Role of the metal-support interface in the hydrodeoxygenation reaction of phenol

Teles, Camila A.; Rabelo-Neto, Raimundo C.; Duong, Nhung; Quiroz, Jhon; Camargo, Pedro H. C.; Jacobs, Gary; Resasco, Daniel E.; Noronha, Fábio B.

doi:10.1016/j.apcatb.2020.119238

Role of the metal-support interface in the hydrodeoxygenation reaction of phenol

Journal Article · Mon Jun 15 00:00:00 EDT 2020 · Applied Catalysis B: Environmental

DOI:https://doi.org/10.1016/j.apcatb.2020.119238· OSTI ID:1850247

Teles, Camila A. ^[1]; ^[2]; Duong, Nhung ^[3]; Quiroz, Jhon ^[4]; ^[4]; ^[5]; ^[6]; ^[7]

National Inst. of Technology, Rio de Janeiro (Brazil). Catalysis Division; Military Inst. of Engineering, Rio de Janeiro, (Brazil). Chemical Engineering Dept.; National Inst. of Technology, Rio de Janeiro (Brazil)
National Inst. of Technology, Rio de Janeiro (Brazil). Catalysis Division
Univ. of Oklahoma, Norman, OK (United States). School of Chemical, Biological and Materials Engineering. Center for Biomass refining
Univ. of Helsinki (Finland). Dept. of Chemistry
Univ. of Texas at San Antonio, TX (United States). Dept. of Biomedical Engineering and Chemical Engineering; Univ. of Texas at San Antonio, TX (United States). Dept. of Mechanical Engineering
Univ. of Oklahoma, Norman, OK (United States). School of Chemical, Biological and Materials Engineering. Center for Biomass refining
National Inst. of Technology, Rio de Janeiro (Brazil). Catalysis Division; Military Inst. of Engineering, Rio de Janeiro, (Brazil). Chemical Engineering Dept.

In this paper, the effect of interfacial sites between Pd particles and Nb₂O₅ species is investigated by testing a series of Pd-Nb₂O₅/SiO₂ catalysts with different niobium loadings for the HDO reaction of phenol in the gas phase. Important differences in the selectivity to deoxygenated product were observed depending on the presence of niobium oxide close to Pd particles, which reveals the key role of the type of active phase in the control of reaction steps. It was found that Pd/SiO₂ catalyst promotes hydrogenation pathways, producing cyclohexanone as the major product. For Pd-Nb₂O₅/SiO₂ catalyst containing a Nb/Pd molar ratio of 0.5, a sharp increase in the selectivity to benzene is observed (7.5-fold). Increasing the Nb/Pd molar ratio, the formation of benzene is enhanced. The results showed that the Pd-Nb₂O₅ interface, composed by an oxophilic oxide in the perimeter of the metal particle, is responsible for the activation of the Csingle bondO bond, promoting the deoxygenation reaction.

View Accepted Manuscript (DOE)

Research Organization:: University of Oklahoma, Norman, OK (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: FG36-08GO88064

OSTI ID:: 1850247

Alternate ID(s):: OSTI ID: 1778301

Journal Information:: Applied Catalysis B: Environmental, Journal Name: Applied Catalysis B: Environmental Journal Issue: C Vol. 277; ISSN 0926-3373

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

09 BIOMASS FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
42 ENGINEERING
Bio-oil
Chemistry
Engineering
Hydrodeoxygenation
Metal-support interface
Niobia
Phenol

Role of the metal-support interface in the hydrodeoxygenation reaction of phenol

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