In Situ/Operando (Soft) X-ray Spectroscopy Study of Beyond Lithium-ion Batteries

Yang, Feipeng; Feng, Xuefei; Liu, Y. ‐Sheng; Kao, Li Cheng; Glans, P. ‐A.; Yang, Wanli; Guo, Jinghua

doi:10.1002/eem2.12172

In Situ/Operando (Soft) X-ray Spectroscopy Study of Beyond Lithium-ion Batteries

Journal Article · Fri Apr 02 00:00:00 EDT 2021 · Energy & Environmental Materials

DOI:https://doi.org/10.1002/eem2.12172· OSTI ID:1838430

^[1]; Feng, Xuefei ^[1]; Liu, Y. ‐Sheng ^[1]; Kao, Li Cheng ^[2]; Glans, P. ‐A. ^[2]; ^[2]; ^[3]

Argonne National Lab. (ANL), Lemont, IL (United States). Joint Center for Energy Storage Research (JCESR); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Argonne National Lab. (ANL), Lemont, IL (United States). Joint Center for Energy Storage Research (JCESR); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Univ. of California, Santa Cruz, CA (United States)

The lightweight, rechargeable lithium-ion battery is one of the dominant energy storage devices globally in portable electronics due to its high energy density, no memory effect, wide operating voltage, lightweight, and good charge efficiency. However, due to safety concerns, the depletion of lithium reserves, and the corresponding increase of cost, an alternative battery system becomes more and more desirable. To develop alternative battery systems with low cost and high material abundance, for example, sodium, magnesium, zinc, and calcium, it is important to understand the chemical and electronic structure of materials. Additionally, soft X-ray spectroscopy, for example, X-ray absorption spectroscopy (XAS), X-ray emission spectroscopy (XES), and resonant inelastic soft X-ray scattering (RIXS), is an element-specific technique with sensitivity to the local chemical environment and structural order of the element of interest. Modern soft X-ray systems enable operando experiments that can be applied to amorphous and crystalline samples, making it a powerful tool for studying the electronic and structural changes in electrode and electrolyte species. In this article, the application of in situ/operando (soft) X-ray spectroscopy in beyond lithium-ion batteries is reviewed to demonstrate how such spectroscopic characterizations could facilitate the interpretation of interfacial phenomena under in situ/operando condition and subsequent development of the beyond lithium-ion batteries.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1838430

Journal Information:: Energy & Environmental Materials, Journal Name: Energy & Environmental Materials Journal Issue: 2 Vol. 4; ISSN 2575-0356

Publisher:: Wiley - Zhengzhou UniversityCopyright Statement

Country of Publication:: United States

Language:: English

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Soft X-ray XANES studies of various phases related to LiFePO4 based cathode materials Yang, Songlan; Wang, Dongniu; Liang, Guoxian Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee03445j	journal	January 2012
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Dissociate lattice oxygen redox reactions from capacity and voltage drops of battery electrodes Wu, Jinpeng; Zhuo, Zengqing; Rong, Xiaohui Science Advances, Vol. 6, Issue 6 https://doi.org/10.1126/sciadv.aaw3871	journal	February 2020
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Solvated Ion Intercalation in Graphite: Sodium and Beyond Park, Jooha; Xu, Zheng-Long; Kang, Kisuk Frontiers in Chemistry, Vol. 8 https://doi.org/10.3389/fchem.2020.00432	journal	May 2020
Understanding and Overcoming the Challenges Posed by Electrode/Electrolyte Interfaces in Rechargeable Magnesium Batteries Mizuno, Fuminori; Singh, Nikhilendra; Arthur, Timothy S. Frontiers in Energy Research, Vol. 2 https://doi.org/10.3389/fenrg.2014.00046	journal	November 2014
Fingerprint Oxygen Redox Reactions in Batteries through High-Efficiency Mapping of Resonant Inelastic X-ray Scattering Wu, Jinpeng; Li, Qinghao; Sallis, Shawn Condensed Matter, Vol. 4, Issue 1 https://doi.org/10.3390/condmat4010005	journal	January 2019
Beyond Lithium-Based Batteries Biemolt, Jasper; Jungbacker, Peter; van Teijlingen, Tess Materials, Vol. 13, Issue 2 https://doi.org/10.3390/ma13020425	journal	January 2020

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