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Metal–organic frameworks based on multicarboxylate linkers

Journal Article · · Coordination Chemistry Reviews
 [1];  [2];  [2];  [3];  [2];  [3];  [4]
  1. Tarbiat Modares Univ., Tehran (Iran). Faculty of Sciences. Dept. of Chemistry; Tarbiat Modares Univ., Tehran (Iran)
  2. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
  3. Tarbiat Modares Univ., Tehran (Iran). Faculty of Sciences. Dept. of Chemistry
  4. Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry; Texas A & M Univ., College Station, TX (United States). Dept. of Materials Science and Engineering
+ Show Author Affiliations

When designing metal–organic frameworks (MOFs), linker design is one of the most important factors in constructing a wide variety of structures. Judicious choice of linker size, geometry, and connectivity can create diverse structures and topologies, which can aid in the quest to design MOFs with both high stability and permanent porosity. Multi-connected linkers have become a focus in the MOF community, as high connectivity can improve stability and tunability of frameworks. In particular, multicarboxylate ligands have been reported extensively in the literature to construct stable MOFs with versatile pore environments, which can be termed as metal-multicarboxylate frameworks (MMCFs). These structures have great application potential in gas adsorption and separation, catalysis, and sensing. In this work, we review the literature on multicarboxylate linkers (nCOOH ≥ 3) in MOF systems and their applications, with specific emphasis on how high linker connectivity affects properties of MOFs such as topology, porosity, stability, and functionality.

Research Organization:
Texas A & M Univ., College Station, TX (United States); Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE); USDOE Office of Science (SC), Basic Energy Sciences (BES); Robert A. Welch Foundation; National Science Foundation (NSF)
Grant/Contract Number:
FE0026472; SC0001015
OSTI ID:
1849173
Alternate ID(s):
OSTI ID: 1656658
Journal Information:
Coordination Chemistry Reviews, Journal Name: Coordination Chemistry Reviews Journal Issue: C Vol. 426; ISSN 0010-8545
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

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High Volumetric Hydrogen Adsorption in a Porous Anthracene-Decorated Metal–Organic Framework journal September 2018
Chitosan Immobilization on Bio-MOF Nanostructures: A Biocompatible pH-Responsive Nanocarrier for Doxorubicin Release on MCF-7 Cell Lines of Human Breast Cancer journal October 2018
A Stable Zr(IV)-Based Metal–Organic Framework Constructed from C═C Bridged Di-isophthalate Ligand for Sensitive Detection of Cr 2 O 7 2– in Water journal November 2018
Linker Competition within a Metal–Organic Framework for Topological Insights journal December 2018
Facilitating Laboratory Research Experience Using Reticular Chemistry journal July 2018
Water-Stable Anionic Metal–Organic Framework for Highly Selective Separation of Methane from Natural Gas and Pyrolysis Gas journal April 2016
A Highly Stable 3D Luminescent Indium–Polycarboxylic Framework for the Turn-off Detection of UO 2 2+ , Ru 3+ , and Biomolecule Thiamines journal October 2016
Boosted Sensor Performance by Surface Modification of Bifunctional rht -Type Metal–Organic Framework with Nanosized Electrochemically Reduced Graphene Oxide journal January 2017
New rht -Type Metal–Organic Frameworks Decorated with Acylamide Groups for Efficient Carbon Dioxide Capture and Chemical Fixation from Raw Power Plant Flue Gas journal November 2016
Development of a Porous Coordination Polymer with a High Gas Capacity Using a Thiophene-Based Bent Tetracarboxylate Ligand journal April 2017
Hydrolytically Stable Luminescent Cationic Metal Organic Framework for Highly Sensitive and Selective Sensing of Chromate Anions in Natural Water Systems journal May 2017
Highly Stable and Regenerative Metal–Organic Framework Designed by Multiwalled Divider Installation Strategy for Detection of Co(II) Ions and Organic Aromatics in Water journal August 2016
Detoxification of a Sulfur Mustard Simulant Using a BODIPY-Functionalized Zirconium-Based Metal–Organic Framework journal July 2017
A Copper(II)-Paddlewheel Metal–Organic Framework with Exceptional Hydrolytic Stability and Selective Adsorption and Detection Ability of Aniline in Water journal August 2017
Resorcin[4]arene-Based Microporous Metal–Organic Framework as an Efficient Catalyst for CO 2 Cycloaddition with Epoxides and Highly Selective Luminescent Sensing of Cr 2 O 7 2– journal October 2017
New Metal–Organic Frameworks for Chemical Fixation of CO 2 journal December 2017
Reticular Chemistry and the Discovery of a New Family of Rare Earth (4, 8)-Connected Metal-Organic Frameworks with csq Topology Based on RE 4 (μ 3 -O) 2 (COO) 8 Clusters journal December 2017
Honeycomb Metal–Organic Framework with Lewis Acidic and Basic Bifunctional Sites: Selective Adsorption and CO 2 Catalytic Fixation journal March 2018
Zr(IV)-Based Metal-Organic Framework with T-Shaped Ligand: Unique Structure, High Stability, Selective Detection, and Rapid Adsorption of Cr 2 O 7 2– in Water journal May 2018
Tuning Water Sorption in Highly Stable Zr(IV)-Metal–Organic Frameworks through Local Functionalization of Metal Clusters journal July 2018
Lewis Acid Activation of a Hydrogen Bond Donor Metal–Organic Framework for Catalysis journal April 2016
Enhanced Uptake and Selectivity of CO 2 Adsorption in a Hydrostable Metal–Organic Frameworks via Incorporating Methylol and Methyl Groups journal September 2014
Studies on Metal–Organic Frameworks of Cu(II) with Isophthalate Linkers for Hydrogen Storage journal October 2013
The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets journal December 2008
A Novel Five-Connected BN Topological Network Metal−Organic Framework Mn(II) Cluster Complex journal March 2007
Microporous La(III) Metal−Organic Framework Using a Semirigid Tricarboxylic Ligand: Synthesis, Single-Crystal to Single-Crystal Sorption Properties, and Gas Adsorption Studies journal August 2010
Coordination Polymers of 5-(2-Amino/Acetamido-4-carboxyphenoxy)-benzene-1,3-dioic Acids with Transition Metal Ions: Synthesis, Structure, and Catalytic Activity journal June 2011
Syntheses, Structures, Photoluminescence, and Gas Adsorption of Rare Earth–Organic Frameworks Based on a Flexible Tricarboxylate journal December 2011
Two Solvent-Dependent Zinc(II) Supramolecular Isomers: Rare kgd and Lonsdaleite Network Topologies Based on a Tripodal Flexible Ligand journal December 2011
Two Large-Pore Metal–Organic Frameworks Derived from a Single Polytopic Strut journal February 2012
Impact of Alkyl-Functionalized BTC on Properties of Copper-Based Metal–Organic Frameworks journal June 2012
Structural Diversity for a Series of Novel Zn Metal–Organic Frameworks Based on Different Secondary Building Units journal July 2012
Two Novel 3d-4f Heterometallic Frameworks Assembled from a Flexible Bifunctional Macrocyclic Ligand journal August 2012
Structural Diversity and Properties of Coordination Polymers Built from a Rigid Octadentenate Carboxylic Acid journal November 2012
Synthesis, Characterization, and Adsorption Studies of Nickel(II), Zinc(II), and Magnesium(II) Coordination Frameworks of BTTB journal February 2013
Structure Versatility of Coordination Polymers Constructed from a Semirigid Tetracarboxylate Ligand: Syntheses, Structures, and Photoluminescent Properties journal December 2012
Single- and Double-Layer Structures and Sorption Properties of Two Microporous Metal–Organic Frameworks with Flexible Tritopic Ligand journal March 2013
A Doubly Interpenetrated Metal–Organic Framework with Open Metal Sites and Suitable Pore Sizes for Highly Selective Separation of Small Hydrocarbons at Room Temperature journal April 2013
Tuning the Moisture and Thermal Stability of Metal–Organic Frameworks through Incorporation of Pendant Hydrophobic Groups journal September 2013
Luminescent Response of One Anionic Metal–Organic Framework Based on Novel Octa-nuclear Zinc Cluster to Exchanged Cations journal January 2014
Microporous Heptazine Functionalized (3,24)-Connected rht -Metal–Organic Framework: Synthesis, Structure, and Gas Sorption Analysis journal January 2014
Metallacarborane-Based Metal–Organic Framework with a Complex Topology journal January 2014
Secondary Building Unit (SBU) Controlled Formation of a Catalytically Active Metal–Organic Polyhedron (MOP) Derived from a Flexible Tripodal Ligand journal January 2014
Two Metal–Organic Frameworks with a Tetratopic Linker: Solvent-Dependent Polymorphism and Postsynthetic Bromination journal March 2014
Solvent-Induced Single Crystal To Single Crystal Transformation and Complete Metal Exchange of a Pyrene-Based Metal–Organic Framework journal March 2014
Crystal Structures and Properties of Cd(II) Coordination Polymers Supported by a New Chiral Aromatic Polycarboxylate Ligand journal March 2014
Two Copper(II) Metal–Organic Frameworks with Nanoporous Channels and Vacant Coordination Sites journal May 2014
Three Porphyrin-Encapsulating Metal–Organic Materials with Ordered Metalloporphyrin Moieties journal March 2014
Two Series of Solvent-Dependent Lanthanide Coordination Polymers Demonstrating Tunable Luminescence and Catalysis Properties journal May 2014
Luminescent Anionic Metal–Organic Framework with Potential Nitrobenzene Sensing journal May 2014
Fluorescent Dodecapus in 3D Framework journal August 2014
Control of Metal–Organic Framework Crystal Topology by Ligand Functionalization: Functionalized HKUST-1 Derivatives journal October 2014
Syntheses, Crystal Structures, and Properties of Two 2-Fold Interpenetrating Metal–Organic Frameworks Based on a Trigonal Rigid Ligand journal October 2014
Structural Diversity Modulated by the Ratios of a Ternary Solvent Mixture: Syntheses, Structures, and Luminescent Properties of Five Zinc(II) Metal–Organic Frameworks journal February 2015
Construction and Characterization of Several New Lanthanide−Organic Frameworks: From 2D Lattice to 2D Double-Layer and to Porous 3D Net with Interweaving Triple-Stranded Helixes journal June 2008
Syntheses, Structures, Near-Infrared, and Visible Luminescence of Lanthanide-Organic Frameworks with Flexible Macrocyclic Polyamine Ligands journal April 2008
Novel Inorganic–Organic Hybrid Frameworks of Manganese(II): Syntheses, Crystal Structures, and Physical Properties journal May 2008
Syntheses, Structures, and Photoluminescence of Four d 10 Metal−Organic Frameworks Constructed from 3,5-Bis-oxyacetate-benzoic Acid journal August 2008
(4,4) Rectangular Lattices of Cobalt(II) with 1,2,4,5-Benzenetetracarboxylic Acid: Influence of the Packing in the Crystal Structure journal September 2008
Structure, Hydrogen Storage, and Luminescence Properties of Three 3D Metal−Organic Frameworks with NbO and PtS Topologies journal June 2008
Employing La 2 - (La = Eu, Tb, Pr) or Co 3 -Based Molecule Building Blocks To Construct 3,8-Connected Nets: Hydrothermal Synthesis, Structure, Luminescence, and Magnetic Properties journal May 2008
A Series of Three-Dimensional Lanthanide Coordination Compounds with the Rutile Topology journal December 2008
Two Metal-Carboxylate Frameworks Featuring Uncommon 2D + 3D and 3-Fold-Interpenetration: (3,5)-Connected Isomeric hms and gra Nets journal March 2009
Coordination Chemistry of Cyclohexane-1,2,4,5-tetracarboxylate (H 4 L ). Synthesis, Structure, and Magnetic Properties of Metal-Organic Frameworks with Conformation-Flexible H 4 L Ligand journal March 2009
Coordination Polymers Versus Metal−Organic Frameworks journal July 2009
A Porous Polyhedral Metal-Organic Framework Based on Zn 2 (COO) 3 and Zn 2 (COO) 4 SBUs journal May 2009
Structural Transitions and Flexibility during Dehydration−Rehydration Process in the MOF-type Aluminum Pyromellitate Al 2 (OH) 2 [C 10 O 8 H 2 ] (MIL-118) journal June 2009
Synthesis and Stability of Tagged UiO-66 Zr-MOFs journal December 2010
Robust Metal–Organic Framework with An Octatopic Ligand for Gas Adsorption and Separation: Combined Characterization by Experiments and Molecular Simulation journal December 2011
Aqueous Molecular Sieving and Strong Gas Adsorption in Highly Porous MOFs with a Facile Synthesis journal December 2012
Carborane-Based Metal–Organic Framework with High Methane and Hydrogen Storage Capacities journal August 2013
Isoreticular Series of (3,24)-Connected Metal–Organic Frameworks: Facile Synthesis and High Methane Uptake Properties journal February 2014
Computational Design of Metal–Organic Frameworks Based on Stable Zirconium Building Units for Storage and Delivery of Methane journal September 2014
Hysteretic Gas and Vapor Sorption in Flexible Interpenetrated Lanthanide-Based Metal–Organic Frameworks with Coordinated Molecular Gating via Reversible Single-Crystal-to-Single-Crystal Transformation for Enhanced Selectivity journal February 2015
Metal−Organic Frameworks Based on Double-Bond-Coupled Di-Isophthalate Linkers with High Hydrogen and Methane Uptakes journal May 2008
Metal–Organic Frameworks for Separations journal September 2011
Topological Analysis of Metal–Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the Minimal Transitivity Principle journal November 2013
Water Stability and Adsorption in Metal–Organic Frameworks journal September 2014
A New Porous Three-Dimensional Lanthanide Coordination Polymer journal July 2000
Photoluminescent Metal−Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates journal February 2003
(10,3)-a Noninterpenetrated Network Built from a Piedfort Ligand Pair journal March 2006
Construction of Robust Open Metal−Organic Frameworks with Chiral Channels and Permanent Porosity journal April 2007
Metal−Organic Frameworks from Copper Dimers with cis - and trans -1,4-Cyclohexanedicarboxylate and cis,cis -1,3,5-Cyclohexanetricarboxylate journal July 2007
Three-Dimensional Metal−Organic Frameworks Based on Tetrahedral and Square-Planar Building Blocks: Hydrogen Sorption and Dye Uptake Studies journal October 2010
3-D Coordination Polymers Based on the Tetrathiafulvalenetetracarboxylate (TTF-TC) Derivative: Synthesis, Characterization, and Oxidation Issues journal August 2010
Porous Anionic, Cationic, and Neutral Metal-Carboxylate Frameworks Constructed from Flexible Tetrapodal Ligands: Syntheses, Structures, Ion-Exchanges, and Magnetic Properties journal March 2011
Functional Mesoporous Metal−Organic Frameworks for the Capture of Heavy Metal Ions and Size-Selective Catalysis journal December 2010
Pore with Gate: Enhancement of the Isosteric Heat of Adsorption of Dihydrogen via Postsynthetic Cation Exchange in Metal−Organic Frameworks journal October 2011
Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals journal September 2011
An Interpenetrated Metal–Organic Framework and Its Gas Storage Behavior: Simulation and Experiment journal November 2011
Pressure-Responsive Curvature Change of a “Rigid” Geodesic Ligand in a (3,24)-Connected Mesoporous Metal–Organic Framework journal November 2011
A Highly Porous Interpenetrated Metal–Organic Framework from the Use of a Novel Nanosized Organic Linker journal November 2011
Microwave-Assisted Synthesis of a Series of Lanthanide Metal–Organic Frameworks and Gas Sorption Properties journal January 2012
Highly Porous 4,8-Connected Metal–Organic Frameworks: Synthesis, Characterization, and Hydrogen Uptake journal January 2012
3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials journal February 2012
Synthesis, Structures, and Properties of Two Three-Dimensional Metal–Organic Frameworks, Based on Concurrent Ligand Extension journal June 2012
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks journal June 2012
Comparison of the Effect of Functional Groups on Gas-Uptake Capacities by Fixing the Volumes of Cages A and B and Modifying the Inner Wall of Cage C in rht-Type MOFs journal September 2012
Expanded Porous MOF-505 Analogue Exhibiting Large Hydrogen Storage Capacity and Selective Carbon Dioxide Adsorption journal March 2013
A Route to Metal–Organic Frameworks through Framework Templating journal January 2013
Luminescent Triarylboron-Functionalized Zinc Carboxylate Metal–Organic Framework journal January 2013
Porous and Robust Lanthanide Metal-Organoboron Frameworks as Water Tolerant Lewis Acid Catalysts journal September 2013
Design and Synthesis of Two Porous Metal–Organic Frameworks with nbo and agw Topologies Showing High CO 2 Adsorption Capacity journal September 2013
Metastable Interwoven Mesoporous Metal–Organic Frameworks journal September 2013
Gas Sorption, Second-Order Nonlinear Optics, and Luminescence Properties of a Series of Lanthanide–Organic Frameworks Based on Nanosized Tris((4-carboxyl)phenylduryl)amine Ligand journal October 2013
Structural Dynamism and Controlled Chemical Blocking/Unblocking of Active Coordination Space of a Soft Porous Crystal journal October 2013
Color Tuning and White Light Emission via in Situ Doping of Luminescent Lanthanide Metal–Organic Frameworks journal December 2013
Versatile Mesoporous Dy III Coordination Framework for Highly Efficient Trapping of Diverse Pollutants journal June 2014
Deprotonation-Triggered Stokes Shift Fluorescence of an Unexpected Basic-Stable Metal–Organic Framework journal December 2014
Synthesis of Two Triarylboron-Functionalized Metal–Organic Frameworks: In Situ Decarboxylic Reaction, Structure, Photoluminescence, and Gas Adsorption Properties journal September 2014
Homochiral Metal–Organic Frameworks with Enantiopure Proline Units for the Catalytic Synthesis of β-Lactams journal October 2014
Solvent Templates Induced Porous Metal–Organic Materials: Conformational Isomerism and Catalytic Activity journal January 2015
A New Design Strategy to Access Zwitterionic Metal–Organic Frameworks from Anionic Viologen Derivates journal January 2015
Dual-Functionalized Metal–Organic Frameworks Constructed from Hexatopic Ligand for Selective CO 2 Adsorption journal February 2015
Hydrothermal Synthesis, Structures, and Photoluminescent Properties of Benzenepentacarboxylate Bridged Networks Incorporating Zinc(II)−Hydroxide Clusters or Zinc(II)−Carboxylate Layers journal January 2008
3D Metal−Organic Frameworks Based on Elongated Tetracarboxylate Building Blocks for Hydrogen Storage journal May 2008
Tetravalent Silicon Connectors Me n Si( p -C 6 H 4 CO 2 H) 4− n ( n = 0, 1, 2) for the Construction of Metal−Organic Frameworks journal October 2008
Three-Dimensional Metal-Organic Frameworks Based on Functionalized Tetracarboxylate Linkers: Synthesis, Strucures, and Gas Sorption Studies journal March 2009
Conformation Preference of a Flexible Cyclohexanetetracarboxylate Ligand in Three New Metal-Organic Frameworks: Structures, Magnetic and Luminescent Properties journal July 2009
Highly Porous Metal-Organic Framework Containing a Novel Organosilicon Linker − A Promising Material for Hydrogen Storage journal July 2009
Interpenetrating Polyhedral MOF with a Primitive Cubic Network Based on Supermolecular Building Blocks Constructed of a Semirigid C 3 -Symmetric Carboxylate Ligand journal September 2009
A Large-Surface-Area Boracite-Network-Topology Porous MOF Constructed from a Conjugated Ligand Exhibiting a High Hydrogen Uptake Capacity journal July 2009
Synthesis and Gas Sorption Properties of a Metal-Azolium Framework (MAF) Material journal November 2009
A Twofold Interpenetrating Porous Metal−Organic Framework with High Hydrothermal Stability: Structure and Gas Sorption Behavior journal November 2009
Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels journal October 1995
Cu2(ATC)·6H2O:  Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC:  1,3,5,7-Adamantane Tetracarboxylate) journal November 2000
Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures journal August 2001
Tertiary Building Units:  Synthesis, Structure, and Porosity of a Metal−Organic Dendrimer Framework (MODF-1) October 2001
Cu2[o-Br-C6H3(CO2)2]2(H2O)2·(DMF)8(H2O)2:  A Framework Deliberately Designed To Have the NbO Structure Type journal January 2002
Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn 4 O(NTB) 2 ] journal May 2005
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units journal February 2005
A 3D Canted Antiferromagnetic Porous Metal−Organic Framework with Anatase Topology through Assembly of an Analogue of Polyoxometalate journal November 2005
An Interweaving MOF with High Hydrogen Uptake journal March 2006
MIL-96, a Porous Aluminum Trimesate 3D Structure Constructed from a Hexagonal Network of 18-Membered Rings and μ 3 -Oxo-Centered Trinuclear Units journal August 2006
A Metal−Organic Framework with Entatic Metal Centers Exhibiting High Gas Adsorption Affinity journal September 2006
Synthesis of MIL-102, a Chromium Carboxylate Metal−Organic Framework, with Gas Sorption Analysis journal November 2006
A Mesoporous Metal−Organic Framework with Permanent Porosity journal December 2006
Framework-Catenation Isomerism in Metal−Organic Frameworks and Its Impact on Hydrogen Uptake journal February 2007
An Illustration of the Limit of the Metal Organic Framework's Isoreticular Principle Using a Semirigid Tritopic Linker Obtained by “Click” Chemistry journal October 2007
Porous Crystal Derived from a Tricarboxylate Linker with Two Distinct Binding Motifs journal December 2007
Metal-Organic Framework from an Anthracene Derivative Containing Nanoscopic Cages Exhibiting High Methane Uptake journal January 2008
Supermolecular Building Blocks (SBBs) and Crystal Design:  12-Connected Open Frameworks Based on a Molecular Cubohemioctahedron journal February 2008
Metal−Organic Polyhedral Frameworks: High H 2 Adsorption Capacities and Neutron Powder Diffraction Studies journal March 2010
Linker-Directed Vertex Desymmetrization for the Production of Coordination Polymers with High Porosity journal October 2010
Enhanced CO 2 Binding Affinity of a High-Uptake rht -Type Metal−Organic Framework Decorated with Acylamide Groups journal February 2011
Immobilization of MP-11 into a Mesoporous Metal–Organic Framework, MP-11@mesoMOF: A New Platform for Enzymatic Catalysis journal July 2011
Three-Dimensional Porous Metal–Metalloporphyrin Framework Consisting of Nanoscopic Polyhedral Cages journal October 2011
The Quest for Modular Nanocages: tbo -MOF as an Archetype for Mutual Substitution, Functionalization, and Expansion of Quadrangular Pillar Building Blocks journal September 2011
A Chiral Porous Metal–Organic Framework for Highly Sensitive and Enantioselective Fluorescence Sensing of Amino Alcohols journal May 2012
Designing Higher Surface Area Metal–Organic Frameworks: Are Triple Bonds Better Than Phenyls? journal June 2012
Porous Metalloporphyrinic Frameworks Constructed from Metal 5,10,15,20-Tetrakis(3,5-biscarboxylphenyl)porphyrin for Highly Efficient and Selective Catalytic Oxidation of Alkylbenzenes journal June 2012
Photoactive Chiral Metal–Organic Frameworks for Light-Driven Asymmetric α-Alkylation of Aldehydes journal August 2012
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? journal August 2012
High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework journal July 2012
Conformational Locking by Design: Relating Strain Energy with Luminescence and Stability in Rigid Metal–Organic Frameworks journal November 2012
An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence journal September 2013
Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination journal October 2013
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials journal March 2014
Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement journal May 2014
High Methane Storage Capacity in Aluminum Metal–Organic Frameworks journal February 2014
Stepwise Synthesis of Robust Metal–Organic Frameworks via Postsynthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation journal May 2014
Facile Control of the Charge Density and Photocatalytic Activity of an Anionic Indium Porphyrin Framework via in Situ Metalation journal October 2014
A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology journal December 2014
Topology-Guided Design and Syntheses of Highly Stable Mesoporous Porphyrinic Zirconium Metal–Organic Frameworks with High Surface Area journal December 2014
Introduction of Functionality, Selection of Topology, and Enhancement of Gas Adsorption in Multivariate Metal–Organic Framework-177 journal February 2015
Structure-Assisted Functional Anchor Implantation in Robust Metal–Organic Frameworks with Ultralarge Pores journal January 2015
Two-Photon Responsive Metal–Organic Framework journal March 2015
Ultrahigh Surface Area Zirconium MOFs and Insights into the Applicability of the BET Theory journal March 2015
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
journal October 2008
High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites journal February 2009
Metathesis in Single Crystal: Complete and Reversible Exchange of Metal Ions Constituting the Frameworks of Metal−Organic Frameworks journal March 2009
Highly Porous and Robust 4,8-Connected Metal−Organic Frameworks for Hydrogen Storage journal April 2009
A Multifunctional 3D Ferroelectric and NLO-Active Porous Metal−Organic Framework journal May 2009
Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows journal July 2009
A Guest-Responsive Fluorescent 3D Microporous Metal−Organic Framework Derived from a Long-Lifetime Pyrene Core
  • Stylianou, Kyriakos C.; Heck, Romain; Chong, Samantha Y.
  • Journal of the American Chemical Society, Vol. 132, Issue 12, p. 4119-4130 https://doi.org/10.1021/ja906041f
journal March 2010
Net-Clipping: An Approach to Deduce the Topology of Metal–Organic Frameworks Built with Zigzag Ligands journal May 2020
Systematic Ligand Modulation Enhances the Moisture Stability and Gas Sorption Characteristics of Quaternary Metal–Organic Frameworks journal March 2015
Quest for Highly Connected Metal–Organic Framework Platforms: Rare-Earth Polynuclear Clusters Versatility Meets Net Topology Needs journal April 2015
Ultrastable Polymolybdate-Based Metal–Organic Frameworks as Highly Active Electrocatalysts for Hydrogen Generation from Water journal May 2015
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes journal June 2015
Piezofluorochromic Metal–Organic Framework: A Microscissor Lift journal August 2015
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide journal October 2015
Ultraporous, Water Stable, and Breathing Zirconium-Based Metal–Organic Frameworks with ftw Topology journal September 2015
Reticular Synthesis of HKUST-like tbo-MOFs with Enhanced CH 4 Storage journal January 2016
Non-Interpenetrated Metal–Organic Frameworks Based on Copper(II) Paddlewheel and Oligoparaxylene-Isophthalate Linkers: Synthesis, Structure, and Gas Adsorption journal March 2016
A Triazole-Containing Metal–Organic Framework as a Highly Effective and Substrate Size-Dependent Catalyst for CO 2 Conversion journal February 2016
Size-Controlled Synthesis of Porphyrinic Metal–Organic Framework and Functionalization for Targeted Photodynamic Therapy journal March 2016
Observation of Binding and Rotation of Methane and Hydrogen within a Functional Metal–Organic Framework journal July 2016
Förster Energy Transport in Metal–Organic Frameworks Is Beyond Step-by-Step Hopping journal January 2016
Seed-Mediated Synthesis of Metal–Organic Frameworks journal January 2016
Highly Stable Zr(IV)-Based Metal–Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water journal May 2016
Encapsulation of a Nerve Agent Detoxifying Enzyme by a Mesoporous Zirconium Metal–Organic Framework Engenders Thermal and Long-Term Stability journal June 2016
Highly Porous Zirconium Metal–Organic Frameworks with β-UH 3 -like Topology Based on Elongated Tetrahedral Linkers journal June 2016
A New Approach to Non-Coordinating Anions: Lewis Acid Enhancement of Porphyrin Metal Centers in a Zwitterionic Metal–Organic Framework journal August 2016
Metal–Organic Frameworks Stabilize Mono(phosphine)–Metal Complexes for Broad-Scope Catalytic Reactions journal July 2016
Reticular Chemistry at Its Best: Directed Assembly of Hexagonal Building Units into the Awaited Metal-Organic Framework with the Intricate Polybenzene Topology, pbz-MOF journal September 2016
1D-2D-3D Transformation Synthesis of Hierarchical Metal–Organic Framework Adsorbent for Multicomponent Alkane Separation journal January 2017
Applying the Power of Reticular Chemistry to Finding the Missing alb-MOF Platform Based on the (6,12)-Coordinated Edge-Transitive Net journal February 2017
A Fine-Tuned Metal–Organic Framework for Autonomous Indoor Moisture Control journal July 2017
Porous Metal–Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storage journal September 2017
Boosting Chemical Stability, Catalytic Activity, and Enantioselectivity of Metal–Organic Frameworks for Batch and Flow Reactions journal September 2017
Modulating the Performance of an Asymmetric Organocatalyst by Tuning Its Spatial Environment in a Metal–Organic Framework journal September 2017
Systematic Engineering of Single Substitution in Zirconium Metal–Organic Frameworks toward High-Performance Catalysis journal December 2017
Control the Structure of Zr-Tetracarboxylate Frameworks through Steric Tuning journal November 2017
Unusual and Tunable Negative Linear Compressibility in the Metal–Organic Framework MFM-133(M) (M = Zr, Hf) journal February 2018
Acid-Resistant Mesoporous Metal–Organic Framework toward Oral Insulin Delivery: Protein Encapsulation, Protection, and Release journal April 2018
Topology-Guided Stepwise Insertion of Three Secondary Linkers in Zirconium Metal–Organic Frameworks journal May 2018
Enriching the Reticular Chemistry Repertoire: Merged Nets Approach for the Rational Design of Intricate Mixed-Linker Metal–Organic Framework Platforms journal June 2018
A Flexible Metal–Organic Framework with 4-Connected Zr 6 Nodes journal August 2018
Optimal Binding of Acetylene to a Nitro-Decorated Metal–Organic Framework journal October 2018
Creating Well-Defined Hexabenzocoronene in Zirconium Metal–Organic Framework by Postsynthetic Annulation journal January 2019
Reticular Access to Highly Porous acs -MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption journal February 2019
Topology Exploration in Highly Connected Rare-Earth Metal–Organic Frameworks via Continuous Hindrance Control journal April 2019
Ligand Rigidification for Enhancing the Stability of Metal–Organic Frameworks journal May 2019
Highly Electroconductive Metal–Organic Framework: Tunable by Metal Ion Sorption Quantity journal June 2019
Face-Sharing Archimedean Solids Stacking for the Construction of Mixed-Ligand Metal–Organic Frameworks journal July 2019
Structural Stability of Metal Organic Framework MOF-177 journal November 2009
In Situ Growth of Metal–Organic Framework Thin Films with Gas Sensing and Molecule Storage Properties journal June 2013
Prediction of Molecular Separation of Polar–Apolar Mixtures on Heterogeneous Metal–Organic Frameworks: HKUST-1 journal June 2014
Design and synthesis of an exceptionally stable and highly porous metal-organic framework journal November 1999
Chemical, thermal and mechanical stabilities of metal–organic frameworks journal February 2016
A route to high surface area, porosity and inclusion of large molecules in crystals journal February 2004
Protecting group and switchable pore-discriminating adsorption properties of a hydrophilic–hydrophobic metal–organic framework journal March 2011
Selectivity and direct visualization of carbon dioxide and sulfur dioxide in a decorated porous host journal September 2012
Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal–organic frameworks journal June 2014
Supramolecular binding and separation of hydrocarbons within a functionalized porous metal–organic framework journal December 2014
Soft porous crystals journal November 2009
A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis journal July 2010
Superior thermoelasticity and shape-memory nanopores in a porous supramolecular organic framework journal May 2016
Unravelling exceptional acetylene and carbon dioxide adsorption within a tetra-amide functionalized metal-organic framework journal February 2017
Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework journal February 2017
Efficient and tunable white-light emission of metal–organic frameworks by iridium-complex encapsulation journal November 2013
Engineering chiral porous metal-organic frameworks for enantioselective adsorption and separation journal July 2014
Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks journal December 2014
Stable metal-organic frameworks containing single-molecule traps for enzyme encapsulation journal January 2015
Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging journal December 2009
Destruction of chemical warfare agents using metal–organic frameworks journal March 2015
Selective nitrogen capture by porous hybrid materials containing accessible transition metal ion sites journal December 2016
Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks journal December 2017
Dynamic photo-switching in light-responsive JUC-62 for CO 2 capture journal October 2017
Pentiptycene-Based Luminescent Cu (II) MOF Exhibiting Selective Gas Adsorption and Unprecedentedly High-Sensitivity Detection of Nitroaromatic Compounds (NACs) journal February 2016
Highly-thermostable metal–organic frameworks (MOFs) of zinc and cadmium 4,4′-(hexafluoroisopropylidene)diphthalates with a unique fluorite topology journal January 2007
Synthesis and catalytic properties of MIL-100(Fe), an iron( iii ) carboxylate with large pores journal January 2007
A three-dimensional metal–organic framework with a distorted Kagome related layer showing canted antiferromagnetic behaviour journal January 2008
Gas and liquid phase adsorption in isostructural Cu 3 [biaryltricarboxylate] 2 microporous coordination polymers journal January 2011
A stepwise transition from microporosity to mesoporosity in metal–organic frameworks by thermal treatment journal January 2011
The unique rht-MOF platform, ideal for pinpointing the functionalization and CO 2 adsorption relationship journal January 2012
Highly porous metal–organic framework sustained with 12-connected nanoscopic octahedra journal January 2013
MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application journal January 2012
A porous metal–metalloporphyrin framework featuring high-density active sites for chemical fixation of CO 2 under ambient conditions journal January 2014
Unusual preservation of polyhedral molecular building units in a metal–organic framework with evident desymmetrization in ligand design journal January 2014
Porous coordination polymers based on azamacrocyclic complex: syntheses, solvent-induced reversible crystal-to-crystal transformation and gas sorption properties journal January 2014
Five MOFs with different topologies based on anthracene functionalized tetracarboxylic acid: syntheses, structures, and properties journal January 2014
Tunable colors and white-light emission based on a microporous luminescent Zn( ii )-MOF journal January 2014
A proton-conducting lanthanide metal–organic framework integrated with a dielectric anomaly and second-order nonlinear optical effect journal January 2014
Enhanced CO 2 sorption and selectivity by functionalization of a NbO-type metal–organic framework with polarized benzothiadiazole moieties journal January 2014
A ketone functionalized luminescent terbium metal–organic framework for sensing of small molecules journal January 2015
Assembly of metal–organic polyhedra into highly porous frameworks for ethene delivery journal January 2015
Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker journal January 2015
A microporous metal–organic framework with rare lvt topology for highly selective C 2 H 2 /C 2 H 4 separation at room temperature journal January 2015
Isoreticular MOFs based on a rhombic dodecahedral MOP as a tertiary building unit journal January 2014
Copolymerisation at work: the first example of a highly porous MOF comprising a triarylborane-based linker journal January 2015
Tuning the structure and function of metal–organic frameworks via linker design journal January 2014
The synthesis, structure, topology and catalytic application of a novel cubane-based copper( ii ) metal–organic framework derived from a flexible amido tripodal acid journal January 2015
A NbO type microporous metal–organic framework constructed from a naphthalene derived ligand for CH 4 and C 2 H 2 storage at room temperature journal January 2014
A new microporous metal–organic framework with open metal sites and exposed carboxylic acid groups for selective separation of CO 2 /CH 4 and C 2 H 2 /CH 4 journal January 2014
Template-directed construction of conformational supramolecular isomers for bilayer porous metal–organic frameworks with distinct gas sorption behaviors journal January 2015
A NbO-type metal–organic framework exhibiting high deliverable capacity for methane storage journal January 2015
A highly robust metal–organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO 2 over CH 4 journal January 2015
A microporous metal–organic framework with polarized trifluoromethyl groups for high methane storage journal January 2015
A polyhedral metal–organic framework based on the supermolecular building block strategy exhibiting high performance for carbon dioxide capture and separation of light hydrocarbons journal January 2015
Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices journal January 2015
High acetylene/ethylene separation in a microporous zinc( ii ) metal–organic framework with low binding energy journal January 2016
Topology-guided design of an anionic bor -network for photocatalytic [Ru(bpy) 3 ] 2+ encapsulation journal January 2016
The dynamic response of a flexible indium based metal–organic framework to gas sorption journal January 2016
Significant enhancement of gas uptake capacity and selectivity via the judicious increase of open metal sites and Lewis basic sites within two polyhedron-based metal–organic frameworks journal January 2016
A metal–organic framework based on cyclotriphosphazene-functionalized hexacarboxylate for selective adsorption of CO 2 and C 2 H 6 over CH 4 at room temperature journal January 2015
[Co(H 2 O) 6 ] 2+ and H 3 O + encapsulated in a unique 3D anionic Co( ii ) framework with hydrophilic hexagonal and circular channels journal January 2015
Synthesis and gas sorption properties of a homochiral metal–organic framework with octahedral cages journal January 2015
A microporous lanthanum metal–organic framework as a bi-functional chemosensor for the detection of picric acid and Fe 3+ ions journal January 2015
A hydrothermally stable Zn( ii )-based metal–organic framework: structural modulation and gas adsorption journal January 2015
Merging open metal sites and Lewis basic sites in a NbO-type metal–organic framework for improved C 2 H 2 /CH 4 and CO 2 /CH 4 separation journal January 2015
Metal–organic frameworks constructed from crown ether-based 1,4-benzenedicarboxylic acid derivatives journal January 2016
C 2 H 2 adsorption in three isostructural metal–organic frameworks: boosting C 2 H 2 uptake by rational arrangement of nitrogen sites journal January 2016
High methane storage and working capacities in a NbO-type metal–organic framework journal January 2016
Porous metal–organic frameworks with Lewis basic nitrogen sites for high-capacity methane storage journal January 2015
Dual-porous metal organic framework for room temperature CO 2 fixation via cyclic carbonate synthesis journal January 2016
An amino-decorated NbO-type metal–organic framework for high C 2 H 2 storage and selective CO 2 capture journal January 2015
A new luminescent Cd( ii )-MOF as a highly selective chemical probe for Fe 3+ in aqueous solution with mixed metal ions journal January 2015
Photoinduced water oxidation by an organic ligand incorporated into the framework of a stable metal–organic framework journal January 2016
Lanthanide metal–organic frameworks containing a novel flexible ligand for luminescence sensing of small organic molecules and selective adsorption journal January 2015
An In III -based anionic metal–organic framework: sensitization of lanthanide (III) ions and selective absorption and separation of cationic dyes journal January 2015
A luminescent Zr-based metal–organic framework for sensing/capture of nitrobenzene and high-pressure separation of CH 4 /C 2 H 6 journal January 2015
Porous barium–organic frameworks with highly efficient catalytic capacity and fluorescence sensing ability journal January 2015
The accessibility of nitrogen sites makes a difference in selective CO 2 adsorption of a family of isostructural metal–organic frameworks journal January 2015
Design of metal organic framework–enzyme based bioelectrodes as a novel and highly sensitive biosensing platform journal January 2015
Finely tuning MOFs towards high performance in C 2 H 2 storage: synthesis and properties of a new MOF-505 analogue with an inserted amide functional group journal January 2016
Two pillared metal–organic frameworks comprising a long pillar ligand used as fluorescent sensors for nitrobenzene and heterogeneous catalysts for the Knoevenagel condensation reaction journal January 2016
A porous lanthanide metal–organic framework based on a flexible cyclotriphosphazene-functionalized hexacarboxylate exhibiting selective gas adsorption journal January 2016
Topological control of 3,4-connected frameworks based on the Cu 2 -paddle-wheel node: tbo or pto , and why? journal January 2016
The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene journal January 2017
Unique anisotropic optical properties of a highly stable metal–organic framework based on trinuclear iron( iii ) secondary building units linked by tetracarboxylic linkers with an anthracene core journal January 2016
Immobilization of Bacillus subtilis lipase on a Cu-BTC based hierarchically porous metal–organic framework material: a biocatalyst for esterification journal January 2016
An aminopyrimidine-functionalized cage-based metal–organic framework exhibiting highly selective adsorption of C 2 H 2 and CO 2 over CH 4 journal January 2016
Interplay between hydrophobicity and basicity toward the catalytic activity of isoreticular MOF organocatalysts journal January 2016
An anionic metal–organic framework based on angular tetracarboxylic acid and a mononuclear copper ion for selective gas adsorption journal January 2016
Synthesis and structure of color tunable and white-light emitting lanthanide metal–organic framework materials constructed from conjugated 1,1′-butadiynebenzene-3,3′,5,5′-tetracarboxylate ligand journal January 2016
Coupling two enzymes into a tandem nanoreactor utilizing a hierarchically structured MOF journal January 2016
A NbO-type copper metal–organic framework decorated with carboxylate groups exhibiting highly selective CO 2 adsorption and separation of organic dyes journal January 2016
A metal–organic framework functionalized with piperazine exhibiting enhanced CH 4 storage journal January 2017
A multi-aromatic hydrocarbon unit induced hydrophobic metal–organic framework for efficient C 2 /C 1 hydrocarbon and oil/water separation journal January 2017
A highly porous metal–organic framework for large organic molecule capture and chromatographic separation journal January 2017
Phase transition triggered aggregation-induced emission in a photoluminescent uranyl–organic framework journal January 2018
Enzyme–MOF (metal–organic framework) composites journal January 2017
A porous metal–organic framework based on an asymmetric angular diisophthalate for selective adsorption of C 2 H 2 and CO 2 over CH 4 journal January 2017
A comparative study of C 2 H 2 adsorption properties in five isomeric copper-based MOFs based on naphthalene-derived diisophthalates journal January 2017
A pair of polymorphous metal–organic frameworks based on an angular diisophthalate linker: synthesis, characterization and gas adsorption properties journal January 2018
Rational construction of an ssa -type of MOF through pre-organizing the ligand's conformation and its exceptional gas adsorption properties journal January 2018
Highly effective Brønsted base/lewis acid cooperative catalysis: a new Cd metal–organic framework for the synthesis of Hantzsch 1,4-DHPs at ambient temperature journal January 2017
A rare Pb 9 cluster-organic framework constructed from a flexible cyclotriphosphazene-functionalized hexacarboxylate exhibiting selective gas separation journal January 2017
A heterometallic sodium–europium-cluster-based metal–organic framework as a versatile and water-stable chemosensor for antibiotics and explosives journal January 2017
Highly selective room temperature acetylene sorption by an unusual triacetylenic phosphine MOF journal January 2018
A mesoporous NNN-pincer-based metal–organic framework scaffold for the preparation of noble-metal-free catalysts journal January 2019
A metal–organic framework based on a custom-designed diisophthalate ligand exhibiting excellent hydrostability and highly selective adsorption of C 2 H 2 and CO 2 over CH 4 journal January 2018
Three ligand-originated MOF isomers: the positional effect of the methyl group on structures and selective C 2 H 2 /CH 4 and CO 2 /CH 4 adsorption properties journal January 2018
Three isoreticular ssa-type MOFs derived from bent diisophthalate ligands: exploring the substituent effect on structural stabilities and selective C 2 H 2 /CH 4 and CO 2 /CH 4 adsorption properties journal January 2018
Improving the capability of UiO-66 for Cr( vi ) adsorption from aqueous solutions by introducing isonicotinate N -oxide as the functional group journal January 2018
Water-stable fluorinated metal–organic frameworks (F-MOFs) with hydrophobic properties as efficient and highly active heterogeneous catalysts in aqueous solution journal January 2018
Functional group effect of isoreticular metal–organic frameworks on heavy metal ion adsorption journal January 2018
Acid- and base-stable porous mechanically interlocked 2D metal–organic polyrotaxane for in situ organochlorine insecticide encapsulation, sensing and removal journal January 2018
Enhancing light hydrocarbon storage and separation through introducing Lewis basic nitrogen sites within a carboxylate-decorated copper–organic framework journal January 2018
Pillar-layered MOFs: functionality, interpenetration, flexibility and applications journal January 2018
Flexible metal–organic frameworks for the wavelength-based luminescence sensing of aqueous pH journal January 2018
Solvent-assisted ligand exchange (SALE) for the enhancement of epoxide ring-opening reaction catalysis based on three amide-functionalized metal–organic frameworks journal January 2019
Harnessing MOF materials in photovoltaic devices: recent advances, challenges, and perspectives journal January 2019
Metal-organic frameworks journal January 2003
Synthesis, characterization, and photoluminescence of isostructural Mn, Co, and Zn MOFs having a diamondoid structure with large tetrahedral cages and high thermal stability journal January 2005
Temperature-dependent supramolecular stereoisomerism in porous copper coordination networks based on a designed carboxylate ligand journal January 2005
A designed metal–organic framework based on a metal–organic polyhedron journal January 2008
Single- or double-stranded helices-sustained molecular bilayer architecture journal January 2008
Metal–organic framework materials as catalysts journal January 2009
Metal–organophosphine and metal–organophosphonium frameworks with layered honeycomb-like structures journal January 2009
Novel lanthanide coordination polymers based on bis-tridentate chelator pyrazine-2,3,5,6-tetracarboxylate with nano-channels and water clusters journal January 2009
A three-dimensional metal–organic framework based on a triazine derivative: syntheses, structure analysis, and sorption studies journal January 2009
Novel (3,6)-connected network and (4,6)-connected framework in two copper(II) and cadmium(II) complexes of flexible (2S,3S,4R,5R)-tetrahydrofurantetracarboxylic acid: synthesis, structure, thermostability, and luminescence studies journal January 2009
Large H2 storage capacity of a new polyhedron-based metal–organic framework with high thermal and hygroscopic stability journal January 2009
A new MOF-505 analog exhibiting high acetylene storage journal January 2009
An unusual case of symmetry-preserving isomerism journal January 2010
A NbO-type metal–organic framework derived from a polyyne-coupled di-isophthalate linker formed in situ journal January 2010
Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand journal January 2010
A rod packing microporous metal–organic framework with open metal sites for selective guest sorption and sensing of nitrobenzene journal January 2010
A two-fold interpenetrated (3,6)-connected metal–organic framework with rutile topology showing a large solvent cavity journal January 2010
A new type of polyhedron-based metal–organic frameworks with interpenetrating cationic and anionic nets demonstrating ion exchange, adsorption and luminescent properties journal January 2011
High capacity gas storage by a 4,8-connected metal–organic polyhedral framework journal January 2011
A novel low density metal–organic framework with pcu topology by dendritic ligand journal January 2011
A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra journal January 2011
Fluorescent metal–organic framework for selective sensing of nitroaromatic explosives journal January 2011
Hydrothermal syntheses, crystal structures and magnetic properties of four Mn(ii) and Co(ii) coordination polymers generated from new carboxylate-introduced 1,2,3-triazole ligands journal January 2011
Solvent and temperature influence structural variation from nonporous 2D → 3D parallel polycatenation to 3D microporous metal–organic framework journal January 2011
Pore with gate: modulating hydrogen storage in metal-organic framework materials via cation exchange journal January 2011
High and selective CO2 capture by two mesoporous acylamide-functionalized rht-type metal–organic frameworks journal January 2012
Unusual microporous polycatenane-like metal–organic frameworks for the luminescent sensing of Ln3+ cations and rapid adsorption of iodine journal January 2012
Quest for highly porous metal–metalloporphyrin framework based upon a custom-designed octatopic porphyrin ligand journal January 2012
Controllable synthesis of a non-interpenetrating microporous metal–organic framework based on octahedral cage-like building units for highly efficient reversible adsorption of iodine journal January 2012
A versatile metal–organic framework for carbon dioxide capture and cooperative catalysis journal January 2012
A highly porous metal–organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake journal January 2012
Chiral transformations of achiral porous metal–organic frameworks via a stepwise approach journal January 2012
A microporous lanthanide-tricarboxylate framework with the potential for purification of natural gas journal January 2012
Amino substituted Cu3(btc)2: a new metal–organic framework with a versatile functionality journal January 2012
A pcu-type metal–organic framework based on covalently quadruple cross-linked supramolecular building blocks (SBBs): structure and adsorption properties journal January 2012
An unusual (4,10)-connected 3-D metal–organic framework based on non-planar tricarboxyl tecton and tetracadmium(ii) secondary building units journal January 2012
Porous metal–organic framework based on a macrocyclic tetracarboxylate ligand exhibiting selective CO2 uptake journal January 2012
Mixed-motif interpenetration and cross-linking of high-connectivity networks led to robust and porous metal–organic frameworks with high gas uptake capacities journal January 2012
Vertex-directed self-assembly of a high symmetry supermolecular building block using a custom-designed porphyrin journal January 2012
Cavity-induced enantioselectivity reversal in a chiral metal–organic framework Brønsted acid catalyst journal January 2012
A high connectivity metal–organic framework with exceptional hydrogen and methane uptake capacities journal January 2012
A crystal engineering rationale in designing a CdII coordination polymer based metallogel derived from a C3 symmetric tris-amide-tris-carboxylate ligand journal January 2012
A unique magnesium-based 3D MOF with nanoscale cages and temperature dependent selective gas sorption properties journal January 2013
A microporous metal–organic framework of a rare sty topology for high CH4 storage at room temperature journal January 2013
Low-energy regeneration and high productivity in a lanthanide–hexacarboxylate framework for high-pressure CO2–CH4–H2 separation journal January 2013
A 4 + 4 strategy for synthesis of zeolitic metal–organic frameworks: an indium-MOF with SOD topology as a light-harvesting antenna journal January 2013
An electron rich porous extended framework as a heterogeneous catalyst for Diels–Alder reactions journal January 2013
Two homochiral organocatalytic metal organic materials with nanoscopic channels journal January 2013
A robust amino-functionalized titanium(iv) based MOF for improved separation of acid gases journal January 2013
Enantioselective ring-opening of meso-epoxides by aromatic amines catalyzed by a homochiral metal–organic framework journal January 2013
A highly stable dynamic fluorescent metal–organic framework for selective sensing of nitroaromatic explosives journal January 2013
Coexistence of cages and one-dimensional channels in a porous MOF with high H2 and CH4 uptakes journal January 2014
A highly porous NbO type metal–organic framework constructed from an expanded tetracarboxylate journal January 2014
Linker extensions in metal–organic frameworks: a way to isoreticular networks or new topologies? journal January 2013
Wings waving: coordinating solvent-induced structural diversity of new Cu(ii) flexible MOFs with crystal to crystal transformation and gas sorption capability journal January 2013
Structural design of porous coordination networks from tetrahedral building units journal January 2013
A highly porous 4,4-paddlewheel-connected NbO-type metal–organic framework with a large gas-uptake capacity journal January 2013
Gram-scale, high-yield synthesis of a robust metal–organic framework for storing methane and other gases journal January 2013
Trigonal prism or octahedron: the conformational change of a dendritic six-node ligand in MOFs journal January 2013
Realization of both high hydrogen selectivity and capacity in a guest responsive metal–organic framework journal January 2013
A new metal–organic framework with ultra-high surface area journal January 2014
A porous metal–organic framework with an elongated anthracene derivative exhibiting a high working capacity for the storage of methane journal January 2014
Tailoring porosity and rotational dynamics in a series of octacarboxylate metal-organic frameworks journal March 2017
A lanthanide metal-organic framework based on a custom-designed macrocyclic ligand journal June 2016
Syntheses, Crystal Structure, and Fluorescent Property of a New Cd(II) Complex Constructed from 1,2,4,5-Benzenetetracarboxylate journal October 2013
A fluorescent paramagnetic Mn metal–organic framework based on semi-rigid pyrene tetracarboxylic acid: sensing of solvent polarity and explosive nitroaromatics journal August 2015
Metal-organic framework based on hinged cube tessellation as transformable mechanical metamaterial journal May 2019
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
Ultrahigh Porosity in Metal-Organic Frameworks journal July 2010
Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices journal December 2013
A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n journal February 1999
Bottom-up construction of a superstructure in a porous uranium-organic crystal journal April 2017
Balancing volumetric and gravimetric uptake in highly porous materials for clean energy journal April 2020
Synthesis, crystal structure, and porosity calculation of novel lanthanide coordination polymers involving naphthalene-1,4,5,8-tetra-carboxylate as ligand journal July 2013
DFT Study on Adsorption of Drug Artemisinin Onto Carbon Nanotubes journal April 2017
Let’s Talk about MOFs—Topology and Terminology of Metal-Organic Frameworks and Why We Need Them journal February 2015
A microporous metal–organic framework with open metal sites for selective sensing Fe3+, CrO42- and nitrobenzene journal November 2017

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry