Construction of hierarchically porous metal–organic frameworks through linker labilization

Yuan, Shuai; Zou, Lanfang; Qin, Jun-Sheng; Li, Jialuo; Huang, Lan; Feng, Liang; Wang, Xuan; Bosch, Mathieu; Alsalme, Ali; Cagin, Tahir; Zhou, Hong-Cai

doi:10.1038/ncomms15356

Construction of hierarchically porous metal–organic frameworks through linker labilization

Journal Article · Thu May 25 00:00:00 EDT 2017 · Nature Communications

DOI:https://doi.org/10.1038/ncomms15356· OSTI ID:1389292

Yuan, Shuai ^[1]; Zou, Lanfang ^[2]; Qin, Jun-Sheng ^[3]; Li, Jialuo ^[2]; ^[4]; Feng, Liang ^[2]; Wang, Xuan ^[2]; Bosch, Mathieu ^[2]; Alsalme, Ali ^[5]; Cagin, Tahir ^[6]; ^[7]

Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry; Texas A&M University
Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry; King Saud Univ., Riyadh (Saudi Arabia). Chemistry Dept.
Texas A & M Univ., College Station, TX (United States). Dept. of Materials Science and Engineering
King Saud Univ., Riyadh (Saudi Arabia). Chemistry Dept.
Texas A & M Univ., College Station, TX (United States). Dept. of Materials Science and Engineering, Artie McFerrin Dept. of Chemical Engineering
Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry, Dept. of Materials Science and Engineering; King Saud Univ., Riyadh (Saudi Arabia). Chemistry Dept.

One major goal of metal–organic framework (MOF) research is the expansion of pore size and volume. Although many approaches have been attempted to increase the pore size of MOF materials, it is still a challenge to construct MOFs with precisely customized pore apertures for specific applications. W present a new method, namely linker labilization, to increase the MOF porosity and pore size, giving rise to hierarchical-pore architectures. Microporous MOFs with robust metal nodes and pro-labile linkers were initially synthesized. The mesopores were subsequently created as crystal defects through the splitting of a pro-labile-linker and the removal of the linker fragments by acid treatment. We also demonstrate that linker labilization method can create controllable hierarchical porous structures in stable MOFs, which facilitates the diffusion and adsorption process of guest molecules to improve the performances of MOFs in adsorption and catalysis.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS); Texas A & M Univ., College Station, TX (United States); Univ. of California, Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: FE0026472; SC0001015

OSTI ID:: 1389292

Journal Information:: Nature Communications, Journal Name: Nature Communications Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Stable metal–organic frameworks as a host platform for catalysis and biomimetics Qin, Jun-Sheng; Yuan, Shuai; Lollar, Christina Chemical Communications, Vol. 54, Issue 34 https://doi.org/10.1039/c7cc09173g	journal	January 2018
Photochemistry and photophysics of MOFs: steps towards MOF-based sensing enhancements Dolgopolova, Ekaterina A.; Rice, Allison M.; Martin, Corey R. Chemical Society Reviews, Vol. 47, Issue 13 https://doi.org/10.1039/c7cs00861a	journal	January 2018
A gel-like/freeze-drying strategy to construct hierarchically porous polyoxometalate-based metal–organic framework catalysts Li, Xiao-Hui; Liu, Yi-Wei; Liu, Shu-Mei Journal of Materials Chemistry A, Vol. 6, Issue 11 https://doi.org/10.1039/c7ta10334d	journal	January 2018
Rapid room temperature conversion of hydroxy double salt to MOF-505 for CO ₂ capture Chen, Yongwei; Wu, Houxiao; Xiao, Qiangqiang CrystEngComm, Vol. 21, Issue 1 https://doi.org/10.1039/c8ce01489b	journal	January 2019
Adsorption of anthracene substitutes into suprachannels: bulk vs. included guests Lee, Daseul; Kim, Dongwon; Lee, Haeri CrystEngComm, Vol. 21, Issue 14 https://doi.org/10.1039/c8ce02185f	journal	January 2019
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials Kirchon, Angelo; Feng, Liang; Drake, Hannah F. Chemical Society Reviews, Vol. 47, Issue 23 https://doi.org/10.1039/c8cs00688a	journal	January 2018
Chiral coordination polymers based on d ¹⁰ metals and 2-aminonicotinate with blue fluorescent/green phosphorescent anisotropic emissions Pajuelo-Corral, Oier; Rodríguez-Diéguez, Antonio; García, Jose A. Dalton Transactions, Vol. 47, Issue 26 https://doi.org/10.1039/c8dt01159a	journal	January 2018
Templated fabrication of hierarchically porous metal–organic frameworks and simulation of crystal growth Duan, Chongxiong; Zhang, Hang; Yang, Minhui Nanoscale Advances, Vol. 1, Issue 3 https://doi.org/10.1039/c8na00262b	journal	January 2019
A 2D porous pentiptycene-based MOF for efficient detection of Ba ²⁺ and selective adsorption of dyes from water Zhang, Minghui; Qi, Ziqiang; Feng, Yang Inorganic Chemistry Frontiers, Vol. 5, Issue 6 https://doi.org/10.1039/c8qi00098k	journal	January 2018
Hierarchically porous metal–organic frameworks: rapid synthesis and enhanced gas storage Duan, Chongxiong; Zhang, Hang; Li, Feier Soft Matter, Vol. 14, Issue 47 https://doi.org/10.1039/c8sm01143e	journal	January 2018
Fine-tuning of nano-traps in a stable metal–organic framework for highly efficient removal of propyne from propylene Wen, Hui-Min; Li, Libo; Lin, Rui-Biao Journal of Materials Chemistry A, Vol. 6, Issue 16 https://doi.org/10.1039/c8ta00598b	journal	January 2018
An antiferromagnetic metalloring pyrazolate (Pz) framework with [Cu ₁₂ (μ ₂ -OH) ₁₂ (Pz) ₁₂ ] nodes for separation of C ₂ H ₂ /CH ₄ mixture Li, Ziyin; Ye, Yingxiang; Yao, Zizhu Journal of Materials Chemistry A, Vol. 6, Issue 40 https://doi.org/10.1039/c8ta04498h	journal	January 2018
Zinc/itaconate coordination polymers as first examples with long-lasting phosphorescence based on acyclic ligands Wibowo, Atmanto Heru; Suryandari, Yetti; Masykur, Abu Journal of Materials Chemistry C, Vol. 6, Issue 40 https://doi.org/10.1039/c8tc03598a	journal	January 2018
The chemistry of multi-component and hierarchical framework compounds Feng, Liang; Wang, Kun-Yu; Day, Gregory S. Chemical Society Reviews, Vol. 48, Issue 18 https://doi.org/10.1039/c9cs00250b	journal	January 2019
Constructing new metal–organic frameworks with complicated ligands from “One-Pot” in situ reactions Kong, Xiang-Jing; He, Tao; Zhang, Yong-Zheng Chemical Science, Vol. 10, Issue 14 https://doi.org/10.1039/c9sc00178f	journal	January 2019
A multifunctional Zr( iv )-based metal–organic framework for highly efficient elimination of Cr( vi ) from the aqueous phase Liu, Junmin; Ye, Yu; Sun, Xiaodong Journal of Materials Chemistry A, Vol. 7, Issue 28 https://doi.org/10.1039/c9ta04026a	journal	January 2019
Accurate tuning of rare earth metal–organic frameworks with unprecedented topology for white-light emission Wang, Yutong; Zhang, Kai; Wang, Xiaokang Journal of Materials Chemistry C, Vol. 8, Issue 4 https://doi.org/10.1039/c9tc05471e	journal	January 2020
Rising Up: Hierarchical Metal–Organic Frameworks in Experiments and Simulations Luo, Y.; Ahmad, M.; Schug, A. Wiley https://doi.org/10.5445/ir/1000095815	text	January 2019

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CCDC 1525246: Experimental Crystal Structure Determination: RAZVIA : catena-[tris(μ-4,4'-diazene-1,2-diyldibenzoato)-tetrakis(μ-oxo)-tri-zirconium unknown solvate] Yuan, Shuai; Zou, Lanfang; Qin, Jun-Sheng https://doi.org/10.5517/ccdc.csd.cc1n64hh The current record is supplemented by this dataset	dataset	December 2016
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