Selective alkane activation with single-site atoms on amorphous support

Hock, Adam S.; Schweitzer, Neil M.; Miller, Jeffrey T.; Hu, Bo

Selective alkane activation with single-site atoms on amorphous support

Patent · Tue Nov 24 04:00:00 EST 2015

OSTI ID:1226832

Hock, Adam S.; Schweitzer, Neil M.; Miller, Jeffrey T.; Hu, Bo

The present invention relates generally to catalysts and methods for use in olefin production. More particularly, the present invention relates to novel amorphously supported single-center, Lewis acid metal ions and use of the same as catalysts.

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Number(s):: 9,192,919

Application Number:: 13/830,320

OSTI ID:: 1226832

Country of Publication:: United States

Language:: English

References (6)

Dehydrogenation and oxydehydrogenation of paraffins to olefins Bhasin, M. M.; McCain, J. H.; Vora, B. V. Applied Catalysis A: General, Vol. 221, Issue 1-2, p. 397-419 https://doi.org/10.1016/S0926-860X(01)00816-X	journal	November 2001
Structure and Density of Active Zn Species in Zn/H-ZSM5 Propane Aromatization Catalysts Biscardi, Joseph A.; Meitzner, George D.; Iglesia, Enrique Journal of Catalysis, Vol. 179, Issue 1 https://doi.org/10.1006/jcat.1998.2177	journal	October 1998
Oxidative dehydrogenation of ethane and propane: How far from commercial implementation? Cavani, F.; Ballarini, N.; Cericola, A. Catalysis Today, Vol. 127, Issue 1-4, p. 113-131 https://doi.org/10.1016/j.cattod.2007.05.009	journal	September 2007
Olefins from conventional and heavy feedstocks: Energy use in steam cracking and alternative processes Ren, T.; Patel, M.; Blok, K. Energy, Vol. 31, Issue 4 https://doi.org/10.1016/j.energy.2005.04.001	journal	March 2006
The synthesis of highly dispersed noble and base metals on silica via strong electrostatic adsorption: I. Amorphous silica Jiao, Ling; Regalbuto, John R. Journal of Catalysis, Vol. 260, Issue 2 https://doi.org/10.1016/j.jcat.2008.09.022	journal	December 2008
Single-Site Heterogeneous Catalysts Thomas, John Meurig; Raja, Robert; Lewis, Dewi W. Angewandte Chemie International Edition, Vol. 44, Issue 40, p. 6456-6482 https://doi.org/10.1002/anie.200462473	journal	October 2005

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Selective alkane activation with single-site atoms on amorphous support

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