fe,Ta)O ₃ Evans, Donald M.; Alexe, Marin; Schilling, Alina Advanced Materials, Vol. 27, Issue 39 https://doi.org/10.1002/adma.201501749	journal	September 2015
Temperature dependence of the A1 and E optical phonons in BaTiO3 Scalabrin, A.; Chaves, A. S.; Shim, D. S. Physica Status Solidi (b), Vol. 79, Issue 2 https://doi.org/10.1002/pssb.2220790240	journal	February 1977
Raman scattering by polaritons in tetragonal BaTiO3 Pinczuk, A.; Burstein, E.; Ushioda, S. Solid State Communications, Vol. 7, Issue 1 https://doi.org/10.1016/0038-1098(69)90711-X	journal	January 1969
Raman scattering in the ferroelectric system Pb1−xBaxTiO3 Burns, Gerald; Scott, Bruce A. Solid State Communications, Vol. 9, Issue 11 https://doi.org/10.1016/0038-1098(71)90570-9	journal	June 1971
Underdamped soft phonon in orthorhombic BaTiO3 Laabidi, K.; Fontana, M. D.; Jannot, B. Solid State Communications, Vol. 76, Issue 6 https://doi.org/10.1016/0038-1098(90)90623-J	journal	November 1990
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
Ferroelectric phase transition of Li-doped KTa1-Nb O3 single crystals with weak random fields: Inelastic light scattering study Rahaman, Md. Mijanur; Imai, Tadayuki; Sakamoto, Tadashi Journal of Alloys and Compounds, Vol. 735 https://doi.org/10.1016/j.jallcom.2017.11.039	journal	February 2018
Influence of doping concentration on room-temperature ferromagnetism for Fe-doped BaTiO3 ceramics Lin, Fangting; Jiang, Dongmei; Ma, Xueming Journal of Magnetism and Magnetic Materials, Vol. 320, Issue 5 https://doi.org/10.1016/j.jmmm.2007.08.008	journal	March 2008
Cobalt oxide surface chemistry: The interaction of CoO(100), Co3O4(110) and Co3O4(111) with oxygen and water Petitto, Sarah C.; Marsh, Erin M.; Carson, Gregory A. Journal of Molecular Catalysis A: Chemical, Vol. 281, Issue 1-2 https://doi.org/10.1016/j.molcata.2007.08.023	journal	February 2008
Synthesis and structural analysis of Co-doped BaTiO3 Padilla-Campos, L.; Diaz-Droguett, D. E.; Lavín, R. Journal of Molecular Structure, Vol. 1099 https://doi.org/10.1016/j.molstruc.2015.07.012	journal	November 2015
Influence of domain on grain size effects of the dielectric properties of BaTiO3 nanoceramics and nanoparticles Fang, Chao; Chen, LiangYan; Zhou, DongXiang Physica B: Condensed Matter, Vol. 409 https://doi.org/10.1016/j.physb.2012.10.016	journal	January 2013
Indirect but Efficient: Laser-Excited Electrons Can Drive Ultrafast Polarization Switching in Ferroelectric Materials Lian, Chao; Ali, Zulfikhar A.; Kwon, Hyuna The Journal of Physical Chemistry Letters, Vol. 10, Issue 12 https://doi.org/10.1021/acs.jpclett.9b01046	journal	June 2019
Why Are There so Few Magnetic Ferroelectrics? Hill, Nicola A. The Journal of Physical Chemistry B, Vol. 104, Issue 29 https://doi.org/10.1021/jp000114x	journal	July 2000
The evolution of multiferroics Fiebig, Manfred; Lottermoser, Thomas; Meier, Dennis Nature Reviews Materials, Vol. 1, Issue 8 https://doi.org/10.1038/natrevmats.2016.46	journal	July 2016
Multiferroic and magnetoelectric materials Eerenstein, W.; Mathur, N. D.; Scott, J. F. Nature, Vol. 442, Issue 7104 https://doi.org/10.1038/nature05023	journal	August 2006
Advances in magnetoelectric multiferroics Spaldin, N. A.; Ramesh, R. Nature Materials, Vol. 18, Issue 3 https://doi.org/10.1038/s41563-018-0275-2	journal	February 2019
Scalable energy-efficient magnetoelectric spin–orbit logic Manipatruni, Sasikanth; Nikonov, Dmitri E.; Lin, Chia-Ching Nature, Vol. 565, Issue 7737 https://doi.org/10.1038/s41586-018-0770-2	journal	December 2018
Re-epithelialization and immune cell behaviour in an ex vivo human skin model Rakita, Ana; Nikolić, Nenad; Mildner, Michael Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-019-56847-4	journal	January 2020
Fano resonance of Li-doped KTa1−xNbxO3 single crystals studied by Raman scattering Rahaman, M. M.; Imai, T.; Sakamoto, T. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep23898	journal	April 2016
Electrical properties of Fe-doped BaTiO ₃ Masó, N.; Beltrán, H.; Cordoncillo, E. J. Mater. Chem., Vol. 16, Issue 17 https://doi.org/10.1039/B515834F	journal	January 2006
Exploring phase transitions and magnetoelectric coupling of epitaxial asymmetric multilayer heterostructures Pradhan, Dhiren K.; Kumari, Shalini; Puli, Venkata S. Journal of Materials Chemistry C, Vol. 8, Issue 35 https://doi.org/10.1039/D0TC02924F	journal	January 2020
Induced magnetism and magnetoelectric coupling in ferroelectric BaTiO3 by Cr-doping synthesized by a facile chemical route Shah, Jyoti; Kotnala, Ravinder K. Journal of Materials Chemistry A, Vol. 1, Issue 30 https://doi.org/10.1039/c3ta11845b	journal	January 2013
Characteristics of the surface layer of barium strontium titanate thin films deposited by laser ablation Craciun, V.; Singh, R. K. Applied Physics Letters, Vol. 76, Issue 14 https://doi.org/10.1063/1.126216	journal	April 2000
Frequency-temperature response of ferroelectromagnetic Pb(Fe1∕2Nb1∕2)O3 ceramics obtained by different precursors. III. Dielectric relaxation near the transition temperature Raymond, O.; Font, R.; Portelles, J. Journal of Applied Physics, Vol. 99, Issue 12 https://doi.org/10.1063/1.2201853	journal	June 2006
Coupling between octahedral tilting and ferroelectric order in tetragonal tungsten bronze-structured dielectrics Levin, Igor; Stennett, Martin C.; Miles, Gabrielle C. Applied Physics Letters, Vol. 89, Issue 12 https://doi.org/10.1063/1.2355434	journal	September 2006
Surface core-level shifts of strontium observed in photoemission of barium strontium titanate thin films Baniecki, J. D.; Ishii, M.; Shioga, T. Applied Physics Letters, Vol. 89, Issue 16 https://doi.org/10.1063/1.2357880	journal	October 2006
Observation of Fano asymmetry in Raman spectra of SrTiO3 and CaxSr1−xTiO3 perovskite nanocubes Banerjee, Sarbajit; Kim, Dae-In; Robinson, Richard D. Applied Physics Letters, Vol. 89, Issue 22 https://doi.org/10.1063/1.2400095	journal	November 2006
Room-temperature ferromagnetism in Fe-doped PbTiO3 nanocrystals Ren, Zhaohui; Xu, Gang; Wei, Xiao Applied Physics Letters, Vol. 91, Issue 6 https://doi.org/10.1063/1.2766839	journal	August 2007
Multiferroic magnetoelectric composites: Historical perspective, status, and future directions Nan, Ce-Wen; Bichurin, M. I.; Dong, Shuxiang Journal of Applied Physics, Vol. 103, Issue 3 https://doi.org/10.1063/1.2836410	journal	February 2008
Magnetic behavior and thickness dependence in Co-doped BaTiO3 thin films Lin, Yuan-Hua; Zhang, Songyin; Deng, Chaoyong Applied Physics Letters, Vol. 92, Issue 11 https://doi.org/10.1063/1.2898525	journal	March 2008
Room-temperature ferromagnetism in the Co-doped Ba0.5Sr0.5TiO3 thin films Luo, L. B.; Zhao, Y. G.; Tian, H. F. Applied Physics Letters, Vol. 92, Issue 23 https://doi.org/10.1063/1.2945282	journal	June 2008
Effect of Mn substitution on electrical and magnetic properties of Bi0.9La0.1FeO3 Pradhan, Dillip K.; Choudhary, R. N. P.; Rinaldi, C. Journal of Applied Physics, Vol. 106, Issue 2 https://doi.org/10.1063/1.3158121	journal	July 2009
Grain‐size effects on dielectric properties in barium titanate ceramics Kinoshita, Kyoichi; Yamaji, Akihiko Journal of Applied Physics, Vol. 47, Issue 1 https://doi.org/10.1063/1.322330	journal	January 1976
Enhanced nonvolatile resistive switching in dilutely cobalt doped TiO2 Bogle, Kashinath A.; Bachhav, Mukesh N.; Deo, Meenal S. Applied Physics Letters, Vol. 95, Issue 20 https://doi.org/10.1063/1.3263713	journal	November 2009
Effect of Fe-doping concentration on microstructure, electrical, and magnetic properties of Pb(Zr0.5Ti0.5)O3 thin films prepared by chemical solution deposition Bai, W.; Meng, X. J.; Lin, T. Journal of Applied Physics, Vol. 106, Issue 12 https://doi.org/10.1063/1.3273384	journal	December 2009
Role of oxygen vacancies on relaxation and conduction behavior of KNbO3 ceramic Singh, Gurvinderjit; Tiwari, V. S.; Gupta, P. K. Journal of Applied Physics, Vol. 107, Issue 6 https://doi.org/10.1063/1.3309745	journal	March 2010
Intrinsic magnetism in BaTiO ₃ with magnetic transition element dopants (Co, Cr, Fe) synthesized by sol-precipitation method Liu, Hongxue; Cao, Baobao; O’Connor, Charles Journal of Applied Physics, Vol. 109, Issue 7 https://doi.org/10.1063/1.3556768	journal	April 2011
Decisive role of oxygen vacancy in ferroelectric versus ferromagnetic Mn-doped BaTiO ₃ thin films Shuai, Yao; Zhou, Shengqiang; Bürger, Danilo Journal of Applied Physics, Vol. 109, Issue 8 https://doi.org/10.1063/1.3576125	journal	April 2011
Use of Raman spectroscopy to determine the site occupancy of dopants in BaTiO ₃ Pokorný, J.; Pasha, U. M.; Ben, L. Journal of Applied Physics, Vol. 109, Issue 11 https://doi.org/10.1063/1.3592192	journal	June 2011
Structural, optical and magnetic properties of polycrystalline BaTi _1−x Fe _x O ₃ ceramics Dang, N. V.; Thanh, T. D.; Hong, L. V. Journal of Applied Physics, Vol. 110, Issue 4 https://doi.org/10.1063/1.3625235	journal	August 2011
Enhanced dielectric and piezoelectric properties of x BaZrO ₃ -(1− x )BaTiO ₃ ceramics Dong, Liang; Stone, Donald S.; Lakes, Roderic S. Journal of Applied Physics, Vol. 111, Issue 8 https://doi.org/10.1063/1.4705467	journal	April 2012
Influences of annealing temperature on structural characterization and magnetic properties of Mn-doped BaTiO ₃ ceramics Phan, The-Long; Zhang, P.; Grinting, D. Journal of Applied Physics, Vol. 112, Issue 1 https://doi.org/10.1063/1.4733691	journal	July 2012
Oxygen-vacancy-related dielectric relaxations in SrTiO ₃ at high temperatures Wang, C. C.; Lei, C. M.; Wang, G. J. Journal of Applied Physics, Vol. 113, Issue 9 https://doi.org/10.1063/1.4794349	journal	March 2013
Room temperature multiferroic properties of Pb(Fe _0.5 Nb _0.5 )O ₃ –Co _0.65 Zn _0.35 Fe ₂ O ₄ composites Pradhan, Dhiren K.; Puli, Venkata S.; Narayan Tripathy, Satya Journal of Applied Physics, Vol. 114, Issue 23 https://doi.org/10.1063/1.4847595	journal	December 2013
Studies on magnetoelectric coupling in PFN-NZFO composite at room temperature Pradhan, Dhiren K.; Sahoo, Satyaprakash; Barik, Sujit K. Journal of Applied Physics, Vol. 115, Issue 19 https://doi.org/10.1063/1.4875661	journal	May 2014
Relaxor-like dynamics of ferroelectric K(Ta ₁₋ _x Nb _x )O ₃ crystals probed by inelastic light scattering Rahaman, M. M.; Imai, T.; Miyazu, J. Journal of Applied Physics, Vol. 116, Issue 7 https://doi.org/10.1063/1.4893363	journal	August 2014
Local geometric and electronic structures and origin of magnetism in Co-doped BaTiO ₃ multiferroics Phan, The-Long; Thang, P. D.; Ho, T. A. Journal of Applied Physics, Vol. 117, Issue 17 https://doi.org/10.1063/1.4907182	journal	May 2015
Magnetism switching and band-gap narrowing in Ni-doped PbTiO ₃ thin films Zhou, Wenliang; Deng, Hongmei; Yu, Lu Journal of Applied Physics, Vol. 117, Issue 19 https://doi.org/10.1063/1.4921459	journal	May 2015
Magnetic and multiferroic properties of dilute Fe-doped BaTiO ₃ crystals Staruch, M.; ElBidweihy, H.; Cain, M. G. APL Materials, Vol. 8, Issue 3 https://doi.org/10.1063/5.0002863	journal	March 2020
Room temperature multiferroicity and magnetodielectric coupling in 0–3 composite thin films Pradhan, Dhiren K.; Kumari, Shalini; Vasudevan, Rama K. Journal of Applied Physics, Vol. 127, Issue 19 https://doi.org/10.1063/5.0004480	journal	May 2020
Crystal stability and the theory of ferroelectricity Cochran, W. Advances in Physics, Vol. 9, Issue 36 https://doi.org/10.1080/00018736000101229	journal	October 1960
Dielectric Properties of BaTiO ₃ -KNbO ₃ Composites Balčiūnas, Sergejus; Ivanov, Maksim; Banys, Jūras Ferroelectrics, Vol. 512, Issue 1 https://doi.org/10.1080/00150193.2017.1355178	journal	May 2017
Electric field effects on polar-nanoregions in Li-doped KTa _1- _x Nb _x O ₃ single crystals probed by micro-Brillouin scattering Rahaman, M. M.; Imai, T.; Sakamoto, T. Integrated Ferroelectrics, Vol. 185, Issue 1 https://doi.org/10.1080/10584587.2017.1370282	journal	November 2017
The intrinsic central peak at the structural phase transitions in KNbO ₃ Fontana, M. D.; Ridah, A.; Kugel, G. E. Journal of Physics C: Solid State Physics, Vol. 21, Issue 34 https://doi.org/10.1088/0022-3719/21/34/019	journal	December 1988
Revival of the magnetoelectric effect Fiebig, Manfred Journal of Physics D: Applied Physics, Vol. 38, Issue 8 https://doi.org/10.1088/0022-3727/38/8/R01	journal	April 2005
High piezoelectric properties and domain configuration in BaTiO ₃ ceramics obtained through the solid-state reaction route Shao, Shoufu; Zhang, Jialiang; Zhang, Zong Journal of Physics D: Applied Physics, Vol. 41, Issue 12 https://doi.org/10.1088/0022-3727/41/12/125408	journal	May 2008
Effects of Configuration Interaction on Intensities and Phase Shifts Fano, U. Physical Review, Vol. 124, Issue 6 https://doi.org/10.1103/PhysRev.124.1866	journal	December 1961
Raman Spectrum of Single-Domain BaTi O 3 DiDomenico, M.; Wemple, S. H.; Porto, S. P. S. Physical Review, Vol. 174, Issue 2 https://doi.org/10.1103/PhysRev.174.522	journal	October 1968
Lattice dynamics of crystals with tetragonal BaTiO 3 structure Freire, J. D.; Katiyar, R. S. Physical Review B, Vol. 37, Issue 4 https://doi.org/10.1103/PhysRevB.37.2074	journal	February 1988
Deviation from Curie-Weiss behavior in relaxor ferroelectrics Viehland, Dwight; Jang, S. J.; Cross, L. Eric Physical Review B, Vol. 46, Issue 13 https://doi.org/10.1103/PhysRevB.46.8003	journal	October 1992
Polaronic relaxation in perovskites Bidault, O.; Maglione, M.; Actis, M. Physical Review B, Vol. 52, Issue 6 https://doi.org/10.1103/PhysRevB.52.4191	journal	August 1995
High-pressure Raman studies of polycrystalline BaTiO 3 Venkateswaran, Uma D.; Naik, Vaman M.; Naik, Ratna Physical Review B, Vol. 58, Issue 21 https://doi.org/10.1103/PhysRevB.58.14256	journal	December 1998
Oxygen-vacancy-related low-frequency dielectric relaxation and electrical conduction in B i : S r T i O 3 Ang, Chen; Yu, Zhi; Cross, L. E. Physical Review B, Vol. 62, Issue 1 https://doi.org/10.1103/PhysRevB.62.228	journal	July 2000
Lattice Modes in Ferroelectric Perovskites: PbTi O 3 Burns, Gerald; Scott, Bruce A. Physical Review B, Vol. 7, Issue 7 https://doi.org/10.1103/PhysRevB.7.3088	journal	April 1973
Grain-size effects on the ferroelectric behavior of dense nanocrystalline BaTiO 3 ceramics Zhao, Zhe; Buscaglia, Vincenzo; Viviani, Massimo Physical Review B, Vol. 70, Issue 2 https://doi.org/10.1103/PhysRevB.70.024107	journal	July 2004
Temperature evolution of the relaxor dynamics in Pb ( Zn 1 ∕ 3 Nb 2 ∕ 3 ) O 3 : A critical Raman analysis Toulouse, J.; Jiang, F.; Svitelskiy, O. Physical Review B, Vol. 72, Issue 18 https://doi.org/10.1103/PhysRevB.72.184106	journal	November 2005
Inverted hysteresis loops observed in a randomly distributed cobalt nanoparticle system Yang, JungYup; Kim, JooHyung; Lee, JunSeok Physical Review B, Vol. 78, Issue 9 https://doi.org/10.1103/PhysRevB.78.094415	journal	September 2008
Room-temperature ferromagnetism and ferroelectricity in Fe-doped BaTiO 3 Xu, B.; Yin, K. B.; Lin, J. Physical Review B, Vol. 79, Issue 13 https://doi.org/10.1103/PhysRevB.79.134109	journal	April 2009
Precursor effects, broken local symmetry, and coexistence of order-disorder and displacive dynamics in perovskite ferroelectrics Bussmann-Holder, A.; Beige, H.; Völkel, G. Physical Review B, Vol. 79, Issue 18 https://doi.org/10.1103/PhysRevB.79.184111	journal	May 2009
Landau theory of domain wall magnetoelectricity Daraktchiev, Maren; Catalan, Gustau; Scott, James F. Physical Review B, Vol. 81, Issue 22 https://doi.org/10.1103/PhysRevB.81.224118	journal	June 2010
Precursor dynamics in the ferroelectric phase transition of barium titanate single crystals studied by Brillouin light scattering Ko, Jae-Hyeon; Kim, Tae Hyun; Roleder, K. Physical Review B, Vol. 84, Issue 9 https://doi.org/10.1103/PhysRevB.84.094123	journal	September 2011
Contradictory nature of Co doping in ferroelectric BaTi O 3 Ponath, Patrick; O’Hara, Andrew; Cao, Hai-Xia Physical Review B, Vol. 94, Issue 20 https://doi.org/10.1103/PhysRevB.94.205121	journal	November 2016
Palladium-based ferroelectrics and multiferroics: Theory and experiment Kumari, Shalini; Pradhan, Dhiren K.; Ortega, Nora Physical Review B, Vol. 95, Issue 21 https://doi.org/10.1103/PhysRevB.95.214109	journal	June 2017
Lead palladium titanate: A room-temperature multiferroic Gradauskaite, Elzbieta; Gardner, Jonathan; Smith, Rebecca M. Physical Review B, Vol. 96, Issue 10 https://doi.org/10.1103/PhysRevB.96.104104	journal	September 2017
Auger-Like Resonant Interference in Raman Scattering from One- and Two-Phonon States of BaTi O 3 Rousseau, D. L.; Porto, S. P. S. Physical Review Letters, Vol. 20, Issue 24 https://doi.org/10.1103/PhysRevLett.20.1354	journal	June 1968
Carrier-mediated control over the soft mode and ferroelectricity in BaTiO 3 Gu, Fangyuan; Murray, Éamonn; Tangney, Paul Physical Review Materials, Vol. 5, Issue 3 https://doi.org/10.1103/PhysRevMaterials.5.034414	journal	March 2021
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Theoretical Prediction of Magnetic Properties of Ba(Ti1-xMx)O3 (M=Sc,V,Cr,Mn,Fe,Co,Ni,Cu) Nakayama, Hiroyuki; Katayama-Yoshida, Hiroshi Japanese Journal of Applied Physics, Vol. 40, Issue Part 2, No. 12B https://doi.org/10.1143/JJAP.40.L1355	journal	December 2001
Enhanced Magnetic Properties of Co-Doped BiFeO3 Thin Films via Structural Progression Bai, Liang; Sun, Mingjie; Ma, Wenjing Nanomaterials, Vol. 10, Issue 9 https://doi.org/10.3390/nano10091798	journal	September 2020
Magnetoelectric Composites: Applications, Coupling Mechanisms, and Future Directions Pradhan, Dhiren K.; Kumari, Shalini; Rack, Philip D. Nanomaterials, Vol. 10, Issue 10 https://doi.org/10.3390/nano10102072	journal	October 2020

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