Selective alkane activation with single-site atoms on amorphous support

Hock, Adam S.; Schweitzer, Neil M.; Miller, Jeffrey T.; Hu, Bo

Selective alkane activation with single-site atoms on amorphous support

Patent · 12 October 2021

OSTI ID:1859925

Hock, Adam S.; Schweitzer, Neil M.; Miller, Jeffrey T.; Hu, Bo

The present invention relates generally to catalysts and methods for use in olefin production. More particularly, the present invention relates to novel amorphously supported single-center, Lewis acid metal ions and use of the same as catalysts.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Number(s):: 11,141,714

Application Number:: 14/946,453

OSTI ID:: 1859925

Country of Publication:: United States

Language:: English

References (12)

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Structure and Density of Active Zn Species in Zn/H-ZSM5 Propane Aromatization Catalysts Biscardi, Joseph A.; Meitzner, George D.; Iglesia, Enrique Journal of Catalysis, Vol. 179, Issue 1 https://doi.org/10.1006/jcat.1998.2177	journal	October 1998
Oxidative dehydrogenation of ethane over Na₂WO₄-Mn/SiO₂ catalyst using oxygen and carbon dioxide as oxidants Liu, Yu; Xue, Jinahen; Liu, Xuxia Studies in Surface Science and Catalysis, Vol. 119, p. 593-597 https://doi.org/10.1016/S0167-2991(98)80496-5	book	January 1998
Dehydrogenation and oxydehydrogenation of paraffins to olefins Bhasin, M. M.; McCain, J. H.; Vora, B. V. Applied Catalysis A: General, Vol. 221, Issue 1-2, p. 397-419 https://doi.org/10.1016/S0926-860X(01)00816-X	journal	November 2001
Oxidative dehydrogenation of ethane and propane: How far from commercial implementation? Cavani, F.; Ballarini, N.; Cericola, A. Catalysis Today, Vol. 127, Issue 1-4, p. 113-131 https://doi.org/10.1016/j.cattod.2007.05.009	journal	September 2007
Olefins from conventional and heavy feedstocks: Energy use in steam cracking and alternative processes Ren, T.; Patel, M.; Blok, K. Energy, Vol. 31, Issue 4 https://doi.org/10.1016/j.energy.2005.04.001	journal	March 2006
The synthesis of highly dispersed noble and base metals on silica via strong electrostatic adsorption: I. Amorphous silica Jiao, Ling; Regalbuto, John R. Journal of Catalysis, Vol. 260, Issue 2 https://doi.org/10.1016/j.jcat.2008.09.022	journal	December 2008
Selective propane dehydrogenation with single-site CoII on SiO2 by a non-redox mechanism Hu, Bo; “Bean” Getsoian, Andrew; Schweitzer, Neil M. Journal of Catalysis, Vol. 322 https://doi.org/10.1016/j.jcat.2014.10.018	journal	February 2015
Isolated Fe ^II on Silica As a Selective Propane Dehydrogenation Catalyst Hu, Bo; Schweitzer, Neil M.; Zhang, Guanghui ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00248	journal	May 2015
Identification of a Pt ₃ Co Surface Intermetallic Alloy in Pt–Co Propane Dehydrogenation Catalysts Cesar, Laryssa Goncalves; Yang, Ce; Lu, Zheng ACS Catalysis, Vol. 9, Issue 6 https://doi.org/10.1021/acscatal.9b00549	journal	April 2019
Control of Dispersion of Ni ²⁺ Ions via Chelate Ligands in the Preparation of Ni/SiO ₂ Materials. A XAFS Study Carriat, J. Y.; Che, M.; Kermarec, M. Journal of the American Chemical Society, Vol. 120, Issue 9 https://doi.org/10.1021/ja9725561	journal	February 1998
Silica-Grafted Diethylzinc and a Silsesquioxane-Based Zinc Alkyl Complex as Catalysts for the Alternating Oxirane−Carbon Dioxide Copolymerization Duchateau, Robbert; van Meerendonk, Wouter J.; Huijser, Saskia Organometallics, Vol. 26, Issue 17 https://doi.org/10.1021/om700367x	journal	July 2007

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