Advances in supramolecular host-mediated reactivity

Morimoto, Mariko; Bierschenk, Stephen M.; Xia, Kay T.; Bergman, Robert G.; Raymond, Kenneth N.; Toste, F. Dean

doi:10.1038/s41929-020-00528-3

Title: Advances in supramolecular host-mediated reactivity

Journal Article · Wed Nov 25 00:00:00 EST 2020 · Nature Catalysis

DOI:https://doi.org/10.1038/s41929-020-00528-3· OSTI ID:1839003

Morimoto, Mariko ^[1]; Bierschenk, Stephen M. ^[1]; Xia, Kay T. ^[1];

^[1]; Raymond, Kenneth N. ^[1];

^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Since the trailblazing discoveries of Lehn, Cram and Pedersen, supramolecular chemistry has established itself as a cornerstone of organic chemistry. Supramolecular hosts offer defined microenvironments that mimic the active sites of enzymes, utilizing specific host–guest interactions to enable remarkable rate enhancements and product selectivity. The development of a diverse array of self-assembled hosts, coupled with the increased demand for shorter and greener synthetic routes, have spurred significant progress in the field of supramolecular catalysis. This Review Article covers recent advances in the field, ranging from novel organic reactivity aided by supramolecular hosts to catalytic cooperation between hosts and organometallic compounds or metal nanoparticles. Furthermore, strides have also been made in the synthetic application of these hosts in site-selective substrate modifications and challenging photochemical reactions. These efforts have enabled the incorporation of non-covalent macromolecular catalysis in natural product syntheses, evidencing their unique advantages as a synthetic tool, and their powerful potential for practical applications.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1839003

Journal Information:: Nature Catalysis, Vol. 3, Issue 12; ISSN 2520-1158

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

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Tandem Reactivity of a Self-Assembled Cage Catalyst with Endohedral Acid Groups Holloway, Lauren R.; Bogie, Paul M.; Lyon, Yana Journal of the American Chemical Society, Vol. 140, Issue 26 https://doi.org/10.1021/jacs.8b03984	journal	June 2018
Cofactor Controlled Encapsulation of a Rhodium Hydroformylation Catalyst Jongkind, Lukas J.; Elemans, Johannes A. A. W.; Reek, Joost N. H. Angewandte Chemie International Edition, Vol. 58, Issue 9 https://doi.org/10.1002/anie.201812610	journal	February 2019
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Mechanistic Interplay between Light Switching and Guest Binding in Photochromic [Pd ₂ Dithienylethene ₄ ] Coordination Cages Li, Ru-Jin; Holstein, Julian. J.; Hiller, Wolf G. Journal of the American Chemical Society, Vol. 141, Issue 5 https://doi.org/10.1021/jacs.8b11872	journal	January 2019

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