The chemical and physical properties of tetravalent lanthanides: Pr, Nd, Tb, and Dy

Gompa, Thaige P.; Ramanathan, Arun; Rice, Natalie T.; La Pierre, Henry S.

doi:10.1039/d0dt01400a

The chemical and physical properties of tetravalent lanthanides: Pr, Nd, Tb, and Dy

Journal Article · Thu May 21 00:00:00 EDT 2020 · Dalton Transactions

DOI:https://doi.org/10.1039/d0dt01400a· OSTI ID:1853166

^[1]; Ramanathan, Arun ^[2]; ^[2]; ^[2]

Georgia Institute of Technology, Atlanta, GA (United States); OSTI
Georgia Institute of Technology, Atlanta, GA (United States)

The fundamental redox chemistry and valence electronic structure of the lanthanides in molecular complexes and extended solids continues to be a fertile area of research. The contemporary understanding of the accessible oxidation states of the lanthanide elements and the variability in their electronic structure is the result of several paradigm shifts. While the lanthanide elements have already found widespread use in technical and consumer applications, the continued reevaluation of basic redox properties is a central chemical concern to establish a more complete description of periodic properties. This fundamental understanding of valence electronic structure as it is derived from oxidation state and coordination environment is essential for the continued development of lanthanides in quantum information science and quantum materials research. This review presents the chemical and physical properties of tetravalent lanthanide ions in extended solids and molecules with a focus on the elements apart from cerium: praseodymium, neodymium, terbium, and dysprosium.

View Accepted Manuscript (DOE)

Research Organization:: Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019385

OSTI ID:: 1853166

Alternate ID(s):: OSTI ID: 1632968

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 45 Vol. 49; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (364)

A New Route to Neodymium(II) and Dysprosium(II) Iodides Bochkarev, Mikhail N.; Fagin, Anatolii A. Chemistry - A European Journal, Vol. 5, Issue 10 https://doi.org/10.1002/(SICI)1521-3765(19991001)5:10<2990::AID-CHEM2990>3.0.CO;2-U	journal	October 1999
[NdI2(thf)5], the First Crystallographically Authenticated Neodymium(II) Complex Bochkarev, Mikhail N.; Fedushkin, Igor L.; Dechert, Sebastian Angewandte Chemie International Edition, Vol. 40, Issue 17 https://doi.org/10.1002/1521-3773(20010903)40:17<3176::AID-ANIE3176>3.0.CO;2-Y	journal	September 2001
Tetravalent Dysprosium in a Perovskite-Type Oxide Han, Donglin; Uda, Tetsuya; Nose, Yoshitaro Advanced Materials, Vol. 24, Issue 15 https://doi.org/10.1002/adma.201200127	journal	March 2012
Recent Progress in Oxo- and Fluorometalate Chemistry Hoppe, Rudolf Angewandte Chemie International Edition in English, Vol. 20, Issue 1 https://doi.org/10.1002/anie.198100631	journal	January 1981
LaI: An Unprecedented Binary Rare Earth Metal Monohalide with a NiAs-Type Structure Martin, James D.; Corbett, John D. Angewandte Chemie International Edition in English, Vol. 34, Issue 2 https://doi.org/10.1002/anie.199502331	journal	February 1995
Synthesis and Structure of the First Molecular Thulium(II) Complex:[TmI2(MeOCH2CH2OMe)3] Bochkarev, Mikhail N.; Fedushkin, Igor L.; Fagin, Anatoly A. Angewandte Chemie International Edition in English, Vol. 36, Issue 12 https://doi.org/10.1002/anie.199701331	journal	February 1997
Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State Hitchcock, Peter B.; Lappert, Michael F.; Maron, Laurent Angewandte Chemie International Edition, Vol. 47, Issue 8 https://doi.org/10.1002/anie.200704887	journal	February 2008
All the Lanthanides Do It and Even Uranium Does Oxidation State +2 Meyer, Gerd Angewandte Chemie International Edition, Vol. 53, Issue 14 https://doi.org/10.1002/anie.201311325	journal	March 2014
Coordination and Redox Isomerization in the Reduction of a Uranium(III) Monoarene Complex La Pierre, Henry S.; Kameo, Hajime; Halter, Dominik P. Angewandte Chemie International Edition, Vol. 53, Issue 28 https://doi.org/10.1002/anie.201402048	journal	July 2014
Synthesis and Characterization of a Uranium(II) Monoarene Complex Supported by δ Backbonding La Pierre, Henry S.; Scheurer, Andreas; Heinemann, Frank W. Angewandte Chemie International Edition, Vol. 53, Issue 28 https://doi.org/10.1002/anie.201402050	journal	May 2014
The Renaissance of Non-Aqueous Uranium Chemistry Liddle, Stephen T. Angewandte Chemie International Edition, Vol. 54, Issue 30 https://doi.org/10.1002/anie.201412168	journal	June 2015
Pentavalent Lanthanide Compounds: Formation and Characterization of Praseodymium(V) Oxides Zhang, Qingnan; Hu, Shu-Xian; Qu, Hui Angewandte Chemie International Edition, Vol. 55, Issue 24 https://doi.org/10.1002/anie.201602196	journal	April 2016
Solution Synthesis, Structure, and CO ₂ Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe ₃ ) ₂ ] ₃ } ⁻ Woen, David H.; Chen, Guo P.; Ziller, Joseph W. Angewandte Chemie International Edition, Vol. 56, Issue 8 https://doi.org/10.1002/anie.201611758	journal	January 2017
A Structurally Characterized Organometallic Plutonium(IV) Complex Apostolidis, Christos; Walter, Olaf; Vogt, Jochen Angewandte Chemie International Edition, Vol. 56, Issue 18 https://doi.org/10.1002/anie.201701858	journal	March 2017
Reduction of a Cerium(III) Siloxide Complex To Afford a Quadruple-Decker Arene-Bridged Cerium(II) Sandwich Kelly, Rory P.; Maron, Laurent; Scopelliti, Rosario Angewandte Chemie International Edition, Vol. 56, Issue 49 https://doi.org/10.1002/anie.201709769	journal	November 2017
Essential and Ubiquitous: The Emergence of Lanthanide Metallobiochemistry Daumann, Lena J. Angewandte Chemie International Edition, Vol. 58, Issue 37 https://doi.org/10.1002/anie.201904090	journal	August 2019
Isolation of a Perfectly Linear Uranium(II) Metallocene Guo, Fu‐Sheng; Tsoureas, Nikolaos; Huang, Guo‐Zhang Angewandte Chemie International Edition, Vol. 59, Issue 6 https://doi.org/10.1002/anie.201912663	journal	February 2020
Stabilization of the Oxidation State +IV in Siloxide‐Supported Terbium Compounds Willauer, Aurélien R.; Palumbo, Chad T.; Scopelliti, Rosario Angewandte Chemie International Edition, Vol. 59, Issue 9 https://doi.org/10.1002/anie.201914733	journal	February 2020
DFT Study of the Active Site of the XoxF-Type Natural, Cerium-Dependent Methanol Dehydrogenase Enzyme Bogart, Justin A.; Lewis, Andrew J.; Schelter, Eric J. Chemistry - A European Journal, Vol. 21, Issue 4 https://doi.org/10.1002/chem.201405159	journal	November 2014
Expanding the Chemistry of Molecular U ²⁺ Complexes: Synthesis, Characterization, and Reactivity of the {[C ₅ H ₃ (SiMe ₃ ) ₂ ] ₃ U} ⁻ Anion Windorff, Cory J.; MacDonald, Matthew R.; Meihaus, Katie R. Chemistry - A European Journal, Vol. 22, Issue 2 https://doi.org/10.1002/chem.201503583	journal	December 2015
Extending the Row of Lanthanide Tetrafluorides: A Combined Matrix-Isolation and Quantum-Chemical Study Vent-Schmidt, Thomas; Fang, Zongtang; Lee, Zachary Chemistry - A European Journal, Vol. 22, Issue 7 https://doi.org/10.1002/chem.201504182	journal	January 2016
Remarkably High Stability of Late Actinide Dioxide Cations: Extending Chemistry to Pentavalent Berkelium and Californium Dau, Phuong D.; Vasiliu, Monica; Peterson, Kirk A. Chemistry - A European Journal, Vol. 23, Issue 68 https://doi.org/10.1002/chem.201704193	journal	November 2017
Synthesis, Structure, and Magnetism of Tris(amide) [Ln{N(SiMe ₃ ) ₂ } ₃ ] ¹⁻ Complexes of the Non-traditional +2 Lanthanide Ions Ryan, Austin J.; Darago, Lucy E.; Balasubramani, Sree Ganesh Chemistry - A European Journal, Vol. 24, Issue 30 https://doi.org/10.1002/chem.201800610	journal	May 2018
Rare‐Earth Metal(II) Aryloxides: Structure, Synthesis, and EPR Spectroscopy of [K(2.2.2‐cryptand)][Sc(OC 6 H 2 t Bu 2 ‐2,6‐Me‐4) 3 ] Moehring, Samuel A.; Beltrán‐Leiva, María J.; Páez‐Hernández, Dayán Chemistry – A European Journal, Vol. 24, Issue 68 https://doi.org/10.1002/chem.201803807	journal	November 2018
Ab Initio Analysis of Metal–Ligand Bonding in An(COT) ₂ with An=Th, U in Their Ground‐ and Core‐Excited States Ganguly, Gaurab; Sergentu, Dumitru‐Claudiu; Autschbach, Jochen Chemistry – A European Journal, Vol. 26, Issue 8 https://doi.org/10.1002/chem.201904166	journal	November 2019
Evaluating Electron‐Transfer Reactivity of Complexes of Actinides in +2 and +3 Oxidation States by using EPR Spectroscopy Moehring, Samuel A.; Evans, William J. Chemistry – A European Journal, Vol. 26, Issue 7 https://doi.org/10.1002/chem.201905581	journal	January 2020
Lanthanide(III) Sandwich and Half-Sandwich Complexes with Bulky Cyclooctatetraenyl Ligands: Synthesis, Structures, and Magnetic Properties: Lanthanide(III) Sandwich and Half-Sandwich Complexes with Bulky Cyclooctatetraenyl Ligands: Synthesis, Structures, and Magnetic Properties Lorenz, Volker; Liebing, Phil; Böhme, Michael European Journal of Inorganic Chemistry, Vol. 2017, Issue 41 https://doi.org/10.1002/ejic.201700878	journal	November 2017
Comparative studies of quasi-relativistic density functional methods for the description of lanthanide and actinide complexes Vetere, Valentina; Maldivi, Pascale; Adamo, Carlo Journal of Computational Chemistry, Vol. 24, Issue 7 https://doi.org/10.1002/jcc.10228	journal	May 2003
Electron Paramagnetic Resonance of Tetravalent Praseodymium in Zircon Harris, E. A.; Mellor, J. H.; Parke, S. physica status solidi (b), Vol. 122, Issue 2 https://doi.org/10.1002/pssb.2221220241	journal	April 1984
Optical Absorption in Thin Films of Cerium Dioxide and Cerium Dioxide Containing Silicon Monoxide Hogarth, C. A.; Al-Dhhan, Z. T. physica status solidi (b), Vol. 137, Issue 2 https://doi.org/10.1002/pssb.2221370245	journal	October 1986
Messungen an zwei- und vierwertigen Verbindungen der seltenen Erden. II. Eine Systematik der seltenen Erden, begründet auf periodischen Eigenschaftsänderungen ihrer lonen Klemm, Wilhelm Zeitschrift für anorganische und allgemeine Chemie, Vol. 184, Issue 1 https://doi.org/10.1002/zaac.19291840127	journal	November 1929
Messungen an zwei- und vierwertigen Verbindungen der seltenen Erden. V. Certetrafluorid Klemm, Wilhelm; Henkel, Paul Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 220, Issue 2 https://doi.org/10.1002/zaac.19342200210	journal	October 1934
Über die Wertigkeit des Praseodyms und des Terbiums Prandtl, Wilhelm; Rieder, Georg Zeitschrift für anorganische und allgemeine Chemie, Vol. 238, Issue 2-3 https://doi.org/10.1002/zaac.19382380207	journal	July 1938
Über einige höhere Fluoride (PbF ₄ , CeF ₄ , BiF ₅ ) von Wartenberg, H. Zeitschrift für anorganische und allgemeine Chemie, Vol. 244, Issue 4 https://doi.org/10.1002/zaac.19402440401	journal	August 1940
Komplexe Fluoride Seltener Erden: Cs3TbF7 Hoppe, Rudolf; R�dder, Karl-Martin Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 312, Issue 5-6 https://doi.org/10.1002/zaac.19613120506	journal	November 1961
Komplexe Fluoride des vierwertigen Praseodyms Hoppe, Rudolf; Liebe, Werner Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 313, Issue 3-4 https://doi.org/10.1002/zaac.19613130313	journal	December 1961
�ber Ordnungsvarianten des NaCl-Typs. Neue kubische Formen von NaMO2 (M=Sc, Y, Dy, Tm, Yb, Lu), K2MO3 Rb2MO3, (M = Ce, Pr, Th) und Cs2ThO3 Brunn, H.; Hoppe, R. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 430, Issue 1 https://doi.org/10.1002/zaac.19774300114	journal	April 1977
Die Kristallstruktur von Cs2PrO3, sowie �ber Cs2CeO3, Cs2TbO3, Rb2CeO3 und Rb2TbO3 Brunn, H.; Hoppe, R. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 433, Issue 1 https://doi.org/10.1002/zaac.19774330120	journal	August 1977
�ber vierwertiges Dysprosium in Sauerstoff-Perowskiten und �ber Verbindungen des Formeltyps Ba3SE4O9 (SE = Selten-Erd-Element) Brauer, G.; Kristen, H. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 462, Issue 1 https://doi.org/10.1002/zaac.19804620104	journal	March 1980
Anwendung der Edelgasfluoride zur Darstellung von Verbindungen vierwertiger Lanthanoide Spitzin, V. I.; Martynenko, L. I.; Kiselew, J. U. M. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 495, Issue 1 https://doi.org/10.1002/zaac.19824950105	journal	December 1982
�ber Li8PrO6 und Li8TbO6 (Mit einer Bemerkung �ber Li8CeO6) Wolf, R.; Hoppe, R. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 522, Issue 3 https://doi.org/10.1002/zaac.19855220306	journal	January 1985
Neue Vertreter der Li8SnO6-Familie: Li8IrO6, Li8PtO6 und Li8CeO6 [1, 2] Kroeschell, P.; Wolf, R.; Hoppe, R. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 536, Issue 5 https://doi.org/10.1002/zaac.19865360510	journal	May 1986
Neue Oxoterbate(IV) mit Lithium Rb2Li14[Tb3O14] und Li6Tb2O7 Wolf, R.; Hoppe, R. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 539, Issue 8 https://doi.org/10.1002/zaac.19865390812	journal	August 1986
�ber Na2PrO3 und Na2TbO3 Wolf, R.; Hoppe, R. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 556, Issue 1 https://doi.org/10.1002/zaac.19885560110	journal	January 1988
The First Mixed-Valent Europium(II,III) Oxide Bromide: Eu2O2Br Hammerich, Stefanie; Pantenburg, Ingo; Meyer, Gerd Zeitschrift für anorganische und allgemeine Chemie, Vol. 632, Issue 8-9 https://doi.org/10.1002/zaac.200600030	journal	July 2006
The Elusive Tetrasamarium-oxide-hexabromide, Sm4OBr6 Hammerich, Stefanie; Pantenburg, Ingo; Meyer, Gerd Zeitschrift für anorganische und allgemeine Chemie, Vol. 632, Issue 14 https://doi.org/10.1002/zaac.200600134	journal	October 2006
Neue Vertreter des K2Li14[Pb3O14]-Typs Cs2Li14[Tb3O14] und K2Li14[Zr3O14] [1, 2] Voigt, S.; Werthmann, R.; Hoppe, R. Zeitschrift für anorganische und allgemeine Chemie, Vol. 574, Issue 1 https://doi.org/10.1002/zaac.655740107	journal	July 1989
Standard molar enthalpies of formation of PrO2and SrPrO3: the unusual thermodynamic stability of APrO3(A = Sr, Ba) Gramsch, S. A.; Morss, L. R. The Journal of Chemical Thermodynamics, Vol. 27, Issue 5 https://doi.org/10.1006/jcht.1995.0056	journal	May 1995
The thermochemical properties of BaCeO3(s) and SrCeO3(s) fromT=(5 to 1500) K Cordfunke, E. H. P.; Booij, A. S.; Huntelaar, M. E. The Journal of Chemical Thermodynamics, Vol. 30, Issue 4 https://doi.org/10.1006/jcht.1997.0302	journal	April 1998
Magnetic Susceptibility and Electron Paramagnetic Resonance Spectrum of Tetravalent Praseodymium Ions in BaPrO3 Hinatsu, Yukio Journal of Solid State Chemistry, Vol. 102, Issue 2 https://doi.org/10.1006/jssc.1993.1046	journal	February 1993
Electron Paramagnetic Resonance Spectrum of Pr4+ in BaCeO3 Hinatsu, Yukio; Edelstein, Norman Journal of Solid State Chemistry, Vol. 112, Issue 1 https://doi.org/10.1006/jssc.1994.1263	journal	September 1994
Electron Paramagnetic Resonance Spectra of Pr4+in BaCeO3, BaZrO3, BaSnO3, and Their Solid Solutions Hinatsu, Yukio Journal of Solid State Chemistry, Vol. 122, Issue 2 https://doi.org/10.1006/jssc.1996.0131	journal	March 1996
On the Existence of PrSrO3-Type Phase and Its Bi/Pr-Substituted Solid Solution Horyń, R.; Wołcyrz, M.; Bukowski, Z. Journal of Solid State Chemistry, Vol. 124, Issue 1 https://doi.org/10.1006/jssc.1996.0222	journal	June 1996
Magnetic Susceptibilities and Electron Paramagnetic Resonance Spectra of Lithium-Rich Lanthanide Oxides Li8Pro6and Li8TbO6 Hinatsu, Yukio Journal of Solid State Chemistry, Vol. 128, Issue 2 https://doi.org/10.1006/jssc.1996.7193	journal	February 1997
Electron Paramagnetic Resonance Spectra of Pr4+Ions Doped in Sr2SnO4and Ba2SnO4 Hinatsu, Yukio Journal of Solid State Chemistry, Vol. 130, Issue 2 https://doi.org/10.1006/jssc.1997.7293	journal	May 1997
Structure and Magnetic Properties of Tetravalent Praseodymium Perovskite SrPrO3 Hinatsu, Yukio; Itoh, Masahiro; Edelstein, Norman Journal of Solid State Chemistry, Vol. 132, Issue 2 https://doi.org/10.1006/jssc.1997.7471	journal	September 1997
Electron Paramagnetic Resonance Study of Pr4+Ions Doped in BaSnO3, Ba2SnO4, and Ba3Sn2O7 Hinatsu, Yukio; Tezuka, Keitaro Journal of Solid State Chemistry, Vol. 138, Issue 2 https://doi.org/10.1006/jssc.1998.7792	journal	July 1998
Electron Paramagnetic Resonance Spectrum of Pr4+in Sr2CeO4 Hinatsu, Yukio; Wakeshima, Makoto; Edelstein, Norman Journal of Solid State Chemistry, Vol. 144, Issue 1 https://doi.org/10.1006/jssc.1998.8047	journal	April 1999
Electron Paramagnetic Resonance Spectra of Pr4+Ions Doped in Pyrochlore-Type Compounds La2Sn2O7and La2Zr2O7 Tezuka, Keitaro; Hinatsu, Yukio Journal of Solid State Chemistry, Vol. 143, Issue 1 https://doi.org/10.1006/jssc.1998.8106	journal	February 1999
Giant Negative Magnetoresistance in GdI2: Prediction and Realization Felser, C.; Ahn, K.; Kremer, R. K. Journal of Solid State Chemistry, Vol. 147, Issue 1 https://doi.org/10.1006/jssc.1999.8274	journal	October 1999
Electron Paramagnetic Resonance Study of Pr4+ Ions Doped in BaHfO3 Perovskite Tezuka, Keitaro; Hinatsu, Yukio Journal of Solid State Chemistry, Vol. 156, Issue 1 https://doi.org/10.1006/jssc.2000.8982	journal	January 2001
On the Crystal Structure of BaTbO3 Fu, W. T.; Visser, D.; IJdo, D. J. W. Journal of Solid State Chemistry, Vol. 165, Issue 2 https://doi.org/10.1006/jssc.2002.9566	journal	May 2002
Neue Oxoterbate (IV) Hoppe, Rudolf; Seeger, Klaus Die Naturwissenschaften, Vol. 55, Issue 6 https://doi.org/10.1007/BF00591711	journal	January 1968
�ber Oxoterbate(IV): Na2TbO3 Hoppe, Rudolf; Lidecke, Werner Die Naturwissenschaften, Vol. 49, Issue 11 https://doi.org/10.1007/BF00601415	journal	January 1962
Neue tern�re Oxide vierwertiger Seltener Erden und des Thoriums Paletta, Elisabeth; Hoppe, Rudolf Die Naturwissenschaften, Vol. 53, Issue 23 https://doi.org/10.1007/BF00632275	journal	January 1966
�ber die vierwertigen Verbindungen des Praseodyms, 1. Mitt.: Komplexe Chloride, Nitrate und Sulfate des vierwertigen Praseodyms Pajakoff, Sw. Monatshefte f�r Chemie, Vol. 94, Issue 2 https://doi.org/10.1007/BF00900284	journal	January 1963
EPR study of the perovskitic structure SrTbO3 Azzoni, C. B.; Del Nero, Gr. L.; Lanzi, G. Lettere Al Nuovo Cimento Series 2, Vol. 19, Issue 10 https://doi.org/10.1007/BF02746850	journal	July 1977
PQQ-dependent methanol dehydrogenases: rare-earth elements make a difference Keltjens, Jan T.; Pol, Arjan; Reimann, Joachim Applied Microbiology and Biotechnology, Vol. 98, Issue 14 https://doi.org/10.1007/s00253-014-5766-8	journal	May 2014
On the oxidation states of metal elements in MO3 - (M=V, Nb, Ta, Db, Pr, Gd, Pa) anions Su, Jing; Hu, Shuxian; Huang, Wei Science China Chemistry, Vol. 59, Issue 4 https://doi.org/10.1007/s11426-015-5481-z	journal	February 2016
The preparation of praseodymium tetrafluoride Soriano, J.; Givon, M.; Shamir, J. Inorganic and Nuclear Chemistry Letters, Vol. 2, Issue 1 https://doi.org/10.1016/0020-1650(66)80082-X	journal	January 1966
Stabilization of praseodymium(IV) and terbium(IV) in aqueous carbonate solution Hobart, D. E.; Samhoun, K.; Young, J. P. Inorganic and Nuclear Chemistry Letters, Vol. 16, Issue 5 https://doi.org/10.1016/0020-1650(80)80069-9	journal	January 1980
Thermodynamics of lanthanide and actinide perovskite-type oxides IV. Molar enthalpies of formation of MM′O3 (M = Ba or Sr, M′ = Ce, Tb, or Am) compounds Goudiakas, J.; Haire, R. G.; Fuger, J. The Journal of Chemical Thermodynamics, Vol. 22, Issue 6 https://doi.org/10.1016/0021-9614(90)90150-O	journal	June 1990
Tetravalent lanthanides—I Sodium praseodymium(IV) fluorides Asprey, L. B.; Keenan, T. K. Journal of Inorganic and Nuclear Chemistry, Vol. 16, Issue 3-4 https://doi.org/10.1016/0022-1902(61)80499-5	journal	February 1961
Solvolytic disproportionation of non-stoichiometric oxides of praseodymium and terbium Sastry, R. L. N.; Mehrotra, P. N.; Rao, C. N. R. Journal of Inorganic and Nuclear Chemistry, Vol. 28, Issue 10 https://doi.org/10.1016/0022-1902(66)80102-1	journal	October 1966
Electron-transfer and f → d absorption bands of some lanthanide and actinide complexes and the standard (III–IV) oxidation potentials for each member of the lanthanide and actinide series Nugent, L. J.; Baybarz, R. D.; Burnett, J. L. Journal of Inorganic and Nuclear Chemistry, Vol. 33, Issue 8 https://doi.org/10.1016/0022-1902(71)80226-9	journal	August 1971
Charge-transfer spectra of tetravalent lanthanide ions in oxides Hoefdraad, H. E. Journal of Inorganic and Nuclear Chemistry, Vol. 37, Issue 9 https://doi.org/10.1016/0022-1902(75)80915-8	journal	September 1975
Enthalpy formation of americium dioxide and a thermochemical estimate of the electrode potential Am4+/Am3+ Morss, L. R.; Fuger, J. Journal of Inorganic and Nuclear Chemistry, Vol. 43, Issue 9 https://doi.org/10.1016/0022-1902(81)80548-9	journal	January 1981
Thermal decomposition of curium tetrafluoride and terbium tetrafluoride Gibson, John K.; Haire, Richard G. Journal of Solid State Chemistry, Vol. 73, Issue 2 https://doi.org/10.1016/0022-4596(88)90140-5	journal	April 1988
The magnetic susceptibility of Pr4+ in BaPrO3: Evidence of long-range magnetic order Bickel, M.; Goodman, G. L.; Soderholm, L. Journal of Solid State Chemistry, Vol. 76, Issue 1 https://doi.org/10.1016/0022-4596(88)90205-8	journal	September 1988
The oxidation state of Pr in PrBa2Cu3O7 Soderholm, L.; Goodman, G. L. Journal of Solid State Chemistry, Vol. 81, Issue 1 https://doi.org/10.1016/0022-4596(89)90209-0	journal	July 1989
Magnetic properties of the Tb4+ ion in Li2TbF6: Particular crystal chemical behavior within the Li2MIVF6 compounds Guillot, Maurice; El-Ghozzi, Malika; Avignant, Daniel Journal of Solid State Chemistry, Vol. 97, Issue 2 https://doi.org/10.1016/0022-4596(92)90049-2	journal	April 1992
Magnetic susceptibility and electron paramagnetic resonance studies of tetravalent terbium ions in BaTbO3 and SrTbO3 Hinatsu, Yukio Journal of Solid State Chemistry, Vol. 100, Issue 1 https://doi.org/10.1016/0022-4596(92)90163-P	journal	September 1992
Electric-deflection and thermal decomposition studies on CeF4, TbF4, AND PrF4 Kaiser, E. W.; Sunder, W. A.; Falconer, W. E. Journal of the Less Common Metals, Vol. 27, Issue 3 https://doi.org/10.1016/0022-5088(72)90070-7	journal	June 1972
On the nature of tetravalent terbium in carbonate-hydroxide solutions Varlashkin, P. G.; Begun, G. M.; Peterson, J. R. Journal of the Less Common Metals, Vol. 109, Issue 1 https://doi.org/10.1016/0022-5088(85)90112-2	journal	July 1985
Oxidation studies of selected lanthanides in acetonitrile Payne, G. F.; Peterson, J. R. Journal of the Less Common Metals, Vol. 126 https://doi.org/10.1016/0022-5088(86)90325-5	journal	December 1986
The synthesis and characterization of Dy doped into the perovskite BaCeO3 Soderholm, L.; Morss, L. R.; Mohar, M. F. Journal of the Less Common Metals, Vol. 127 https://doi.org/10.1016/0022-5088(87)90369-9	journal	January 1987
Preparation, crystalline properties and X-ray absorption spectra of rare earth oxides ROx (R ≡ Ce, PrandTb; 1.5 ⩽ x ⩽ 2) Gasgnier, M.; Schiffmacher, G.; Albert, L. Journal of the Less Common Metals, Vol. 156, Issue 1-2 https://doi.org/10.1016/0022-5088(89)90407-4	journal	December 1989
Das erste oxopraseodymat mit oktaeder-tripel: Rb2Li14[Pr3O14] Voigt, Stephan; Hoppe, Rudolf Journal of the Less Common Metals, Vol. 156, Issue 1-2 https://doi.org/10.1016/0022-5088(89)90410-4	journal	December 1989
Structure magnetique de l'oxyde de terbium TbO2 Quezel-Ambrunaz, S.; Bertaut, E. F. Solid State Communications, Vol. 11, Issue 5 https://doi.org/10.1016/0038-1098(72)90471-1	journal	September 1972
Neutron scattering investigation of the magnetic ground state of PrO2 Kern, S.; Loong, C. -K.; Faber, J. Solid State Communications, Vol. 49, Issue 3 https://doi.org/10.1016/0038-1098(84)90913-X	journal	January 1984
Theory of core photoabsorption spectra in CeO2 Jo, T.; Kotani, A. Solid State Communications, Vol. 54, Issue 5 https://doi.org/10.1016/0038-1098(85)90948-2	journal	May 1985
Theory of 3d-XPS and L3-XAS in CeF4 Kotani, A.; Okada, K.; Okada, M. Solid State Communications, Vol. 64, Issue 12 https://doi.org/10.1016/0038-1098(87)90362-0	journal	December 1987
Superconducting and normal state properties of Dalichaouch, Y.; Torikachvili, M. S.; Early, E. A. Solid State Communications, Vol. 65, Issue 9 https://doi.org/10.1016/0038-1098(88)90746-6	journal	March 1988
Thermal decomposition of lanthanide and actinide tetrafluorides Gibson, John K.; Haire, Richard G. Thermochimica Acta, Vol. 133 https://doi.org/10.1016/0040-6031(88)87164-8	journal	October 1988
Thermodynamic properties of ternary barium oxides Matsui, Tsuneo Thermochimica Acta, Vol. 253 https://doi.org/10.1016/0040-6031(94)02019-K	journal	April 1995
The synthesis and structures of complex rare-earth halides Meyer, Gerd Progress in Solid State Chemistry, Vol. 14, Issue 3 https://doi.org/10.1016/0079-6786(82)90005-X	journal	January 1982
Structural phase transitions in BaCeO3 Knight, K. Solid State Ionics, Vol. 74, Issue 3-4 https://doi.org/10.1016/0167-2738(94)90199-6	journal	December 1994
4f occupation and hybridization from M-shell excitations in Rare-Earth materials Kaindl, G.; Kalkowski, G.; Brewer, W. D. Journal of Magnetism and Magnetic Materials, Vol. 47-48 https://doi.org/10.1016/0304-8853(85)90390-7	journal	February 1985
Determination of mixing of 4f-ligand orbitals in Ce(SO4)2 by Xanes is Ce(SO4)2 a mixed valent insulating system? Bianconi, A.; Marcelli, A.; Tomellini, M. Journal of Magnetism and Magnetic Materials, Vol. 47-48 https://doi.org/10.1016/0304-8853(85)90396-8	journal	February 1985
Quantitative electron energy loss spectroscopy on M45 edges in rare earth oxides Manoubi, T.; Colliex, C.; Rez, P. Journal of Electron Spectroscopy and Related Phenomena, Vol. 50, Issue 1 https://doi.org/10.1016/0368-2048(90)80001-Q	journal	January 1990
Spectroscopic detection of the magnetic phase transition in BaPrO3 Popova, M. N.; Klimin, S. A.; Golubchik, S. A. Physics Letters A, Vol. 211, Issue 4 https://doi.org/10.1016/0375-9601(95)00974-4	journal	February 1996
Valence determination in high Tc oxide superconductors by XANES and Mössbauer spectroscopy Alp, E. E.; Soderholm, L.; Shenoy, G. K. Physica B+C, Vol. 150, Issue 1-2 https://doi.org/10.1016/0378-4363(88)90108-8	journal	May 1988
Magnetic studies on BaUO3, BaPrO3 and BaTbO3 Hinatsu, Yukio Journal of Alloys and Compounds, Vol. 193, Issue 1-2 https://doi.org/10.1016/0925-8388(93)90325-H	journal	March 1993
X-ray absorption study of tetravalent Dy compounds: Cs2RbDyF7 and Cs2KDyF7 Hu, Z.; Kaindl, G.; Vandré, D. Journal of Alloys and Compounds, Vol. 205, Issue 1-2 https://doi.org/10.1016/0925-8388(94)90799-4	journal	March 1994
Determination of the oxidation state of cerium in rocks by Ce LIII-edge X-ray absorption near-edge structure spectroscopy Takahashi, Yoshio; Sakami, Hiroshi; Nomura, Masaharu Analytica Chimica Acta, Vol. 468, Issue 2 https://doi.org/10.1016/S0003-2670(02)00709-2	journal	September 2002
The action of sodium on NdCl3 and PrCl3: mixed valence NaNd2Cl6 and metallic NaPr2Cl6 Schleid, Thomas; Meyer, Gerd Inorganica Chimica Acta, Vol. 140 https://doi.org/10.1016/S0020-1693(00)81063-4	journal	December 1987
Lanthanide thermodynamic predictions. Part III. Enthalpies of formation of lanthanide(IV) compounds Bratsch, Steven; Silber, Herbert B. Inorganica Chimica Acta, Vol. 65 https://doi.org/10.1016/S0020-1693(00)93492-3	journal	January 1982
Crystal chemistry and magnetic structures of Tb(IV) fluorides El-Ghozzi, M.; Avignant, D. Journal of Fluorine Chemistry, Vol. 107, Issue 2 https://doi.org/10.1016/S0022-1139(00)00363-8	journal	February 2001
Room temperature syntheses of lanthanoid tetrafluorides (LnF4, Ln = Ce, Pr, Tb) Mazej, Z. Journal of Fluorine Chemistry, Vol. 118, Issue 1-2 https://doi.org/10.1016/S0022-1139(02)00223-3	journal	December 2002
Comparative study of the crystal—chemical behaviour of Zr4+, Tb4+ and U4+ ions in MF2—M′F4 systems (M = Ca, Sr, Ba, Cd; M′ = Zr, Tb, U) Largeau, E.; El-Ghozzi, M. Journal of Fluorine Chemistry, Vol. 89, Issue 2 https://doi.org/10.1016/S0022-1139(98)00133-X	journal	May 1998
X-ray powder structure of Sr2CeO4: a new luminescent material discovered by combinatorial chemistry Danielson, Earl; Devenney, Martin; Giaquinta, Daniel M. Journal of Molecular Structure, Vol. 470, Issue 1-2 https://doi.org/10.1016/S0022-2860(98)00485-2	journal	October 1998
Resonance paramagnetique et deformation locale dans les complexes de type UF6M Rigny, P.; Dianoux, A. J.; Plurien, P. Journal of Physics and Chemistry of Solids, Vol. 32, Issue 6 https://doi.org/10.1016/S0022-3697(71)80174-9	journal	January 1971
Synthesis and characterization of tetravalent terbium complexes of alkali terbium hexaoxidoiodates Ying, Yang; Ru-Dong, Yang Polyhedron, Vol. 11, Issue 8 https://doi.org/10.1016/S0277-5387(00)83348-3	journal	January 1992
Studies on the stabilization of terbium(IV) in aqueous tetrametaphosphate solution Li, Xiaojing; Dong, Wenji; Qi, Yulang Polyhedron, Vol. 10, Issue 13 https://doi.org/10.1016/S0277-5387(00)86069-6	journal	January 1991
Crystal field and spectrum of Pr4+ in BaPrO3 Popova, M. N.; Klimin, S. A.; Malkin, B. Z. Physics Letters A, Vol. 223, Issue 4 https://doi.org/10.1016/S0375-9601(96)00734-7	journal	December 1996
Synthesis of Sr2PrO4: a Pr4+-containing oxide in the Sr2PbO4 structure type Fiscus, Jeffrey E.; zur Loye, Hans-Conrad Journal of Alloys and Compounds, Vol. 306, Issue 1-2 https://doi.org/10.1016/S0925-8388(00)00785-4	journal	June 2000
X-ray absorption near-edge structure at the LI–III thresholds of Pr, Nd, Sm, and Dy compounds with unusual valences Hu, Zhiwei; Kaindl, Günter; Meyer, Gerd Journal of Alloys and Compounds, Vol. 246, Issue 1-2 https://doi.org/10.1016/S0925-8388(96)02473-5	journal	January 1997
Core-level spectroscopy of the tetravalent lanthanide compounds M3LnF7 (with MCs, Rb; LnCe, Pr, Nd, Tb, Dy) Hu, Zhiwei; Kaindl, G.; Müller, B. G. Journal of Alloys and Compounds, Vol. 246, Issue 1-2 https://doi.org/10.1016/S0925-8388(96)02474-7	journal	January 1997
Electron paramagnetic resonance spectra of Pr4+ ions doped in BaMO3 (M=Ce, Zr, Sn) and SrCeO3 Hinatsu, Yukio; Edelstein, Norman Journal of Alloys and Compounds, Vol. 250, Issue 1-2 https://doi.org/10.1016/S0925-8388(96)02557-1	journal	March 1997
Recent progress in tetravalent terbium chemistry Avignant, D.; Largeau, E.; Gaumet, V. Journal of Alloys and Compounds, Vol. 275-277 https://doi.org/10.1016/S0925-8388(98)00262-X	journal	July 1998
In situ growth, structure, and real-time chemical reactivity of well-defined CeOx-Ru(0001) model surfaces Grinter, David C.; Senanayake, Sanjaya D.; Flege, Jan Ingo Applied Catalysis B: Environmental, Vol. 197 https://doi.org/10.1016/j.apcatb.2016.02.043	journal	November 2016
Mechanism of NO reduction by CO over Pt/SBA-15 Xiao, Ping; Davis, Ryan C.; Ouyang, Xiaoying Catalysis Communications, Vol. 50 https://doi.org/10.1016/j.catcom.2014.02.027	journal	May 2014
Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds Solomon, Edward I.; Hedman, Britt; Hodgson, Keith O. Coordination Chemistry Reviews, Vol. 249, Issue 1-2 https://doi.org/10.1016/j.ccr.2004.03.020	journal	January 2005
Electronic structure of [Ni(II)S4] complexes from S K-edge X-ray absorption spectroscopy Queen, Matt S.; Towey, Bradley D.; Murray, Kevin A. Coordination Chemistry Reviews, Vol. 257, Issue 2 https://doi.org/10.1016/j.ccr.2012.07.020	journal	January 2013
The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis Piro, Nicholas A.; Robinson, Jerome R.; Walsh, Patrick J. Coordination Chemistry Reviews, Vol. 260 https://doi.org/10.1016/j.ccr.2013.08.034	journal	February 2014
Studying low-energy core–valence transitions with bulk sensitivity using q-dependent NIXS Gordon, R. A.; Seidler, G. T.; Fister, T. T. Journal of Electron Spectroscopy and Related Phenomena, Vol. 184, Issue 3-6 https://doi.org/10.1016/j.elspec.2010.12.007	journal	April 2011
A new method of directly determining the core–hole effect in the Ce L3 XAS of mixed valence Ce compounds—An application of resonant X-ray emission spectroscopy Kotani, A.; Kvashnina, K. O.; Butorin, S. M. Journal of Electron Spectroscopy and Related Phenomena, Vol. 184, Issue 3-6 https://doi.org/10.1016/j.elspec.2010.12.028	journal	April 2011
Neutron diffraction study of the magnetic structures of one-dimensional M2TbF6 (M=Li,K,Rb) fluorides: frustration, incommensurability and magnetic interactions Josse, M.; Dubois, M.; El-Ghozzi, M. Journal of Alloys and Compounds, Vol. 374, Issue 1-2 https://doi.org/10.1016/j.jallcom.2003.11.146	journal	July 2004
Crystal structures and magnetic properties of alkali-metal lanthanide oxides A2LnO3 (A=Li, Na; Ln=Ce, Pr, Tb) Hinatsu, Yukio; Doi, Yoshihiro Journal of Alloys and Compounds, Vol. 418, Issue 1-2 https://doi.org/10.1016/j.jallcom.2005.08.100	journal	July 2006
Unusual magnetic behaviour in Sr2PrO4 Hernández-Velasco, J. Journal of Magnetism and Magnetic Materials, Vol. 310, Issue 2 https://doi.org/10.1016/j.jmmm.2006.10.896	journal	March 2007
EasySpin, a comprehensive software package for spectral simulation and analysis in EPR Stoll, Stefan; Schweiger, Arthur Journal of Magnetic Resonance, Vol. 178, Issue 1, p. 42-55 https://doi.org/10.1016/j.jmr.2005.08.013	journal	January 2006
Arene complexation of Sm, Eu, Tm and Yb atoms: a variable temperature spectroscopic investigation Arnold, Polly L.; Petrukhina, Marina A.; Bochenkov, Vladimir E. Journal of Organometallic Chemistry, Vol. 688, Issue 1-2 https://doi.org/10.1016/j.jorganchem.2003.08.028	journal	December 2003
Temperature-induced phase transitions in BaTbO3 Fu, W. T.; Visser, D.; Knight, K. S. Journal of Solid State Chemistry, Vol. 177, Issue 4-5 https://doi.org/10.1016/j.jssc.2003.12.022	journal	April 2004
Magnetic structures of the M2TbF6 (M=Li, K, Rb) fluorides: A complex behavior resulting from frustration Josse, M.; El-Ghozzi, M.; Avignant, D. Journal of Solid State Chemistry, Vol. 180, Issue 5 https://doi.org/10.1016/j.jssc.2007.02.011	journal	May 2007
Magnetic behaviour of the MTbF6 fluoroterbates (M=Cd, Ca, Sr, (α/β)-Ba) Josse, M.; El-Ghozzi, M.; Avignant, D. Journal of Solid State Chemistry, Vol. 185 https://doi.org/10.1016/j.jssc.2011.10.030	journal	January 2012
Single crystal structures of thallium (I) thorium fluorides and crystal chemistry of monovalent tetravalent cation pentafluorides Oudahmane, Abdelghani; El-Ghozzi, Malika; Jouffret, Laurent Journal of Solid State Chemistry, Vol. 232 https://doi.org/10.1016/j.jssc.2015.09.003	journal	December 2015
Small cause – Great effect: What the 4fn+15d0 → 4fn5d1 configuration crossover does to the chemistry of divalent rare-earth halides and coordination compounds Meyer, Gerd Journal of Solid State Chemistry, Vol. 270 https://doi.org/10.1016/j.jssc.2018.10.050	journal	February 2019
Magnetism of Tb4+ ion in fluorides: correlation with crystal-structure Josse, M.; El-Ghozzi, M.; Dubois, M. Physica B: Condensed Matter, Vol. 350, Issue 1-3 https://doi.org/10.1016/j.physb.2004.03.010	journal	July 2004
The antiferromagnetic structure of BaPrO3 Goossens, D. J.; Robinson, R. A.; Telling, M. T. F. Physica B: Condensed Matter, Vol. 352, Issue 1-4 https://doi.org/10.1016/j.physb.2004.06.061	journal	October 2004
Octupolar order in : A specific heat investigation Magnani, N.; Santini, P.; Amoretti, G. Physica B: Condensed Matter, Vol. 359-361 https://doi.org/10.1016/j.physb.2005.01.294	journal	April 2005
X-ray crystal structure of the tetra(tert-butyl)erbate anion and attempts to prepare tetravalent organolanthanide complexes Noh, Wontae; Girolami, Gregory S. Polyhedron, Vol. 26, Issue 14 https://doi.org/10.1016/j.poly.2007.04.006	journal	August 2007
Revealing Electronic Signatures of Lattice Oxygen Redox in Lithium Ruthenates and Implications for High-Energy Li-Ion Battery Material Designs Yu, Yang; Karayaylali, Pinar; Nowak, Stanisław H. Chemistry of Materials, Vol. 31, Issue 19 https://doi.org/10.1021/acs.chemmater.9b01821	journal	September 2019
Fundamentals and Catalytic Applications of CeO ₂ -Based Materials Montini, Tiziano; Melchionna, Michele; Monai, Matteo Chemical Reviews, Vol. 116, Issue 10 https://doi.org/10.1021/acs.chemrev.5b00603	journal	April 2016
Oxygen K-edge X-ray Absorption Spectra Frati, Federica; Hunault, Myrtille O. J. Y.; de Groot, Frank M. F. Chemical Reviews, Vol. 120, Issue 9 https://doi.org/10.1021/acs.chemrev.9b00439	journal	April 2020
Investigation of Praseodymium Fluorides: A Combined Matrix-Isolation and Quantum-Chemical Study Vent-Schmidt, Thomas; Riedel, Sebastian Inorganic Chemistry, Vol. 54, Issue 23 https://doi.org/10.1021/acs.inorgchem.5b01175	journal	November 2015
Rare Earth Metal Complexes of Bidentate Nitroxide Ligands: Synthesis and Electrochemistry Kim, Jee Eon; Bogart, Justin A.; Carroll, Patrick J. Inorganic Chemistry, Vol. 55, Issue 2 https://doi.org/10.1021/acs.inorgchem.5b02236	journal	November 2015
A Macrocyclic Chelator That Selectively Binds Ln ⁴⁺ over Ln ³⁺ by a Factor of 10 ²⁹ Pham, Tiffany A.; Altman, Alison B.; Stieber, S. Chantal E. Inorganic Chemistry, Vol. 55, Issue 20 https://doi.org/10.1021/acs.inorgchem.6b00684	journal	June 2016
Lanthanide Chemistry: From Coordination in Chemical Complexes Shaping Our Technology to Coordination in Enzymes Shaping Bacterial Metabolism Martinez-Gomez, Norma Cecilia; Vu, Huong N.; Skovran, Elizabeth Inorganic Chemistry, Vol. 55, Issue 20 https://doi.org/10.1021/acs.inorgchem.6b00919	journal	September 2016
One-Pot Hydrothermal Synthesis of Tb ^III ₁₃ (GeO ₄ ) ₆ O ₇ (OH) and K ₂ Tb ^IV Ge ₂ O ₇ : Preparation of a Stable Terbium(4+) Complex Fulle, Kyle; Sanjeewa, Liurukara D.; McMillen, Colin D. Inorganic Chemistry, Vol. 56, Issue 11 https://doi.org/10.1021/acs.inorgchem.7b00821	journal	May 2017
Utility of Lithium in Rare-Earth Metal Reduction Reactions to Form Nontraditional Ln ²⁺ Complexes and Unusual [Li(2.2.2-cryptand)] ¹⁺ Cations Huh, Daniel N.; Darago, Lucy E.; Ziller, Joseph W. Inorganic Chemistry, Vol. 57, Issue 4 https://doi.org/10.1021/acs.inorgchem.7b03000	journal	February 2018
Exploration of the Solid- and Solution-State Structures and Electrochemical Properties of Ce ^IV (atrane) Complexes Solola, Lukman A.; Cheisson, Thibault; Yang, Qiaomu Inorganic Chemistry, Vol. 57, Issue 17 https://doi.org/10.1021/acs.inorgchem.8b00712	journal	August 2018
Cerium Tetrakis(tropolonate) and Cerium Tetrakis(acetylacetonate) Are Not Diamagnetic but Temperature-Independent Paramagnets Halbach, Robert L.; Nocton, Grégory; Booth, Corwin H. Inorganic Chemistry, Vol. 57, Issue 12 https://doi.org/10.1021/acs.inorgchem.8b00928	journal	June 2018
Pentavalent Curium, Berkelium, and Californium in Nitrate Complexes: Extending Actinide Chemistry and Oxidation States Kovács, Attila; Dau, Phuong D.; Marçalo, Joaquim Inorganic Chemistry, Vol. 57, Issue 15 https://doi.org/10.1021/acs.inorgchem.8b01450	journal	July 2018
Chelate-Free Synthesis of the U(II) Complex, [(C ₅ H ₃ (SiMe ₃ ) ₂ ) ₃ U] ^1– , Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs Huh, Daniel N.; Ziller, Joseph W.; Evans, William J. Inorganic Chemistry, Vol. 57, Issue 18 https://doi.org/10.1021/acs.inorgchem.8b01966	journal	August 2018
Using Diamagnetic Yttrium and Lanthanum Complexes to Explore Ligand Reduction and C–H Bond Activation in a Tris(aryloxide)mesitylene Ligand System Palumbo, Chad T.; Halter, Dominik P.; Voora, Vamsee K. Inorganic Chemistry, Vol. 57, Issue 20 https://doi.org/10.1021/acs.inorgchem.8b02053	journal	September 2018
Homoleptic Imidophosphorane Stabilization of Tetravalent Cerium Rice, Natalie T.; Su, Jing; Gompa, Thaige P. Inorganic Chemistry, Vol. 58, Issue 8 https://doi.org/10.1021/acs.inorgchem.9b00368	journal	March 2019
Cs ₃ RE ^III Ge ₃ O ₉ (RE = Pr, Nd, and Sm–Yb) and Cs ₈ Tb ^III ₂ Tb ^IV Ge ₉ O ₂₇ : A Rare Example of a Mixed-Valent Tb(III)/Tb(IV) Oxide Morrison, Gregory; Spagnuolo, Nicholas R.; Karakalos, Stavros G. Inorganic Chemistry, Vol. 58, Issue 13 https://doi.org/10.1021/acs.inorgchem.9b01033	journal	June 2019
Understanding the Multiconfigurational Ground and Excited States in Lanthanide Tetrakis Bipyridine Complexes from Experimental and CASSCF Computational Studies Halbach, Robert L.; Nocton, Grégory; Amaro-Estrada, Jorge I. Inorganic Chemistry, Vol. 58, Issue 18 https://doi.org/10.1021/acs.inorgchem.9b01393	journal	August 2019
Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li] ₂ [M(N═C ^t BuPh) ₆ ] (M = Ce, Th) Assefa, Mikiyas K.; Sergentu, Dumitru-Claudiu; Seaman, Lani A. Inorganic Chemistry, Vol. 58, Issue 19 https://doi.org/10.1021/acs.inorgchem.9b01428	journal	September 2019
A Room-Temperature Stable Y(II) Aryloxide: Using Steric Saturation to Kinetically Stabilize Y(II) Complexes Moehring, Samuel A.; Miehlich, Matthias; Hoerger, Christopher J. Inorganic Chemistry, Vol. 59, Issue 5 https://doi.org/10.1021/acs.inorgchem.9b03587	journal	February 2020
Properties of Lanthanide Hydroxide Molecules Produced in Reactions of Lanthanide Atoms with H ₂ O ₂ and H ₂ + O ₂ Mixtures: Roles of the +I, +II, +III, and +IV Oxidation States Wang, Xuefeng; Andrews, Lester; Fang, Zongtang The Journal of Physical Chemistry A, Vol. 121, Issue 8 https://doi.org/10.1021/acs.jpca.6b12607	journal	February 2017
Probing Chemical Bonding in Uranium Dioxide by Means of High-Resolution X-ray Absorption Spectroscopy Butorin, Sergei M.; Modin, Anders; Vegelius, Johan R. The Journal of Physical Chemistry C, Vol. 120, Issue 51 https://doi.org/10.1021/acs.jpcc.6b09335	journal	December 2016
Reactivity of Ln(II) Complexes Supported by (C 5 H 4 Me) 1– Ligands with THF and PhSiH 3 : Isolation of Ring-Opened, Bridging Alkoxyalkyl, Hydride, and Silyl Products Woen, David H.; Huh, Daniel N.; Ziller, Joseph W. Organometallics, Vol. 37, Issue 18 https://doi.org/10.1021/acs.organomet.8b00419	journal	August 2018
Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C ₅ Me ₄ H) ₃ Ln] Complexes Jenkins, Tener F.; Woen, David H.; Mohanam, Luke N. Organometallics, Vol. 37, Issue 21 https://doi.org/10.1021/acs.organomet.8b00557	journal	October 2018
tert -Butyl(cyclopentadienyl) Ligands Will Stabilize Nontraditional +2 Rare-Earth Metal Ions Angadol, Mary A.; Woen, David H.; Windorff, Cory J. Organometallics, Vol. 38, Issue 5 https://doi.org/10.1021/acs.organomet.8b00941	journal	February 2019
Substituted Quinoline Quinones as Surrogates for the PQQ Cofactor: An Electrochemical and Computational Study Dorfner, Walter L.; Carroll, Patrick J.; Schelter, Eric J. Organic Letters, Vol. 17, Issue 8 https://doi.org/10.1021/acs.orglett.5b00486	journal	March 2015
The Chemistry of Lanthanides in Biology: Recent Discoveries, Emerging Principles, and Technological Applications Cotruvo, Joseph A. ACS Central Science, Vol. 5, Issue 9 https://doi.org/10.1021/acscentsci.9b00642	journal	August 2019
Ligand K-Edge X-ray Absorption Spectroscopy: A Direct Probe of Ligand−Metal Covalency Glaser, Thorsten; Hedman, Britt; Hodgson, Keith O. Accounts of Chemical Research, Vol. 33, Issue 12 https://doi.org/10.1021/ar990125c	journal	December 2000
Unusual valences in rare-earth halides Meyer, Gerd; Meyer, H. Juergen Chemistry of Materials, Vol. 4, Issue 6 https://doi.org/10.1021/cm00024a012	journal	November 1992
Cerium L _III -Edge XAS Investigation of the Structure of Crystalline and Amorphous Cerium Oxides Shahin, Ahmed M.; Grandjean, Fernande; Long, Gary J. Chemistry of Materials, Vol. 17, Issue 2 https://doi.org/10.1021/cm0492437	journal	January 2005
Mechanism of Shape Evolution in Ag Nanoprisms Stabilized by Thiol-Terminated Poly(ethylene glycol): An in Situ Kinetic Study Liu, Lijia; Burnyeat, Cheryl A.; Lepsenyi, Reegan S. Chemistry of Materials, Vol. 25, Issue 21 https://doi.org/10.1021/cm401944b	journal	October 2013
Reduced halides of the rare-earth elements Meyer, Gerd Chemical Reviews, Vol. 88, Issue 1 https://doi.org/10.1021/cr00083a005	journal	January 1988
Thermochemical properties of yttrium, lanthanum, and the lanthanide elements and ions Morss, Lester R. Chemical Reviews, Vol. 76, Issue 6 https://doi.org/10.1021/cr60304a007	journal	December 1976
Chemical Redox Agents for Organometallic Chemistry Connelly, Neil G.; Geiger, William E. Chemical Reviews, Vol. 96, Issue 2 https://doi.org/10.1021/cr940053x	journal	January 1996
Praseodymium tetrafluoride Perros, Theodore P.; Munson, Thomas R.; Naeser, Charles R. Journal of Chemical Education, Vol. 30, Issue 8 https://doi.org/10.1021/ed030p402	journal	August 1953
Plutonium(IV) Sequestration: Structural and Thermodynamic Evaluation of the Extraordinarily Stable Cerium(IV) Hydroxypyridinonate Complexes¹ Xu, Jide; Radkov, Emil; Ziegler, Marco Inorganic Chemistry, Vol. 39, Issue 18, p. 4156-4164 https://doi.org/10.1021/ic000063i	journal	September 2000
Ligand K-Edge X-ray Absorption Spectroscopy as a Probe of Ligand-Metal Bonding: Charge Donation and Covalency in Copper-Chloride Systems Shadle, Susan E.; Hedman, Britt; Hodgson, Keith O. Inorganic Chemistry, Vol. 33, Issue 19 https://doi.org/10.1021/ic00097a009	journal	September 1994
Ground States, Excited States, and Metal−Ligand Bonding in Rare Earth Hexachloro Complexes: A DFT-Based Ligand Field Study Atanasov, M.; Daul, C.; Güdel, H. U. Inorganic Chemistry, Vol. 44, Issue 8 https://doi.org/10.1021/ic040105t	journal	April 2005
Synthesis and Characterization of Cerium and Yttrium Alkoxide Complexes Supported by Ferrocene-Based Chelating Ligands Broderick, Erin M.; Thuy-Boun, Peter S.; Guo, Neng Inorganic Chemistry, Vol. 50, Issue 7 https://doi.org/10.1021/ic102076g	journal	April 2011
The Rhenium Tris(dithiolene) Electron Transfer Series: Calibrating Covalency Sproules, Stephen; Weyhermüller, Thomas; Goddard, Richard Inorganic Chemistry, Vol. 50, Issue 24 https://doi.org/10.1021/ic2016534	journal	December 2011
Single Crystal to Single Crystal Transformation and Hydrogen-Atom Transfer upon Oxidation of a Cerium Coordination Compound Williams, Ursula J.; Mahoney, Brian D.; Lewis, Andrew J. Inorganic Chemistry, Vol. 52, Issue 8 https://doi.org/10.1021/ic4001973	journal	March 2013
Solution Thermodynamic Stability of Complexes Formed with the Octadentate Hydroxypyridinonate Ligand 3,4,3-LI(1,2-HOPO): A Critical Feature for Efficient Chelation of Lanthanide(IV) and Actinide(IV) Ions Deblonde, Gauthier J-P.; Sturzbecher-Hoehne, Manuel; Abergel, Rebecca J. Inorganic Chemistry, Vol. 52, Issue 15 https://doi.org/10.1021/ic4010246	journal	July 2013
Homoleptic Cerium(III) and Cerium(IV) Nitroxide Complexes: Significant Stabilization of the 4+ Oxidation State Bogart, Justin A.; Lewis, Andrew J.; Medling, Scott A. Inorganic Chemistry, Vol. 52, Issue 19 https://doi.org/10.1021/ic401974t	journal	September 2013
Reactions of Lanthanide Atoms with Oxygen Difluoride and the Role of the Ln Oxidation State Mikulas, Tanya; Chen, Mingyang; Dixon, David A. Inorganic Chemistry, Vol. 53, Issue 1 https://doi.org/10.1021/ic402422h	journal	December 2013
Rare Earth Metal-Metal Halide Systems. V. Lanthanum, Cerium, and Praseodymium Bromides Sallach, Robert A.; Corbett, John D. Inorganic Chemistry, Vol. 2, Issue 3 https://doi.org/10.1021/ic50007a007	journal	June 1963
Rare Earth Metal-Metal Halide Systems. VI. Praseodymium Chloride Druding, Leonard F.; Corbett, John D.; Ramsey, Bob N. Inorganic Chemistry, Vol. 2, Issue 4 https://doi.org/10.1021/ic50008a055	journal	August 1963
Rare Earth Metal-Metal Halide Systems. IX. The Dysprosium-Dysprosium(III) Chloride System and the Preparation of Dysprosium(II) Chloride Corbett, John D.; McCollum, Bill C. Inorganic Chemistry, Vol. 5, Issue 5 https://doi.org/10.1021/ic50039a050	journal	May 1966
New theoretical and spectral studies of uranium(V) compounds Selbin, J.; Ballhausen, C. J.; Durrett, D. G. Inorganic Chemistry, Vol. 11, Issue 3 https://doi.org/10.1021/ic50109a017	journal	March 1972
Bonding and Charge Transfer in Nitrogen-Donor Uranyl Complexes: Insights from NEXAFS Spectra Pemmaraju, C. D.; Copping, Roy; Wang, Shuao Inorganic Chemistry, Vol. 53, Issue 21 https://doi.org/10.1021/ic501107a	journal	October 2014
Rare earth metal-metal halide systems. XV. Crystal structure of gadolinium sesquichloride. Phase with unique metal chains Lokken, Donald A.; Corbett, John D. Inorganic Chemistry, Vol. 12, Issue 3 https://doi.org/10.1021/ic50121a012	journal	March 1973
Rare earth metal-metal halide systems. XVIII. Holmium-holmium(III) chloride system. Holmium in the divalent state Loechner, Ulrich.; Corbett, John D. Inorganic Chemistry, Vol. 14, Issue 2 https://doi.org/10.1021/ic50144a044	journal	February 1975
Crystal and molecular structures of tetrakis(catecholato)hafnate(IV) and -cerate(IV). Further evidence for a ligand field effect in the structure of tetrakis(catecholato)uranate(IV) Sofen, Stephen R.; Cooper, Stephen R.; Raymond, Kenneth N. Inorganic Chemistry, Vol. 18, Issue 6 https://doi.org/10.1021/ic50196a046	journal	June 1979
A Ligand Field Series for the 4f-Block from Experimental and DFT Computed Ce(IV/III) Electrochemical Potentials Bogart, Justin A.; Lewis, Andrew J.; Boreen, Michael A. Inorganic Chemistry, Vol. 54, Issue 6 https://doi.org/10.1021/ic503000z	journal	February 2015
Covalency Trends in Group IV Metallocene Dichlorides. Chlorine K-Edge X-Ray Absorption Spectroscopy and Time Dependent-Density Functional Theory Kozimor, Stosh A.; Yang, Ping; Batista, Enrique R. Inorganic Chemistry, Vol. 47, Issue 12 https://doi.org/10.1021/ic8004932	journal	June 2008
La ₂ U ₂ Se ₉ : An Ordered Lanthanide/Actinide Chalcogenide with a Novel Structure Type Bugaris, Daniel E.; Copping, Roy; Tyliszczak, Tolek Inorganic Chemistry, Vol. 49, Issue 5 https://doi.org/10.1021/ic902503n	journal	March 2010
Calculated Properties of Lanthanocene Anions and the Unusual Electronic Structure of Their Neutral Counterparts Liu, Wenjian; Dolg, Michael; Fulde, Peter Inorganic Chemistry, Vol. 37, Issue 5 https://doi.org/10.1021/ic9704703	journal	March 1998
X-ray absorption spectroscopic studies of the blue copper site: metal and ligand K-edge studies to probe the origin of the EPR hyperfine splitting in plastocyanin Shadle, Susan E.; Penner-Hahn, James E.; Schugar, Harvey J. Journal of the American Chemical Society, Vol. 115, Issue 2 https://doi.org/10.1021/ja00055a057	journal	January 1993
Ligand K-edge x-ray absorption spectroscopic studies: metal-ligand covalency in a series of transition metal tetrachlorides Shadle, Susan E.; Hedman, Britt; Hodgson, Keith O. Journal of the American Chemical Society, Vol. 117, Issue 8 https://doi.org/10.1021/ja00113a015	journal	March 1995
X-ray absorption edge spectroscopy of ligands bound to open-shell metal ions: chlorine K-edge studies of covalency in tetrachlorocuprate(2-) Hedman, Britt; Hodgson, Keith O.; Solomon, Edward I. Journal of the American Chemical Society, Vol. 112, Issue 4 https://doi.org/10.1021/ja00160a062	journal	February 1990
The Availability of Dysprosium Diiodide as a Powerful Reducing Agent in Organic Synthesis: Reactivity Studies and Structural Analysis of DyI ₂ ((DME) ₃ and Its Naphthalene Reduction Product ¹ Evans, William J.; Allen, Nathan T.; Ziller, Joseph W. Journal of the American Chemical Society, Vol. 122, Issue 47 https://doi.org/10.1021/ja0034949	journal	November 2000
Bis(cyclooctatetraenyl)uranium (uranocene). A new class of sandwich complexes that utilize atomic f orbitals Streitwieser, Andrew.; Mueller-Westerhoff, Ulrich. Journal of the American Chemical Society, Vol. 90, Issue 26 https://doi.org/10.1021/ja01028a044	journal	December 1968
Structure of di-.pi.-cyclooctatetraeneuranium (uranocene) Zalkin, Allan; Raymond, Kenneth N. Journal of the American Chemical Society, Vol. 91, Issue 20 https://doi.org/10.1021/ja01048a055	journal	September 1969
The Heat of Combustion of Cerium ¹ Huber, Elmer J.; Holley, Charles E. Journal of the American Chemical Society, Vol. 75, Issue 22 https://doi.org/10.1021/ja01118a050	journal	November 1953
Heats of Reaction of Some Oxides of Americium and Praseodymium with Nitric Acid and an Estimate of the Potentials of the Am(III)—Am(IV) and Pr(III)—Pr(IV) Couples ¹ Eyring, L.; Lohr, H. R.; Cunningham, B. B. Journal of the American Chemical Society, Vol. 74, Issue 5 https://doi.org/10.1021/ja01125a014	journal	March 1952
Observations on the Fluorination of Praseodymium and Neodymium Compounds Popov, Alexander I.; Glockler, George Journal of the American Chemical Society, Vol. 74, Issue 5 https://doi.org/10.1021/ja01125a521	journal	March 1952
The Preparation of Rare Earth Metals Spedding, F. H.; Daane, A. H. Journal of the American Chemical Society, Vol. 74, Issue 11 https://doi.org/10.1021/ja01131a024	journal	June 1952
The Effect of Fluorine on Praseodymium Trifluoride Perros, Theodore P.; Naeser, Charles R. Journal of the American Chemical Society, Vol. 74, Issue 14 https://doi.org/10.1021/ja01134a509	journal	July 1952
Higher Oxides of the Lanthanide Elements. Terbium Dioxide ¹ Gruen, D. M.; Koehler, W. C.; Katz, J. J. Journal of the American Chemical Society, Vol. 73, Issue 4 https://doi.org/10.1021/ja01148a020	journal	April 1951
An X-Ray Study of the Rare-earth Oxide Systems: Ce ^IV —Nd ^III , Cr ^IV —Pr ^III , Ce ^IV —Pr ^IV and Pr ^IV —Nd ^III1 McCullough, J. D. Journal of the American Chemical Society, Vol. 72, Issue 3 https://doi.org/10.1021/ja01159a085	journal	March 1950
The Separation of Rare Earths by Ion Exchange. ¹ IV. Further Investigations Concerning Variables Involved in the Separation of Samarium, Neodymium and Praseodymium Spedding, F. H.; Fulmer, E. I.; Butler, T. A. Journal of the American Chemical Society, Vol. 72, Issue 6 https://doi.org/10.1021/ja01162a003	journal	June 1950
The Separation of Rare Earths by Ion Exchange. V. Investigations with One-tenth Per Cent. Citric Acid-Ammonium Citrate Solutions ¹ Spedding, F. H.; Fulmer, E. I.; Powell, J. E. Journal of the American Chemical Society, Vol. 72, Issue 6 https://doi.org/10.1021/ja01162a004	journal	June 1950
The Separation of Rare Earths by Ion Exchange. ^1,2 I. Cerium and Yttrium Spedding, F. H.; Voigt, A. F.; Gladrow, E. M. Journal of the American Chemical Society, Vol. 69, Issue 11 https://doi.org/10.1021/ja01203a058	journal	November 1947
The Separation of Rare Earths by Ion Exchange. ^1,2 II. Neodymium and Praseodymium Spedding, F. H.; Voigt, A. F.; Gladrow, E. M. Journal of the American Chemical Society, Vol. 69, Issue 11 https://doi.org/10.1021/ja01203a060	journal	November 1947
The Separation of Rare Earths by Ion Exchange. ¹ III. Pilot Plant Scale Separations Spedding, F. H.; Fulmer, E. I.; Butler, T. A. Journal of the American Chemical Society, Vol. 69, Issue 11 https://doi.org/10.1021/ja01203a063	journal	November 1947
STUDIES ON THE HIGHER OXIDES OF SOME RARE-EARTH ELEMENTS ¹ Pagel, H. Armin; Brinton, Paul H. M. -P. Journal of the American Chemical Society, Vol. 51, Issue 1 https://doi.org/10.1021/ja01376a006	journal	January 1929
Rare Earth Metal-Metal Halide Systems. the Preparation of Neodymium(Ii) Halides Druding, Leonard F.; Corbett, John D. Journal of the American Chemical Society, Vol. 81, Issue 20 https://doi.org/10.1021/ja01529a067	journal	October 1959
Terbium Oxides. II. The Heats of Formation of Several Oxides ¹ Stubblefield, C. T.; Eick, H.; Eyring, L. Journal of the American Chemical Society, Vol. 78, Issue 16 https://doi.org/10.1021/ja01597a005	journal	August 1956
Terbium Tetrafluoride: Preparation and Properties ¹ Cunningham, B. B.; Feay, D. C.; Rollier, M. A. Journal of the American Chemical Society, Vol. 76, Issue 13 https://doi.org/10.1021/ja01642a001	journal	July 1954
Metal and Ligand K-Edge XAS of Organotitanium Complexes: Metal 4p and 3d Contributions to Pre-edge Intensity and Their Contributions to Bonding DeBeer George, Serena; Brant, Patrick; Solomon, Edward I. Journal of the American Chemical Society, Vol. 127, Issue 2 https://doi.org/10.1021/ja044827v	journal	January 2005
Sulfur K-Edge X-ray Absorption Spectroscopy as a Probe of Ligand−Metal Bond Covalency: Metal vs Ligand Oxidation in Copper and Nickel Dithiolene Complexes Sarangi, Ritimukta; DeBeer George, Serena; Rudd, Deanne Jackson Journal of the American Chemical Society, Vol. 129, Issue 8 https://doi.org/10.1021/ja0665949	journal	February 2007
X-ray Absorption Spectroscopic and Computational Investigation of a Possible S···S Interaction in the [Cu ₃ S ₂ ] ³⁺ Core Sarangi, Ritimukta; Yang, Lei; Winikoff, Stuart G. Journal of the American Chemical Society, Vol. 133, Issue 43 https://doi.org/10.1021/ja111323m	journal	November 2011
Synthesis of a Crystalline Molecular Complex of Y ²⁺ , [(18-crown-6)K][(C ₅ H ₄ SiMe ₃ ) ₃ Y] MacDonald, Matthew R.; Ziller, Joseph W.; Evans, William J. Journal of the American Chemical Society, Vol. 133, Issue 40 https://doi.org/10.1021/ja207151y	journal	October 2011
Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl ₆ ^2– (M = Ti, Zr, Hf, U) and UOCl ₅ ^– Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 134, Issue 12 https://doi.org/10.1021/ja2105015	journal	March 2012
Sulfur K-edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory of Dithiophosphinate Extractants: Minor Actinide Selectivity and Electronic Structure Correlations Daly, Scott R.; Keith, Jason M.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 134, Issue 35 https://doi.org/10.1021/ja303999q	journal	August 2012
Covalency in Metal–Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 135, Issue 5 https://doi.org/10.1021/ja310223b	journal	January 2013
Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr ²⁺ , Gd ²⁺ , Tb ²⁺ , and Lu ²⁺ MacDonald, Matthew R.; Bates, Jefferson E.; Ziller, Joseph W. Journal of the American Chemical Society, Vol. 135, Issue 26 https://doi.org/10.1021/ja403753j	journal	May 2013
Carbon K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Examination of Metal–Carbon Bonding in Metallocene Dichlorides Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 135, Issue 39 https://doi.org/10.1021/ja405844j	journal	September 2013
Identification of the +2 Oxidation State for Uranium in a Crystalline Molecular Complex, [K(2.2.2-Cryptand)][(C ₅ H ₄ SiMe ₃ ) ₃ U] MacDonald, Matthew R.; Fieser, Megan E.; Bates, Jefferson E. Journal of the American Chemical Society, Vol. 135, Issue 36 https://doi.org/10.1021/ja406791t	journal	August 2013
Tuning Reactivity and Electronic Properties through Ligand Reorganization within a Cerium Heterobimetallic Framework Robinson, Jerome R.; Gordon, Zachary; Booth, Corwin H. Journal of the American Chemical Society, Vol. 135, Issue 50 https://doi.org/10.1021/ja410688w	journal	December 2013
Influence of Pyrazolate vs N -Heterocyclic Carbene Ligands on the Slow Magnetic Relaxation of Homoleptic Trischelate Lanthanide(III) and Uranium(III) Complexes Meihaus, Katie R.; Minasian, Stefan G.; Lukens, Wayne W. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja501569t	journal	April 2014
Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl ₆ ^{x –} ( x = 3, 2) Löble, Matthias W.; Keith, Jason M.; Altman, Alison B. Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja510067v	journal	February 2015
Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln ²⁺ Ions in the [K(2.2.2-cryptand)][(C ₅ H ₄ SiMe ₃ ) ₃ Ln] Complexes: The Variable Nature of Dy ²⁺ and Nd ²⁺ Fieser, Megan E.; MacDonald, Matthew R.; Krull, Brandon T. Journal of the American Chemical Society, Vol. 137, Issue 1 https://doi.org/10.1021/ja510831n	journal	December 2014
Trends in Covalency for d- and f-Element Metallocene Dichlorides Identified Using Chlorine K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Kozimor, Stosh A.; Yang, Ping; Batista, Enrique R. Journal of the American Chemical Society, Vol. 131, Issue 34 https://doi.org/10.1021/ja9015759	journal	September 2009
The First Example of a Formal Scandium(I) Complex: Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring Arnold, Polly L.; Cloke, F. Geoffrey N.; Hitchcock, Peter B. Journal of the American Chemical Society, Vol. 118, Issue 32 https://doi.org/10.1021/ja961253o	journal	January 1996
The Oxidation State of Ce in the Sandwich Molecule Cerocene Edelstein, N. M.; Allen, P. G.; Bucher, J. J. Journal of the American Chemical Society, Vol. 118, Issue 51 https://doi.org/10.1021/ja962915c	journal	January 1996
Ab Initio Study of Metal−Ring Bonding in the Bis(η ⁶ -benzene)lanthanide and -actinide Complexes M(C ₆ H ₆ ) ₂ (M = La, Ce, Nd, Gd, Tb, Lu, Th, U) Hong, Gongyi; Schautz, Friedemann; Dolg, Michael Journal of the American Chemical Society, Vol. 121, Issue 7 https://doi.org/10.1021/ja9830400	journal	February 1999
Synthesis and Characterization of the First Sandwich Complex of Trivalent Thorium: A Structural Comparison with the Uranium Analogue Parry, Julian S.; Coles, Simon J. Journal of the American Chemical Society, Vol. 121, Issue 29 https://doi.org/10.1021/ja9903633	journal	July 1999
Accessing the +IV Oxidation State in Molecular Complexes of Praseodymium Willauer, Aurélien R.; Palumbo, Chad T.; Fadaei-Tirani, Farzaneh Journal of the American Chemical Society, Vol. 142, Issue 12 https://doi.org/10.1021/jacs.0c01204	journal	March 2020
Record High Single-Ion Magnetic Moments Through 4f ⁿ 5d ¹ Electron Configurations in the Divalent Lanthanide Complexes [(C ₅ H ₄ SiMe ₃ ) ₃ Ln] ⁻ Meihaus, Katie R.; Fieser, Megan E.; Corbey, Jordan F. Journal of the American Chemical Society, Vol. 137, Issue 31 https://doi.org/10.1021/jacs.5b03710	journal	July 2015
Identification of the Formal +2 Oxidation State of Plutonium: Synthesis and Characterization of {Pu ^II [C ₅ H ₃ (SiMe ₃ ) ₂ ] ₃ } ⁻ Windorff, Cory J.; Chen, Guo P.; Cross, Justin N. Journal of the American Chemical Society, Vol. 139, Issue 11 https://doi.org/10.1021/jacs.7b00706	journal	March 2017
Covalency in Americium(III) Hexachloride Cross, Justin N.; Su, Jing; Batista, Enrique R. Journal of the American Chemical Society, Vol. 139, Issue 25 https://doi.org/10.1021/jacs.7b03755	journal	June 2017
Quantitative Evidence for Lanthanide-Oxygen Orbital Mixing in CeO ₂ , PrO ₂ , and TbO ₂ Minasian, Stefan G.; Batista, Enrique R.; Booth, Corwin H. Journal of the American Chemical Society, Vol. 139, Issue 49 https://doi.org/10.1021/jacs.7b10361	journal	November 2017
Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {Np ^II [C ₅ H ₃ (SiMe ₃ ) ₂ ] ₃ } ^1– Su, Jing; Windorff, Cory J.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 140, Issue 24 https://doi.org/10.1021/jacs.8b03907	journal	May 2018
Synthesis and Characterization of a Neutral U(II) Arene Sandwich Complex Billow, Brennan S.; Livesay, Brooke N.; Mokhtarzadeh, Charles C. Journal of the American Chemical Society, Vol. 140, Issue 50 https://doi.org/10.1021/jacs.8b10888	journal	November 2018
Molecular Complex of Tb in the +4 Oxidation State Palumbo, Chad T.; Zivkovic, Ivica; Scopelliti, Rosario Journal of the American Chemical Society, Vol. 141, Issue 25 https://doi.org/10.1021/jacs.9b05337	journal	June 2019
Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II) Gould, Colin A.; McClain, K. Randall; Yu, Jason M. Journal of the American Chemical Society, Vol. 141, Issue 33 https://doi.org/10.1021/jacs.9b05816	journal	August 2019
Design, Isolation, and Spectroscopic Analysis of a Tetravalent Terbium Complex Rice, Natalie T.; Popov, Ivan A.; Russo, Dominic R. Journal of the American Chemical Society, Vol. 141, Issue 33 https://doi.org/10.1021/jacs.9b06622	journal	July 2019
Enthalpies of solution and of formation of several terbium oxides Fitzgibbon, George C.; Holley, Charles E. Journal of Chemical & Engineering Data, Vol. 13, Issue 1 https://doi.org/10.1021/je60036a020	journal	January 1968
Enthalpy of formation of cerium sesquioxide Baker, Floyd B.; Holley, Charles E. Journal of Chemical & Engineering Data, Vol. 13, Issue 3 https://doi.org/10.1021/je60038a031	journal	July 1968
Do f Electrons Play a Role in the Lanthanide−Ligand Bonds? A DFT Study of Ln(NR ₂ ) ₃ ; R = H, SiH ₃ Maron, Laurent; Eisenstein, Odile The Journal of Physical Chemistry A, Vol. 104, Issue 30 https://doi.org/10.1021/jp0010278	journal	August 2000
Low-Temperature Redox Properties of Nanocrystalline Cerium (IV) Oxides Revealed by in Situ XANES Modeshia, Deena R.; Wright, Christopher S.; Payne, Julia L. The Journal of Physical Chemistry C, Vol. 111, Issue 38 https://doi.org/10.1021/jp075410p	journal	September 2007
Estimating Hybridization of Transition Metal and Oxygen States in Perovskites from O K -edge X-ray Absorption Spectroscopy Suntivich, Jin; Hong, Wesley T.; Lee, Yueh-Lin The Journal of Physical Chemistry C, Vol. 118, Issue 4 https://doi.org/10.1021/jp410644j	journal	January 2014
Are the Ground States of the Later Actinocenes Multiconfigurational? All-Electron Spin−Orbit Coupled CASPT2 Calculations on An(η ⁸ -C ₈ H ₈ ) ₂ (An = Th, U, Pu, Cm) Kerridge, Andrew; Kaltsoyannis, Nikolas The Journal of Physical Chemistry A, Vol. 113, Issue 30 https://doi.org/10.1021/jp903912q	journal	July 2009
Characterization of the Reaction Products of Laser-Ablated Early Lanthanide Metal Atoms with Molecular Oxygen. Infrared Spectra of LnO, LnO ⁺ , LnO ^- , LnO ₂ , LnO ₂ ⁺ , LnO ₂ ^- , LnO ₃ ^- , and (LnO) ₂ in Solid Argon Willson, Stephen P.; Andrews, Lester The Journal of Physical Chemistry A, Vol. 103, Issue 17 https://doi.org/10.1021/jp990005m	journal	April 1999
Cerocene Revisited: The Electronic Structure of and Interconversion Between Ce ₂ (C ₈ H ₈ ) ₃ and Ce(C ₈ H ₈ ) ₂ Walter, Marc D.; Booth, Corwin H.; Lukens, Wayne W. Organometallics, Vol. 28, Issue 3 https://doi.org/10.1021/om7012327	journal	February 2009
Chelation and stabilization of berkelium in oxidation state +IV Deblonde, Gauthier J. -P.; Sturzbecher-Hoehne, Manuel; Rupert, Peter B. Nature Chemistry, Vol. 9, Issue 9 https://doi.org/10.1038/nchem.2759	journal	April 2017
The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes Gregson, Matthew; Lu, Erli; Mills, David P. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14137	journal	February 2017
Quantum fluctuations in spin-ice-like Pr2Zr2O7 Kimura, K.; Nakatsuji, S.; Wen, J-J. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2914	journal	June 2013
Ultra-selective ligand-driven separation of strategic actinides Deblonde, Gauthier J. -P.; Ricano, Abel; Abergel, Rebecca J. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-10240-x	journal	June 2019
Experimental signatures of a three-dimensional quantum spin liquid in effective spin-1/2 Ce2Zr2O7 pyrochlore Gao, Bin; Chen, Tong; Tam, David W. Nature Physics, Vol. 15, Issue 10 https://doi.org/10.1038/s41567-019-0577-6	journal	July 2019
Transition-Metal Doped Ceria Microspheres with Nanoporous Structures for CO Oxidation Zhou, Lin; Li, Xiaoxiao; Yao, Ze Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep23900	journal	March 2016
Synthesis of bis(η-1,3,5-tri-t-butylbenzene) sandwich complexes of yttrium(0) and gadolinium(0); the X-ray crystal structure of the first authentic lanthanide(0) complex, [Gd(η-Bu ^t ₃ C ₆ H ₃ ) ₂ ] Brennan, John G.; Cloke, F. Geoffrey N.; Sameh, Ausama A. J. Chem. Soc., Chem. Commun., Issue 21 https://doi.org/10.1039/C39870001668	journal	January 1987
On the stability and bonding in bis(η-arene)ianthanide complexes Anderson, David M.; Cloke, F. Geoffrey N.; Cox, P. Anthony J. Chem. Soc., Chem. Commun., Issue 1 https://doi.org/10.1039/C39890000053	journal	January 1989
η-Arene complexes of scandium(0) and scandium( II ) Cloke, F. Geoffrey N.; Khan, Karl; Perutz, Robin N. J. Chem. Soc., Chem. Commun., Issue 19 https://doi.org/10.1039/C39910001372	journal	January 1991
New evidence for 5f covalency in actinocenes determined from carbon K-edge XAS and electronic structure theory Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R. Chem. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/C3SC52030G	journal	January 2014
Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C ₅ H ₃ (SiMe ₃ ) ₂ ] ₃ Th} ¹⁻ anion containing thorium in the formal +2 oxidation state Langeslay, Ryan R.; Fieser, Megan E.; Ziller, Joseph W. Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/C4SC03033H	journal	January 2015
Synthesis and hydrolysis of gas-phase lanthanide and actinide oxide nitrate complexes: a correspondence to trivalent metal ion redox potentials and ionization energies Lucena, Ana F.; Lourenço, Célia; Michelini, Maria C. Physical Chemistry Chemical Physics, Vol. 17, Issue 15 https://doi.org/10.1039/C5CP00515A	journal	January 2015
The nature of chemical bonding in actinide and lanthanide ferrocyanides determined by X-ray absorption spectroscopy and density functional theory Dumas, Thomas; Guillaumont, Dominique; Fillaux, Clara Physical Chemistry Chemical Physics, Vol. 18, Issue 4 https://doi.org/10.1039/C5CP05820A	journal	January 2016
Control of cerium oxidation state through metal complex secondary structures Levin, Jessica R.; Dorfner, Walter L.; Carroll, Patrick J. Chemical Science, Vol. 6, Issue 12 https://doi.org/10.1039/C5SC02607E	journal	January 2015
Evidence for 5d-σ and 5d-π covalency in lanthanide sesquioxides from oxygen K-edge X-ray absorption spectroscopy Altman, Alison B.; Pacold, Joseph I.; Wang, Jian Dalton Transactions, Vol. 45, Issue 24 https://doi.org/10.1039/C6DT00358C	journal	January 2016
Pentavalent lanthanide nitride-oxides: NPrO and NPrO ⁻ complexes with NPr triple bonds Hu, Shu-Xian; Jian, Jiwen; Su, Jing Chemical Science, Vol. 8, Issue 5 https://doi.org/10.1039/C7SC00710H	journal	January 2017
Evaluating the electronic structure of formal Ln ^II ions in Ln ^II (C ₅ H ₄ SiMe ₃ ) ₃ ¹⁻ using XANES spectroscopy and DFT calculations Fieser, Megan E.; Ferrier, Maryline G.; Su, Jing Chemical Science, Vol. 8, Issue 9 https://doi.org/10.1039/C7SC00825B	journal	January 2017
Comparisons of lanthanide/actinide +2 ions in a tris(aryloxide)arene coordination environment Fieser, Megan E.; Palumbo, Chad T.; La Pierre, Henry S. Chem. Sci., Vol. 8, Issue 11 https://doi.org/10.1039/C7SC02337E	journal	January 2017
Exploring the electronic structure and speciation of aqueous and colloidal Pu with high energy resolution XANES and computations Vitova, Tonya; Pidchenko, Ivan; Fellhauer, David Chemical Communications, Vol. 54, Issue 91 https://doi.org/10.1039/C8CC06889E	journal	January 2018
Isolation of U( ii ) compounds using strong donor ligands, C ₅ Me ₄ H and N(SiMe ₃ ) ₂ , including a three-coordinate U( ii ) complex Ryan, Austin J.; Angadol, Mary A.; Ziller, Joseph W. Chemical Communications, Vol. 55, Issue 16 https://doi.org/10.1039/C8CC08767A	journal	January 2019
Rare-earth metal and actinide organoimide chemistry Schädle, Dorothea; Anwander, Reiner Chemical Society Reviews, Vol. 48, Issue 24 https://doi.org/10.1039/C8CS00932E	journal	January 2019
Impact of the lanthanide contraction on the activity of a lanthanide-dependent methanol dehydrogenase – a kinetic and DFT study Lumpe, Henning; Pol, Arjan; Op den Camp, Huub J. M. Dalton Transactions, Vol. 47, Issue 31 https://doi.org/10.1039/C8DT01238E	journal	January 2018
Isolation of reactive Ln( ii ) complexes with C ₅ H ₄ Me ligands (Cp ^Me ) using inverse sandwich countercations: synthesis and structure of [(18-crown-6)K(μ-Cp ^Me )K(18-crown-6)][Cp ^Me ₃ Ln ^II ] (Ln = Tb, Ho) Huh, Daniel N.; Ziller, Joseph W.; Evans, William J. Dalton Transactions, Vol. 47, Issue 48 https://doi.org/10.1039/C8DT03890B	journal	January 2018
Scrutinizing metal–ligand covalency and redox non-innocence via nitrogen K-edge X-ray absorption spectroscopy Lukens, James T.; DiMucci, Ida M.; Kurogi, Takashi Chemical Science, Vol. 10, Issue 19 https://doi.org/10.1039/C8SC03350A	journal	January 2019
Differential uranyl( v ) oxo-group bonding between the uranium and metal cations from groups 1, 2, 4, and 12; a high energy resolution X-ray absorption, computational, and synthetic study Zegke, Markus; Zhang, Xiaobin; Pidchenko, Ivan Chemical Science, Vol. 10, Issue 42 https://doi.org/10.1039/C8SC05717F	journal	January 2019
Chemical evidence of the stability of praseodymium( v ) in gas-phase oxide nitrate complexes Monteiro, Bernardo; Bandeira, Nuno A. G.; Lourenço, Célia Chemical Communications, Vol. 55, Issue 94 https://doi.org/10.1039/C9CC08006F	journal	January 2019
Dicerium letterbox-shaped tetraphenolates: f-block complexes designed for two-electron chemistry Arnold, Polly L.; Wang, Kai; Gray, Steven J. Dalton Transactions, Vol. 49, Issue 3 https://doi.org/10.1039/C9DT03291F	journal	January 2020
The duality of electron localization and covalency in lanthanide and actinide metallocenes Smiles, Danil E.; Batista, Enrique R.; Booth, Corwin H. Chemical Science, Vol. 11, Issue 10 https://doi.org/10.1039/C9SC06114B	journal	January 2020
The first structurally authenticated zerovalent heteroarene complex of a lanthanide; synthesis and X-ray structure of bis(2,4,6-tri-tert-butyl- phosphorin)holmium(O) Arnold, Polly L.; Cloke, F. Geoffrey N.; Hitchcock, Peter B. Chemical Communications, Issue 5 https://doi.org/10.1039/a607827c	journal	January 1997
Synthesis and single-crystal structural study of an original low-temperatureform α of BaTbF6 Largeau, Eric; Gaumet, Vincent; El-Ghozzi, Malika Journal of Materials Chemistry, Vol. 7, Issue 9 https://doi.org/10.1039/a701615h	journal	January 1997
The first stable scandocene: synthesis and characterisation of bis(η-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II) Arnold, Polly L.; Cloke, F. Geoffrey N.; Nixon, John F. Chemical Communications, Issue 7 https://doi.org/10.1039/a800089a	journal	January 1998
Structural transitions and conductivity of BaPrO3 and BaPr0.9Y0.1O3−δ Knee, Christopher S.; Magrasó, Anna; Norby, Truls Journal of Materials Chemistry, Vol. 19, Issue 20 https://doi.org/10.1039/b820976f	journal	January 2009
Direct study of the f-electron configuration in lanthanide systems Kvashnina, Kristina O.; Butorin, Sergei M.; Glatzel, Pieter Journal of Analytical Atomic Spectrometry, Vol. 26, Issue 6 https://doi.org/10.1039/c0ja00142b	journal	January 2011
Zero oxidation state compounds of scandium, yttrium, and the lanthanides Cloke, F. Geoffrey N. Chemical Society Reviews, Vol. 22, Issue 1 https://doi.org/10.1039/cs9932200017	journal	January 1993
Large-scale separation of rare-earth salts and the preparation of the pure metals Spedding, Frank H. Discussions of the Faraday Society, Vol. 7 https://doi.org/10.1039/df9490700214	journal	January 1949
5. Rare-earth metal oxides. Part I. The direct oxidation of praseodymium and terbium sesquioxides Marsh, Joseph K. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9460000015	journal	January 1946
Neutron Crystal‐Field Spectroscopy in Rare‐Earth Metallic Compounds Turberfield, K. C.; Passell, L.; Birgeneau, R. J. Journal of Applied Physics, Vol. 42, Issue 4 https://doi.org/10.1063/1.1660422	journal	March 1971
Free Ion 4fn Levels of the Tetravalent Lanthanides. Fluorescence and Absorption Spectra of Cesium Dysprosium (IV) Heptafluoride Varga, Louis P.; Asprey, Larned B. The Journal of Chemical Physics, Vol. 48, Issue 1 https://doi.org/10.1063/1.1664459	journal	January 1968
Electronic Spectra of Weak‐Field Fluoride Complexes of Tetravalent Neodymium Varga, Louis P.; Asprey, Larned B. The Journal of Chemical Physics, Vol. 49, Issue 10 https://doi.org/10.1063/1.1669929	journal	November 1968
Paramagnetic Resonance Absorption in Neptunium Hexafluoride Hutchison, Clyde A.; Weinstock, Bernard The Journal of Chemical Physics, Vol. 32, Issue 1 https://doi.org/10.1063/1.1700947	journal	January 1960
M ‐edge x‐ray absorption spectroscopy of 4 f instabilities in rare‐earth systems (invited) Kaindl, G.; Kalkowski, G.; Brewer, W. D. Journal of Applied Physics, Vol. 55, Issue 6 https://doi.org/10.1063/1.333517	journal	March 1984
Thermodynamic and magnetic properties of the tetravalent rare‐earth perovskite system BaPrO ₃ Cao, G.; Yuen, Tan; Pernambuco‐Wise, P. Journal of Applied Physics, Vol. 70, Issue 10 https://doi.org/10.1063/1.349959	journal	November 1991
Magnetic properties of the Tb ⁴⁺ ion in Li ₂ TbF ₆ Guillot, M.; El‐Ghozzi, M.; Avignant, D. Journal of Applied Physics, Vol. 73, Issue 10 https://doi.org/10.1063/1.353741	journal	May 1993
Spectrum analysis of U 3+ :LaCl 3 Crosswhite, H. M.; Crosswhite, H.; Carnall, W. T. The Journal of Chemical Physics, Vol. 72, Issue 9 https://doi.org/10.1063/1.439742	journal	May 1980
Effective core potential methods for the lanthanides Cundari, Thomas R.; Stevens, Walter J. The Journal of Chemical Physics, Vol. 98, Issue 7 https://doi.org/10.1063/1.464902	journal	April 1993
The Thermodynamic Properties of the f -Elements and their Compounds. Part 2. The Lanthanide and Actinide Oxides Konings, Rudy J. M.; Beneš, Ondrej; Kovács, Attila Journal of Physical and Chemical Reference Data, Vol. 43, Issue 1 https://doi.org/10.1063/1.4825256	journal	March 2014
Towards 10 meV resolution: The design of an ultrahigh resolution soft X-ray RIXS spectrometer Dvorak, Joseph; Jarrige, Ignace; Bisogni, Valentina Review of Scientific Instruments, Vol. 87, Issue 11 https://doi.org/10.1063/1.4964847	journal	November 2016
High-resolution X-ray absorption spectroscopy as a probe of crystal-field and covalency effects in actinide compounds Butorin, Sergei M.; Kvashnina, Kristina O.; Vegelius, Johan R. Proceedings of the National Academy of Sciences, Vol. 113, Issue 29 https://doi.org/10.1073/pnas.1601741113	journal	July 2016
Water Gas Shift Catalysis Ratnasamy, Chandra; Wagner, Jon P. Catalysis Reviews, Vol. 51, Issue 3 https://doi.org/10.1080/01614940903048661	journal	September 2009
The Inorganic Crystal Structure Database (ICSD)—Present and Future Hellenbrandt, Mariette Crystallography Reviews, Vol. 10, Issue 1 https://doi.org/10.1080/08893110410001664882	journal	January 2004
Voronoi–dirichlet polyhedra in crystal chemistry: theory and applications Blatov *, Vladislav A. Crystallography Reviews, Vol. 10, Issue 4 https://doi.org/10.1080/08893110412331323170	journal	October 2004
V. M. Goldschmidt: Geochemische Verteilungsgesetze der Elemente Beskow, Gunnar Geologiska Föreningen i Stockholm Förhandlingar, Vol. 46, Issue 6-7 https://doi.org/10.1080/11035892409454037	journal	December 1924
Paramagnetic resonance of Tb4+ in zircon Hutton, D. R.; Milne, R. J. Journal of Physics C: Solid State Physics, Vol. 2, Issue 12 https://doi.org/10.1088/0022-3719/2/12/313	journal	December 1969
Some magnetic properties of BaPrO ₃ and BaTbO ₃ : the magnetic form factor for Tb ⁴⁺ by neutron diffraction Tofield, B. C.; Jacobson, A. J.; Fender, B. E. F. Journal of Physics C: Solid State Physics, Vol. 5, Issue 20 https://doi.org/10.1088/0022-3719/5/20/008	journal	October 1972
Paramagnetic Resonance Hyperfine Structure of Tetravalent Pa 231 in Cs 2 Zr Cl 6 Axe, J. D.; Stapleton, H. J.; Jeffries, C. D. Physical Review, Vol. 121, Issue 6 https://doi.org/10.1103/PhysRev.121.1630	journal	March 1961
Resonant inelastic x-ray scattering investigation of the crystal-field splitting of Sm 3 + in SmB 6 Amorese, Andrea; Stockert, Oliver; Kummer, Kurt Physical Review B, Vol. 100, Issue 24 https://doi.org/10.1103/PhysRevB.100.241107	journal	December 2019
f -count effects in x-ray-absorption spectra of the 3 d levels in Ce and its intermetallic compounds Fuggle, J. C.; Hillebrecht, F. U.; Esteva, J. -M. Physical Review B, Vol. 27, Issue 8 https://doi.org/10.1103/PhysRevB.27.4637	journal	April 1983
Crystal-field transitions in f -electron oxides Kern, S.; Loong, C. -K.; Lander, G. H. Physical Review B, Vol. 32, Issue 5 https://doi.org/10.1103/PhysRevB.32.3051	journal	September 1985
3d x-ray-absorption lines and the 3 d 9 4 f n + 1 multiplets of the lanthanides Thole, B. T.; van der Laan, G.; Fuggle, J. C. Physical Review B, Vol. 32, Issue 8 https://doi.org/10.1103/PhysRevB.32.5107	journal	October 1985
Specific intermediate-valence state of insulating 4 f compounds detected by L 3 x-ray absorption Bianconi, A.; Marcelli, A.; Dexpert, H. Physical Review B, Vol. 35, Issue 2 https://doi.org/10.1103/PhysRevB.35.806	journal	January 1987
X-ray absorption studies of CeO 2 , PrO 2 , and TbO 2 . II. Rare-earth valence state by L III absorption edges Dexpert, H.; Karnatak, R. C.; Esteva, J. -M. Physical Review B, Vol. 36, Issue 3 https://doi.org/10.1103/PhysRevB.36.1750	journal	July 1987
4 f -ligand hybridization in CeF 4 and TbF 4 probed by core-level spectroscopies Kalkowski, G.; Kaindl, G.; Wortmann, G. Physical Review B, Vol. 37, Issue 3 https://doi.org/10.1103/PhysRevB.37.1376	journal	January 1988
Pressure-induced changes in L III x-ray-absorption near-edge structure of Ce O 2 and Ce F 4 : Relevance to 4 f -electronic structure Kaindl, G.; Schmiester, G.; Sampathkumaran, E. V. Physical Review B, Vol. 38, Issue 14 https://doi.org/10.1103/PhysRevB.38.10174	journal	November 1988
Effect of valence mixing on multiplet structure in core photoabsorption spectra for Ce compounds Jo, T.; Kotani, A. Physical Review B, Vol. 38, Issue 1 https://doi.org/10.1103/PhysRevB.38.830	journal	July 1988
Magnetic ordering and superconductivity in Y 1 − x Pr x Ba 2 Cu 3 O 7 − y Kebede, A.; Jee, C. S.; Schwegler, J. Physical Review B, Vol. 40, Issue 7 https://doi.org/10.1103/PhysRevB.40.4453	journal	September 1989
L III -edge spectroscopy on cerium-based intermediate-valent compounds Malterre, D. Physical Review B, Vol. 43, Issue 2 https://doi.org/10.1103/PhysRevB.43.1391	journal	January 1991
Crystal-field splittings and magnetic properties of Pr 3 + and Nd 3 + in R Ba 2 Cu 3 O 7 Soderholm, L.; Loong, C. -K.; Goodman, G. L. Physical Review B, Vol. 43, Issue 10 https://doi.org/10.1103/PhysRevB.43.7923	journal	April 1991
Antiferromagnetic ordering of BaPrO 3 via neutron diffraction Rosov, N.; Lynn, J. W.; Lin, Q. Physical Review B, Vol. 45, Issue 2 https://doi.org/10.1103/PhysRevB.45.982	journal	January 1992
X-ray-absorption study of PrO 2 at high pressure Hu, Z.; Bertram, S.; Kaindl, G. Physical Review B, Vol. 49, Issue 1 https://doi.org/10.1103/PhysRevB.49.39	journal	January 1994
Valency and 4 f covalency of Cs 2 RbTbF 7 Hu, Z.; Cho, En-Jin; Kaindl, G. Physical Review B, Vol. 51, Issue 12 https://doi.org/10.1103/PhysRevB.51.7514	journal	March 1995
XANES study of rare-earth valency in L Ru 4 P 12 ( L = Ce and Pr) Lee, C. H.; Oyanagi, H.; Sekine, C. Physical Review B, Vol. 60, Issue 19 https://doi.org/10.1103/PhysRevB.60.13253	journal	November 1999
Resonant inelastic x-ray scattering at the L 3 edge of samarium Gallet, J. -J.; Mariot, J. -M.; Journel, L. Physical Review B, Vol. 60, Issue 20 https://doi.org/10.1103/PhysRevB.60.14128	journal	November 1999
Valence determination as a function of doping in PrBa 2 Cu 3 O 7 Staub, U.; Soderholm, L.; Wasserman, S. R. Physical Review B, Vol. 61, Issue 2 https://doi.org/10.1103/PhysRevB.61.1548	journal	January 2000
Cerium L III − edge x-ray absorption study of the Ce x Fe 4 − y Co y Sb 12 skutterudites Grandjean, Fernande; Long, Gary J.; Cortes, Robert Physical Review B, Vol. 62, Issue 19 https://doi.org/10.1103/PhysRevB.62.12569	journal	November 2000
Jahn-Teller effect on PrO 2 : A multimode vibronic model Bevilacqua, G.; Ippolito, D.; Martinelli, L. Physical Review B, Vol. 69, Issue 15 https://doi.org/10.1103/PhysRevB.69.155208	journal	April 2004
Cooperative Jahn-Teller distortion in PrO 2 Gardiner, C. H.; Boothroyd, A. T.; Pattison, P. Physical Review B, Vol. 70, Issue 2 https://doi.org/10.1103/PhysRevB.70.024415	journal	July 2004
Field-induced magnetic and structural domain alignment in PrO 2 Gardiner, C. H.; Boothroyd, A. T.; McKelvy, M. J. Physical Review B, Vol. 70, Issue 2 https://doi.org/10.1103/PhysRevB.70.024416	journal	July 2004
Perturbative approach to J mixing in f -electron systems: Application to actinide dioxides Magnani, N.; Santini, P.; Amoretti, G. Physical Review B, Vol. 71, Issue 5 https://doi.org/10.1103/PhysRevB.71.054405	journal	February 2005
Influence of static Jahn-Teller distortion on the magnetic excitation spectrum of Pr O 2 : A synchrotron x-ray and neutron inelastic scattering study Webster, C. H.; Helme, L. M.; Boothroyd, A. T. Physical Review B, Vol. 76, Issue 13 https://doi.org/10.1103/PhysRevB.76.134419	journal	October 2007
Static and dynamic Jahn-Teller effects and antiferromagnetic order in Pr O 2 : A mean-field analysis Jensen, Jens Physical Review B, Vol. 76, Issue 14 https://doi.org/10.1103/PhysRevB.76.144428	journal	October 2007
Templating rare-earth hybridization via ultrahigh vacuum annealing of ErCl 3 nanowires inside carbon nanotubes Ayala, Paola; Kitaura, Ryo; Nakanishi, Ryo Physical Review B, Vol. 83, Issue 8 https://doi.org/10.1103/PhysRevB.83.085407	journal	February 2011
Core and shallow-core d - to f -shell excitations in rare-earth metals Bradley, J. A.; Moore, K. T.; van der Laan, G. Physical Review B, Vol. 84, Issue 20 https://doi.org/10.1103/PhysRevB.84.205105	journal	November 2011
Electronic structure of EuN: Growth, spectroscopy, and theory Richter, J. H.; Ruck, B. J.; Simpson, M. Physical Review B, Vol. 84, Issue 23 https://doi.org/10.1103/PhysRevB.84.235120	journal	December 2011
4 f electron delocalization and volume collapse in praseodymium metal Bradley, Joseph A.; Moore, Kevin T.; Lipp, Magnus J. Physical Review B, Vol. 85, Issue 10 https://doi.org/10.1103/PhysRevB.85.100102	journal	March 2012
Crystal-Field Splitting and Correlation Effect on the Electronic Structure of A 2 IrO 3 Gretarsson, H.; Clancy, J. P.; Liu, X. Physical Review Letters, Vol. 110, Issue 7 https://doi.org/10.1103/PhysRevLett.110.076402	journal	February 2013
M -Edge X-Ray Absorption Spectroscopy: A New Tool for Dilute Mixed-Valent Materials Kaindl, G.; Brewer, W. D.; Kalkowski, G. Physical Review Letters, Vol. 51, Issue 22 https://doi.org/10.1103/PhysRevLett.51.2056	journal	November 1983
Spectroscopic Evidence for Localized and Extended f -Symmetry States in Ce O 2 Wuilloud, E.; Delley, B.; Schneider, W. -D. Physical Review Letters, Vol. 53, Issue 2 https://doi.org/10.1103/PhysRevLett.53.202	journal	July 1984
Mixed valency versus covalency in rare-earth core-electron spectroscopy Kaindl, G.; Wertheim, G. K.; Schmiester, G. Physical Review Letters, Vol. 58, Issue 6 https://doi.org/10.1103/PhysRevLett.58.606	journal	February 1987
Self-Contained Kondo Effect in Single Molecules Booth, C. H.; Walter, M. D.; Daniel, M. Physical Review Letters, Vol. 95, Issue 26 https://doi.org/10.1103/PhysRevLett.95.267202	journal	December 2005
Multipolar interactions in f -electron systems: The paradigm of actinide dioxides Santini, Paolo; Carretta, Stefano; Amoretti, Giuseppe Reviews of Modern Physics, Vol. 81, Issue 2 https://doi.org/10.1103/RevModPhys.81.807	journal	June 2009
VESTA : a three-dimensional visualization system for electronic and structural analysis Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 41, Issue 3 https://doi.org/10.1107/S0021889808012016	journal	May 2008
Caesium Pentafluoroterbate, CsTbF ₅ Gaumet, V.; Avignant, D. Acta Crystallographica Section C Crystal Structure Communications, Vol. 53, Issue 9 https://doi.org/10.1107/S0108270197005556	journal	September 1997
Crystal space analysis by means of Voronoi–Dirichlet polyhedra Blatov, V. A.; Shevchenko, A. P.; Serenzhkin, V. N. Acta Crystallographica Section A Foundations of Crystallography, Vol. 51, Issue 6 https://doi.org/10.1107/S0108767395006799	journal	November 1995
Anti-KSbF ₆ structure of CaTbF ₆ and CdTbF ₆ : a confirmation of the singular crystal chemistry of Tb ⁴⁺ in fluorides Josse, Michaël; Dubois, Marc; El-Ghozzi, Malika Acta Crystallographica Section B Structural Science, Vol. 61, Issue 1 https://doi.org/10.1107/S0108768104026928	journal	January 2005
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
The crystal structure of rubidium hexafluoroprotactinate(V), RbPaF6 Burns, J. H.; Levy, H. A.; Keller Jnr, O. L. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 24, Issue 12 https://doi.org/10.1107/S0567740868004838	journal	December 1968
The structures of BaCeO3, BaPrO3 and BaTbO3 by neutron diffraction: lattice parameter relations and ionic radii in O-perovskites Jacobson, A. J.; Tofield, B. C.; Fender, B. E. F. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 3 https://doi.org/10.1107/S0567740872003462	journal	March 1972
A note on the crystal and magnetic structure of BaTbO3 Banks, E.; La Placa, S. J.; Kunnmann, W. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 28, Issue 11 https://doi.org/10.1107/S0567740872008052	journal	November 1972
High-temperature monoclinic α-SrHfF ₆ , and isostructural α-SrZrF ₆ : associating Hf ₂ F ₁₂ bipolyhedra and SrF ₈ snub disphenoids Laval, Jean-Paul; Mayet, Richard Acta Crystallographica Section C Structural Chemistry, Vol. 74, Issue 2 https://doi.org/10.1107/S2053229618001110	journal	January 2018
Rare earth metals are essential for methanotrophic life in volcanic mudpots: Rare earth metals essential for methanotrophic life Pol, Arjan; Barends, Thomas R. M.; Dietl, Andreas Environmental Microbiology, Vol. 16, Issue 1 https://doi.org/10.1111/1462-2920.12249	journal	September 2013
Core electron energy loss spectroscopy of cerium: Surface oxidation Strasser, Gregor; Netzer, Falko P. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 2, Issue 2 https://doi.org/10.1116/1.572516	journal	April 1984
Coordination polyhedra LnFn (Ln = La-Lu) in crystal structures Vologzhanina, A. V.; Pushkin, D. V.; Serezhkin, V. N. Russian Journal of Inorganic Chemistry, Vol. 51, Issue 5 https://doi.org/10.1134/S0036023606050123	journal	May 2006
Ground configuration splitting in UCl ₅ Leung, A. F.; Poon, Ying-Ming Canadian Journal of Physics, Vol. 55, Issue 10 https://doi.org/10.1139/p77-125	journal	May 1977
Soft-X-ray Magnetic Circular Dichroism under Pulsed High Magnetic Fields at Eu M _4,5 Edges of Mixed Valence Compound EuNi ₂ (Si _0.18 Ge _0.82 ) ₂ Nakamura, Tetsuya; Hirono, Toko; Kinoshita, Toyohiko Journal of the Physical Society of Japan, Vol. 81, Issue 10 https://doi.org/10.1143/JPSJ.81.103705	journal	October 2012
Energies of the Electronic Configurations of the Singly, Doubly, and Triply Ionized Lanthanides and Actinides Brewer, Leo Journal of the Optical Society of America, Vol. 61, Issue 12 https://doi.org/10.1364/JOSA.61.001666	journal	January 1971
EPR Studies of Tb 4+ in Single Crystals of Zircon and Scheelite Structure Silicates and Germanates Hansen, S.; Mosel, B. D.; Müller-Warmuth, W. Zeitschrift für Naturforschung A, Vol. 51, Issue 8 https://doi.org/10.1515/zna-1996-0801	journal	January 1996
Spectroelectrochemical Studies of the Actinides: Stabilization of Americium(IV) in Aqueous Carbonate Solution Hobart, D. E.; Samhoun, K.; Peterson, J. R. Radiochimica Acta, Vol. 31, Issue 3-4 https://doi.org/10.1524/ract.1982.31.34.139	journal	January 1982
Formation Enthalpies of Tetravalent Lanthanide Perovskites by High Temperature Oxide Melt Solution Calorimetry Ushakov, S. V.; Cheng, J.; Navrotsky, A. MRS Proceedings, Vol. 718 https://doi.org/10.1557/PROC-718-D7.17	journal	January 2002
Theoretical Modelling of High-Resolution X-Ray Absorption Spectra at Uranium M ₄ Edge Kolorenč, Jindřich; Kvashnina, Kristina O. MRS Advances, Vol. 3, Issue 53 https://doi.org/10.1557/adv.2018.470	journal	January 2018

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