Controlled Demolition and Reconstruction of Imidazolate and Carboxylate Metal–Organic Frameworks by Acid Gas Exposure and Linker Treatment

Ganesan, Arvind; Purdy, Stephen C.; Yu, Zhenzi; Bhattacharyya, Souryadeep; Page, Katharine; Sholl, David S.; Nair, Sankar

doi:10.1021/acs.iecr.1c03296

Controlled Demolition and Reconstruction of Imidazolate and Carboxylate Metal–Organic Frameworks by Acid Gas Exposure and Linker Treatment

Journal Article · Thu Oct 21 00:00:00 EDT 2021 · Industrial and Engineering Chemistry Research

DOI:https://doi.org/10.1021/acs.iecr.1c03296· OSTI ID:1831612

^[1]; ^[2]; Yu, Zhenzi ^[1]; Bhattacharyya, Souryadeep ^[1]; ^[3]; ^[1]; ^[1]

Georgia Inst. of Technology, Atlanta, GA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

The metal-linker coordination bond in metal–organic frameworks (MOFs) can be unstable in humid and acid gas environments, leading to loss of crystallinity and porosity. This degradation is not necessarily irreversible; solvent-assisted crystal redemption (“SACRed”) has been shown to recover the physical and chemical properties of ZIF-8 exposed to humid SO₂. This approach can also be useful in creating mixed-linker materials that might be challenging to produce via de novo synthesis. Here, we expand more generally the concept of controlled degradation of a MOF with acid gas, followed by treatment with a fresh linker solution, to the use of different template MOFs (ZIFs, UiO-66, and UiO-67) and acid gases (SO₂ and NO₂ in dry and humid conditions). Significant losses in porosity and crystallinity along with structural changes (acid gas-linker complexes and linker functionalizations) are observed in the acid gas-exposed MOF templates, and SACRed is shown to reconstruct these partially demolished MOFs with a high degree of structural recovery. Detailed structural and spectroscopic characterizations of the controlled degradation and subsequent recovery are presented and analyzed. Furthermore, these findings indicate the generality of controlled degradation and reconstruction as a means for linker replacement in a wider variety of MOFs and also create the potential for linker substitutions (with non-native linkers) to obtain new hybrid MOFs.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1831612

Alternate ID(s):: OSTI ID: 1837265

Journal Information:: Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 43 Vol. 60; ISSN 0888-5885

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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