Recovery of Acid-Gas-Degraded Zeolitic Imidazolate Frameworks by Solvent-Assisted Crystal Redemption (SACRed)

Jayachandrababu, Krishna C.; Bhattacharyya, Souryadeep; Chiang, Yadong; Sholl, David S.; Nair, Sankar

doi:10.1021/acsami.7b11686

Recovery of Acid-Gas-Degraded Zeolitic Imidazolate Frameworks by Solvent-Assisted Crystal Redemption (SACRed)

Journal Article · Tue Sep 26 00:00:00 EDT 2017 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.7b11686· OSTI ID:1469889

Jayachandrababu, Krishna C. ^[1]; Bhattacharyya, Souryadeep ^[1]; Chiang, Yadong ^[1]; ^[1]; ^[1]

Georgia Inst. of Technology, Atlanta, GA (United States). School of Chemical & Biomolecular Engineering

The acid stability of zeolitic imidazolate frameworks (ZIFs) is an important issue hindering their application. Acid-gas damage of ZIFs has been considered irreversible. However, we demonstrate here a methodology called solvent-assisted crystal redemption (SACRed) to reverse acid-gas damage to ZIFs with a high degree of structural and functional recovery. For example, post-SACRed ZIF-8 is shown to be structurally and chemically near-identical with the original pristine ZIF-8 that suffered a large loss of surface area, porosity, and crystallinity during acid-gas exposure. We also provide mechanistic insight into the recovery process using deuterium-labeled linkers and ²H NMR spectroscopy. SACRed treatments could allow large extensions in the lifetime of ZIF-based membranes and adsorbents that degrade over time.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012577

OSTI ID:: 1469889

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 40 Vol. 9; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
MOFs
ZIFs
acid gas
carbon capture
catalysis (heterogeneous)
defects
degradation
materials and chemistry by design
membrane
recovery
synthesis (novel materials)
synthesis (scalable processing)
synthesis (self-assembly)

Recovery of Acid-Gas-Degraded Zeolitic Imidazolate Frameworks by Solvent-Assisted Crystal Redemption (SACRed)

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