Enhancing Pore-Environment Complexity Using a Trapezoidal Linker: Toward Stepwise Assembly of Multivariate Quinary Metal–Organic Frameworks

Pang, Jiandong; Yuan, Shuai; Qin, Junsheng; Wu, Mingyan; Lollar, Christina T.; Li, Jialuo; Huang, Ning; Li, Bao; Zhang, Peng; Zhou, Hong -Cai

doi:10.1021/jacs.8b07411

Enhancing Pore-Environment Complexity Using a Trapezoidal Linker: Toward Stepwise Assembly of Multivariate Quinary Metal–Organic Frameworks

Journal Article · Wed Sep 19 00:00:00 EDT 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b07411· OSTI ID:1566589

Pang, Jiandong ^[1]; ^[2]; Qin, Junsheng ^[2]; Wu, Mingyan ^[3]; Lollar, Christina T. ^[2]; Li, Jialuo ^[2]; ^[2]; ^[2]; Zhang, Peng ^[2]; ^[2]

Texas A & M Univ., College Station, TX (United States); Chinese Academy of Sciences, Fujian (China)
Texas A & M Univ., College Station, TX (United States)
Chinese Academy of Sciences, Fujian (China)

Multicomponent metal–organic frameworks (MOFs) promise the precise placement of synergistic functional groups with atomic-level precision, capable of promoting fascinating developments in basic sciences and applications. However, the complexity of multicomponent systems poses a challenge to their structural design and synthesis. Herein, we show that linkers of low symmetry can bring new opportunities to the construction of multicomponent MOFs. A carbazole-tetracarboxylate linker of C_s point group symmetry was designed and combined with an 8-connected Zr₆ cluster to generate a low-symmetry MOF, PCN-609. PCN-609 contains coordinatively unsaturated Zr sites arranged within a lattice with three crystallographically distinct pockets, which can accommodate linear linkers of different lengths. Sequential linker installation was carried out to postsynthetically insert three linear linkers into PCN-609, giving rise to a quinary MOF. At last, functionalization of each linker from the quinary MOF system creates multivariate pore environments with unprecedented complexity.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Texas A & M Univ., College Station, TX (United States); Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: FE0026472; SC0001015

OSTI ID:: 1566589

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 39 Vol. 140; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Enhancing Pore-Environment Complexity Using a Trapezoidal Linker: Toward Stepwise Assembly of Multivariate Quinary Metal–Organic Frameworks

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