Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution

Milam-Guerrero, JoAnna; Zheng, Michelle; Spence, Nicole R.; Calder, Stuart; Lapidus, Saul; Melot, Brent C.

doi:10.1021/acs.inorgchem.0c03809

Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution

Journal Article · Mon May 03 00:00:00 EDT 2021 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.0c03809· OSTI ID:1846202

Milam-Guerrero, JoAnna; Zheng, Michelle; Spence, Nicole R.; Calder, Stuart; Lapidus, Saul; Melot, Brent C.

Using neutron powder diffraction and magnetic susceptibility measurements, we report on the preparation and characterization of the temperature- and field-dependent properties of CaY2ZrFe4O12, a composition closely related to the high-temperature ferrimagnet Y3Fe5O12. By diluting the concentration of paramagnetic ions on the octahedral sublattice of the garnet structure, we find temperature-dependent canting of the magnetic moments. This reflects the importance of the octahedral sublattice in mediating the magnetic interactions between the tetrahedral sites and offers insight into a large number of competing magnetic interactions in the garnet structure.

Research Organization:: Argonne National Laboratory (ANL)

Sponsoring Organization:: Office of Naval Research

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1846202

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 9 Vol. 60; ISSN 0020-1669

Country of Publication:: United States

Language:: English

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