A historical overview of the activation and porosity of metal–organic frameworks

Zhang, Xuan; Chen, Zhijie; Liu, Xinyao; Hanna, Sylvia L.; Wang, Xingjie; Taheri-Ledari, Reza; Maleki, Ali; Li, Peng; Farha, Omar K.

doi:10.1039/d0cs00997k

A historical overview of the activation and porosity of metal–organic frameworks

Journal Article · Mon Sep 21 00:00:00 EDT 2020 · Chemical Society Reviews

DOI:https://doi.org/10.1039/d0cs00997k· OSTI ID:1848894

^[1]; ^[2]; ^[3]; ^[2]; Wang, Xingjie ^[2]; ^[4]; ^[4]; ^[5]; ^[2]

Northwestern Univ., Evanston, IL (United States); OSTI
Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States); Jilin Univ., Changchun (China)
Iran Univ. of Science and Technology, Tehran (Iran)
Fudan Univ., Shanghai (China)

Since the first reports of metal–organic frameworks (MOFs), this unique class of crystalline, porous materials has garnered increasing attention in a wide variety of applications such as gas storage and separation, catalysis, enzyme immobilization, drug delivery, water capture, and sensing. A fundamental feature of MOFs is their porosity which provides space on the micro- and meso-scale for confining and exposing their functionalities. Therefore, designing MOFs with high porosity and developing suitable activation methods for preserving and accessing their pore space have been a common theme in MOF research. Reticular chemistry allows for the facile design of MOFs from highly tunable metal nodes and organic linkers in order to realize different pore structures, topologies, and functionalities. With the hope of shedding light on future research endeavors in MOF porosity, it is worthwhile to examine the development of MOFs, with an emphasis on their porosity and how to properly access their pore space. In this review, we will provide an overview of the historic evolution of porosity and activation of MOFs, followed by a synopsis of the strategies to design and preserve permanent porosity in MOFs.

View Accepted Manuscript (DOE)

Research Organization:: Northwestern Univ., Evanston, IL (United States); Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: EE0008816; FG02-03ER15457; FG02-08ER15967; NA0003763

OSTI ID:: 1848894

Alternate ID(s):: OSTI ID: 1664494

Journal Information:: Chemical Society Reviews, Journal Name: Chemical Society Reviews Journal Issue: 20 Vol. 49; ISSN 0306-0012

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Journal Article · Thu May 25 00:00:00 EDT 2017 · Nature Communications · OSTI ID:1389292

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

A historical overview of the activation and porosity of metal–organic frameworks

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