Enhancing Pore-Environment Complexity Using a Trapezoidal Linker: Toward Stepwise Assembly of Multivariate Quinary Metal–Organic Frameworks

Pang, Jiandong; Yuan, Shuai; Qin, Junsheng; Wu, Mingyan; Lollar, Christina T.; Li, Jialuo; Huang, Ning; Li, Bao; Zhang, Peng; Zhou, Hong -Cai

doi:10.1021/jacs.8b07411

Title: Enhancing Pore-Environment Complexity Using a Trapezoidal Linker: Toward Stepwise Assembly of Multivariate Quinary Metal–Organic Frameworks

Journal Article · Wed Sep 19 00:00:00 EDT 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b07411· OSTI ID:1566589

Pang, Jiandong ^[1];

^[2]; Qin, Junsheng ^[2]; Wu, Mingyan ^[3]; Lollar, Christina T. ^[2]; Li, Jialuo ^[2];

^[2];

^[2]; Zhang, Peng ^[2];

^[2]

Texas A & M Univ., College Station, TX (United States); Chinese Academy of Sciences, Fujian (China)
Texas A & M Univ., College Station, TX (United States)
Chinese Academy of Sciences, Fujian (China)

Multicomponent metal–organic frameworks (MOFs) promise the precise placement of synergistic functional groups with atomic-level precision, capable of promoting fascinating developments in basic sciences and applications. However, the complexity of multicomponent systems poses a challenge to their structural design and synthesis. Herein, we show that linkers of low symmetry can bring new opportunities to the construction of multicomponent MOFs. A carbazole-tetracarboxylate linker of C_s point group symmetry was designed and combined with an 8-connected Zr₆ cluster to generate a low-symmetry MOF, PCN-609. PCN-609 contains coordinatively unsaturated Zr sites arranged within a lattice with three crystallographically distinct pockets, which can accommodate linear linkers of different lengths. Sequential linker installation was carried out to postsynthetically insert three linear linkers into PCN-609, giving rise to a quinary MOF. At last, functionalization of each linker from the quinary MOF system creates multivariate pore environments with unprecedented complexity.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Texas A & M Univ., College Station, TX (United States); Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: FE0026472; SC0001015

OSTI ID:: 1566589

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 39; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 63 works

Citation information provided by
Web of Science

References (29)

Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013) Batten, Stuart R.; Champness, Neil R.; Chen, Xiao-Ming Pure and Applied Chemistry, Vol. 85, Issue 8 https://doi.org/10.1351/PAC-REC-12-11-20	journal	July 2013
Carbon Dioxide Capture in Metal–Organic Frameworks Sumida, Kenji; Rogow, David L.; Mason, Jarad A. Chemical Reviews, Vol. 112, Issue 2, p. 724-781 https://doi.org/10.1021/cr2003272	journal	September 2011
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Design and fabrication of mesoporous heterogeneous basic catalysts Sun, Lin-Bing; Liu, Xiao-Qin; Zhou, Hong-Cai Chemical Society Reviews, Vol. 44, Issue 15 https://doi.org/10.1039/C5CS00090D	journal	January 2015
Metal cluster-based functional porous coordination polymers Zhang, Wei-Xiong; Liao, Pei-Qin; Lin, Rui-Biao Coordination Chemistry Reviews, Vol. 293-294 https://doi.org/10.1016/j.ccr.2014.12.009	journal	June 2015
Covalent Chemistry beyond Molecules Jiang, Juncong; Zhao, Yingbo; Yaghi, Omar M. Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.5b10666	journal	February 2016
Porous Metal-Organic Frameworks: Promising Materials for Methane Storage Li, Bin; Wen, Hui-Min; Zhou, Wei Chem, Vol. 1, Issue 4 https://doi.org/10.1016/j.chempr.2016.09.009	journal	October 2016
Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents Bobbitt, N. Scott; Mendonca, Matthew L.; Howarth, Ashlee J. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00108H	journal	January 2017
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions Huang, Yuan-Biao; Liang, Jun; Wang, Xu-Sheng Chemical Society Reviews, Vol. 46, Issue 1 https://doi.org/10.1039/C6CS00250A	journal	January 2017
Enzyme–MOF (metal–organic framework) composites Lian, Xizhen; Fang, Yu; Joseph, Elizabeth Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00058H	journal	January 2017
Future Porous Materials Kitagawa, Susumu Accounts of Chemical Research, Vol. 50, Issue 3 https://doi.org/10.1021/acs.accounts.6b00500	journal	March 2017
“Heterogeneity within Order” in Metal-Organic Frameworks Furukawa, Hiroyasu; Müller, Ulrich; Yaghi, Omar M. Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201410252	journal	January 2015
Multivariate Metal–Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts for Sequential Reactions Xia, Qingchun; Li, Zijian; Tan, Chunxia Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b03113	journal	June 2017
Understanding Structure, Metal Distribution, and Water Adsorption in Mixed-Metal MOF-74 Howe, Joshua D.; Morelock, Cody R.; Jiao, Yang The Journal of Physical Chemistry C, Vol. 121, Issue 1 https://doi.org/10.1021/acs.jpcc.6b11719	journal	December 2016
Systematic and Dramatic Tuning on Gas Sorption Performance in Heterometallic Metal–Organic Frameworks Zhai, Quan-Guo; Bu, Xianhui; Mao, Chengyu Journal of the American Chemical Society, Vol. 138, Issue 8 https://doi.org/10.1021/jacs.5b13491	journal	February 2016
Multivariable Modular Design of Pore Space Partition Zhao, Xiang; Bu, Xianhui; Nguyen, Edward T. Journal of the American Chemical Society, Vol. 138, Issue 46 https://doi.org/10.1021/jacs.6b07901	journal	November 2016
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks Deng, H.; Doonan, C. J.; Furukawa, H. Science, Vol. 327, Issue 5967, p. 846-850 https://doi.org/10.1126/science.1181761	journal	February 2010
Mapping of Functional Groups in Metal-Organic Frameworks Kong, X.; Deng, H.; Yan, F. Science, Vol. 341, Issue 6148, p. 882-885 https://doi.org/10.1126/science.1238339	journal	July 2013
Programmed Pore Architectures in Modular Quaternary Metal–Organic Frameworks Liu, Lujia; Konstas, Kristina; Hill, Matthew R. Journal of the American Chemical Society, Vol. 135, Issue 47 https://doi.org/10.1021/ja4100244	journal	November 2013
Cooperative Cluster Metalation and Ligand Migration in Zirconium Metal-Organic Frameworks Yuan, Shuai; Chen, Ying-Pin; Qin, Junsheng Angewandte Chemie International Edition, Vol. 54, Issue 49 https://doi.org/10.1002/anie.201505625	journal	October 2015
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO₂ Adsorption Studies Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804 https://doi.org/10.1021/ja408959g	journal	October 2013
Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs Yuan, Shuai; Chen, Ying-Pin; Qin, Jun-Sheng Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b04501	journal	July 2016
Precise Modulation of the Breathing Behavior and Pore Surface in Zr-MOFs by Reversible Post-Synthetic Variable-Spacer Installation to Fine-Tune the Expansion Magnitude and Sorption Properties Chen, Cheng-Xia; Wei, Zhangwen; Jiang, Ji-Jun Angewandte Chemie International Edition, Vol. 55, Issue 34 https://doi.org/10.1002/anie.201604023	journal	July 2016
Dynamic Spacer Installation for Multirole Metal–Organic Frameworks: A New Direction toward Multifunctional MOFs Achieving Ultrahigh Methane Storage Working Capacity Chen, Cheng-Xia; Wei, Zhang-Wen; Jiang, Ji-Jun Journal of the American Chemical Society, Vol. 139, Issue 17 https://doi.org/10.1021/jacs.7b01320	journal	April 2017
Retrosynthesis of multi-component metal−organic frameworks Yuan, Shuai; Qin, Jun-Sheng; Li, Jialuo Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03102-5	journal	February 2018
Topology-Guided Stepwise Insertion of Three Secondary Linkers in Zirconium Metal–Organic Frameworks Zhang, Xin; Frey, Brandon L.; Chen, Yu-Sheng Journal of the American Chemical Society, Vol. 140, Issue 24 https://doi.org/10.1021/jacs.8b04277	journal	May 2018
Flexible Zirconium MOFs as Bromine-Nanocontainers for Bromination Reactions under Ambient Conditions Pang, Jiandong; Yuan, Shuai; Du, Dongying Angewandte Chemie International Edition, Vol. 56, Issue 46 https://doi.org/10.1002/anie.201709186	journal	October 2017
Control the Structure of Zr-Tetracarboxylate Frameworks through Steric Tuning Pang, Jiandong; Yuan, Shuai; Qin, Junsheng Journal of the American Chemical Society, Vol. 139, Issue 46 https://doi.org/10.1021/jacs.7b09973	journal	November 2017
Defining the Proton Topology of the Zr₆-Based Metal–Organic Framework NU-1000 Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723 https://doi.org/10.1021/jz501899j	journal	October 2014

Cited By (17)

Zeolite-Type Metal Oxalate Frameworks Yi, Fei-Yan; Yang, Huajun; Zhao, Xiang Angewandte Chemie International Edition, Vol. 58, Issue 9 https://doi.org/10.1002/anie.201900106	journal	February 2019
The stepwise substitution in the hierarchical building of {Co ₁₁ Cd ₆ } cluster-based MOFs from {Co ₁₄ } precursor Chen, Yun-Kai; Tao, Ye; Qin, Huang-Fei Inorganic Chemistry Frontiers https://doi.org/10.1039/d0qi00537a	journal	January 2020
The chemistry of multi-component and hierarchical framework compounds Feng, Liang; Wang, Kun-Yu; Day, Gregory S. Chemical Society Reviews, Vol. 48, Issue 18 https://doi.org/10.1039/c9cs00250b	journal	January 2019
Molecular Pivot‐Hinge Installation to Evolve Topology in Rare‐Earth Metal–Organic Frameworks Feng, Liang; Wang, Yutong; Zhang, Kai Angewandte Chemie, Vol. 131, Issue 46 https://doi.org/10.1002/ange.201910717	journal	September 2019
New linker installation in metal–organic frameworks Pang, Qingqing; Tu, Binbin; Li, Qiaowei Dalton Transactions, Vol. 48, Issue 32 https://doi.org/10.1039/c9dt02335f	journal	January 2019
Hierarchical nickel/phosphorus/nitrogen/carbon composites templated by one metal–organic framework as highly efficient supercapacitor electrode materials Yu, Fan; Xiong, Xin; Zhou, Liu-Yin Journal of Materials Chemistry A, Vol. 7, Issue 6 https://doi.org/10.1039/c8ta11568k	journal	January 2019
A mixed-ligand strategy regulates thorium-based MOFs Huang, Zhi-wei; Hu, Kong-qiu; Mei, Lei Dalton Transactions, Vol. 49, Issue 4 https://doi.org/10.1039/c9dt04158c	journal	January 2020
Why Design Matters: From Decorated Metal Oxide Clusters to Functional Metal–Organic Frameworks Schoedel, Alexander; Rajeh, Sahar Topics in Current Chemistry, Vol. 378, Issue 1 https://doi.org/10.1007/s41061-020-0281-0	journal	February 2020
Structural tuning of zinc–porphyrin frameworks via auxiliary nitrogen-containing ligands towards selective adsorption of cationic dyes Wang, Xiao-Ning; Li, Jiang-Li; Zhao, Yu-Meng Chemical Communications, Vol. 55, Issue 46 https://doi.org/10.1039/c9cc02405k	journal	January 2019
Atomic‐ and Molecular‐Level Design of Functional Metal–Organic Frameworks (MOFs) and Derivatives for Energy and Environmental Applications Yilmaz, Gamze; Peh, Shing Bo; Zhao, Dan Advanced Science, Vol. 6, Issue 21 https://doi.org/10.1002/advs.201901129	journal	August 2019
Zeolite‐Type Metal Oxalate Frameworks Yi, Fei‐Yan; Yang, Huajun; Zhao, Xiang Angewandte Chemie, Vol. 131, Issue 9 https://doi.org/10.1002/ange.201900106	journal	January 2019
The synthesis and applications of chiral pyrrolidine functionalized metal–organic frameworks and covalent-organic frameworks Zhou, Mi; El-Sayed, El-Sayed M.; Ju, Zhanfeng Inorganic Chemistry Frontiers, Vol. 7, Issue 6 https://doi.org/10.1039/c9qi01103j	journal	January 2020
Harnessing Bottom‐Up Self‐Assembly To Position Five Distinct Components in an Ordered Porous Framework Tu, Binbin; Diestel, Lisa; Shi, Zhao‐Lin Angewandte Chemie, Vol. 131, Issue 16 https://doi.org/10.1002/ange.201900863	journal	February 2019
Highly open chalcogenide frameworks built from unusual defective supertetrahedral clusters Xue, Chaozhuang; Zhang, Li; Wang, Xiaoli Dalton Transactions, Vol. 48, Issue 29 https://doi.org/10.1039/c9dt01754b	journal	January 2019
Rational modifications of PCN-700 to induce electrical conductivity: a computational study Chong, Sanggyu; Kim, Jihan Dalton Transactions, Vol. 49, Issue 1 https://doi.org/10.1039/c9dt03865e	journal	January 2020
Uncovering Structural Opportunities for Zirconium Metal–Organic Frameworks via Linker Desymmetrization Wang, Yutong; Feng, Liang; Zhang, Kai Advanced Science, Vol. 6, Issue 23 https://doi.org/10.1002/advs.201901855	journal	September 2019
Harnessing Bottom-Up Self-Assembly To Position Five Distinct Components in an Ordered Porous Framework Tu, Binbin; Diestel, Lisa; Shi, Zhao-Lin Angewandte Chemie International Edition, Vol. 58, Issue 16 https://doi.org/10.1002/anie.201900863	journal	March 2019

Linked Research (14)

Similar Records

Stepwise Assembly of Quinary Multivariate Metal–Organic Frameworks via Diversified Linker Exchange and Installation

Journal Article · Thu Jun 15 00:00:00 EDT 2023 · Journal of the American Chemical Society · OSTI ID:1566589

Hu, Yuchen; Zhang, Xin; Khoo, Rebecca Shu Hui; +3 more

Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs

Journal Article · Sat Jun 25 00:00:00 EDT 2016 · Journal of the American Chemical Society · OSTI ID:1566589

Yuan, Shuai; Chen, Ying-Pin; Qin, Jun-Sheng; +6 more

Uncovering Structural Opportunities for Zirconium Metal–Organic Frameworks via Linker Desymmetrization

Journal Article · Mon Sep 30 00:00:00 EDT 2019 · Advanced Science · OSTI ID:1566589

Wang, Yutong; Feng, Liang; Zhang, Kai; +8 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)

CCDC 1854072: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079sc The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854075: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079wg The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854077: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079yj The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854069: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079p8 The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854080: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc207b1n The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854068: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079n7 The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854071: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079rb The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854073: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079td The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854074: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079vf The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854076: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079xh The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854078: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079zk The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854070: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc2079q9 The current record is supplemented by this dataset	dataset	January 2018
CCDC 1854079: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Qin, Junsheng https://doi.org/10.5517/ccdc.csd.cc207b0m The current record is supplemented by this dataset	dataset	January 2018
CCDC 1569633: Experimental Crystal Structure Determination Pang, Jiandong; Yuan, Shuai; Du, Dongying https://doi.org/10.5517/ccdc.csd.cc1ppbb1 The current record is supplemented by this dataset	dataset	January 2018