Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution

Milam-Guerrero, JoAnna; Zheng, Michelle; Spence, Nicole R.; Calder, Stuart; Lapidus, Saul; Melot, Brent C.

doi:10.1021/acs.inorgchem.0c03809

Canting of the Magnetic Moments on the Octahedral Site of an Iron Oxide Garnet in Response to Diamagnetic Cation Substitution

Journal Article · Tue Apr 20 00:00:00 EDT 2021 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.0c03809· OSTI ID:1820767

^[1]; Zheng, Michelle ^[1]; Spence, Nicole R. ^[1]; ^[2]; ^[3]; ^[1]

Univ. of Southern California, Los Angeles, CA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Using neutron powder diffraction and magnetic susceptibility measurements, we report on the preparation and characterization of the temperature- and field-dependent properties of CaY₂ZrFe₄O₁₂, a composition closely related to the high-temperature ferrimagnet Y₃Fe₅O₁₂. By diluting the concentration of paramagnetic ions on the octahedral sublattice of the garnet structure, we find temperature-dependent canting of the magnetic moments. Furthermore, this reflects the importance of the octahedral sublattice in mediating the magnetic interactions between the tetrahedral sites and offers insight into a large number of competing magnetic interactions in the garnet structure.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); US Office of Naval Research (ONR)

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

OSTI ID:: 1820767

Alternate ID(s):: OSTI ID: 1846202

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 9 Vol. 60; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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