Multifunctional Prussian blue analogue magnets: Emerging opportunities

Huang, Yulong; Ren, Shenqiang

doi:10.1016/j.apmt.2020.100886

Multifunctional Prussian blue analogue magnets: Emerging opportunities

Journal Article · Fri Nov 27 00:00:00 EST 2020 · Applied Materials Today

DOI:https://doi.org/10.1016/j.apmt.2020.100886· OSTI ID:1830696

Huang, Yulong ^[1]; Ren, Shenqiang ^[2]

Univ. at Buffalo, NY (United States); University at Buffalo
Univ. at Buffalo, NY (United States)

There is a surge of interest to expand the search for entirely new classes of molecular magnets as the emergence of information storage and quantum computing devices. Prussian blue analogues as a family of molecular magnets are especially attracting wide attention due to their large number of derivatives with a range of magnetic ordering temperature from cryogenic to high temperature. Furthermore, this review presents Prussian blue analogues as multifunctional molecular magnets, which involves the development of molecular magnet syntheses and crystal structures, and magnetic properties under external stimuli. In addition, the porous network structures and vacancy order of Prussian blue analogues present a wide capability to interact with water molecules and gas adsorption. External stimuli, such as thermal, pressure, electric and magnetic field and photoexcitation, play an important role in controlling the hidden states and cooperative phenomena of high temperature molecular magnets based on Prussian blue analogues.

View Accepted Manuscript (DOE)

Research Organization:: Univ. at Buffalo, NY (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: SC0018631

OSTI ID:: 1830696

Alternate ID(s):: OSTI ID: 1781259

Journal Information:: Applied Materials Today, Journal Name: Applied Materials Today Vol. 22; ISSN 2352-9407

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (116)

Enhancement of the Magnetic Ordering Temperature and Air Stability of a Mixed Valent Vanadium Hexacyanochromate(III) Magnet to 99 °C (372 K) Hatlevik, Øyvind; Buschmann, Wayne E.; Zhang, Jie Advanced Materials, Vol. 11, Issue 11 https://doi.org/10.1002/(SICI)1521-4095(199908)11:11<914::AID-ADMA914>3.0.CO;2-T	journal	August 1999
Prussian Blue and Its Analogues: Electrochemistry and Analytical Applications Karyakin, Arkady A. Electroanalysis, Vol. 13, Issue 10 https://doi.org/10.1002/1521-4109(200106)13:10<813::AID-ELAN813>3.0.CO;2-Z	journal	June 2001
Progress in Applications of Prussian Blue Nanoparticles in Biomedicine Qin, Zhiguo; Li, Yan; Gu, Ning Advanced Healthcare Materials, Vol. 7, Issue 20 https://doi.org/10.1002/adhm.201800347	journal	July 2018
Magnetic Materials and Devices for the 21st Century: Stronger, Lighter, and More Energy Efficient Gutfleisch, Oliver; Willard, Matthew A.; Brück, Ekkes Advanced Materials, Vol. 23, Issue 7 https://doi.org/10.1002/adma.201002180	journal	December 2010
Adjustable Zero Thermal Expansion in Antiperovskite Manganese Nitride Song, Xiaoyan; Sun, Zhonghua; Huang, Qingzhen Advanced Materials, Vol. 23, Issue 40 https://doi.org/10.1002/adma.201102552	journal	September 2011
Thermally Induced Electron Transfer in a CsCoFe Prussian Blue Derivative: The Specific Role of the Alkali-Metal Ion Bleuzen, Anne; Escax, Virginie; Ferrier, Alban Angewandte Chemie International Edition, Vol. 43, Issue 28 https://doi.org/10.1002/anie.200460086	journal	July 2004
Negative Thermal Expansion in LnCo(CN) ₆ (Ln=La, Pr, Sm, Ho, Lu, Y): Mechanisms and Compositional Trends Duyker, Samuel G.; Peterson, Vanessa K.; Kearley, Gordon J. Angewandte Chemie International Edition, Vol. 52, Issue 20 https://doi.org/10.1002/anie.201300619	journal	April 2013
Switching Between Giant Positive and Negative Thermal Expansions of a YFe(CN) ₆ -based Prussian Blue Analogue Induced by Guest Species Gao, Qilong; Chen, Jun; Sun, Qiang Angewandte Chemie International Edition, Vol. 56, Issue 31 https://doi.org/10.1002/anie.201702955	journal	June 2017
Kinetically Controlled Crystallization for Synthesis of Monodispersed Coordination Polymer Nanocubes and Their Self-Assembly to Periodic Arrangements Hu, Ming; Ishihara, Shinsuke; Ariga, Katsuhiko Chemistry - A European Journal, Vol. 19, Issue 6 https://doi.org/10.1002/chem.201203138	journal	January 2013
Single Crystal of a Prussian Blue Analog based on Rubidium Manganese Hexacyanoferrate Tokoro, Hiroko; Shiro, Motoo; Hashimoto, Kazuhito Zeitschrift für anorganische und allgemeine Chemie, Vol. 633, Issue 8 https://doi.org/10.1002/zaac.200700129	journal	July 2007
Porous phosphorus-rich CoP3/CoSnO2 hybrid nanocubes for high-performance Zn-air batteries Li, Bing; Xue, Huaiguo; Pang, Huan Science China Chemistry, Vol. 63, Issue 4 https://doi.org/10.1007/s11426-020-9700-8	journal	March 2020
What a chemistry student should know about the history of Prussian blue Kraft, Alexander ChemTexts, Vol. 4, Issue 4 https://doi.org/10.1007/s40828-018-0071-2	journal	October 2018
Ordered bimetallic ferromagnets of chromium(III): [Cr(NH3)6][Cr(CN)6], [Cr(H2O)(NH3)5][Cr(CN)6], and trans-[Cr(en)2(H2O)2]trans-[Cr(en)2(OH)F]2(CIO4)5·2H2O Burriel, Ramón; Casabó, Jaime; Pons, Josefina Physica B+C, Vol. 132, Issue 2 https://doi.org/10.1016/0378-4363(85)90064-6	journal	July 1985
Molecules to build solids: high TC molecule-based magnets by design and recent revival of cyano complexes chemistry Verdaguer, Michel; Bleuzen, A.; Marvaud, V. Coordination Chemistry Reviews, Vol. 190-192 https://doi.org/10.1016/S0010-8545(99)00156-3	journal	September 1999
Amorphous cobalt phosphate porous nanosheets derived from two-dimensional cobalt phosphonate organic frameworks for high performance of oxygen evolution reaction Guo, Xiaowen; Xu, Yuxia; Cheng, Yan Applied Materials Today, Vol. 18 https://doi.org/10.1016/j.apmt.2019.100517	journal	March 2020
Sensor and biosensor preparation, optimisation and applications of Prussian Blue modified electrodes Ricci, F.; Palleschi, G. Biosensors and Bioelectronics, Vol. 21, Issue 3 https://doi.org/10.1016/j.bios.2004.12.001	journal	September 2005
Recent advances in Prussian blue and Prussian blue analogues: synthesis and thermal treatments Zakaria, Mohamed B.; Chikyow, Toyohiro Coordination Chemistry Reviews, Vol. 352 https://doi.org/10.1016/j.ccr.2017.09.014	journal	December 2017
Prussian blue analogues and their derived nanomaterials for electrocatalytic water splitting Cao, Li-Ming; Lu, David; Zhong, Di-Chang Coordination Chemistry Reviews, Vol. 407 https://doi.org/10.1016/j.ccr.2019.213156	journal	March 2020
Construction of Single-Crystalline Prussian Blue Analog Hollow Nanostructures with Tailorable Topologies Nai, Jianwei; Zhang, Jintao; Lou, Xiong Wen (David) Chem, Vol. 4, Issue 8 https://doi.org/10.1016/j.chempr.2018.07.001	journal	August 2018
Prussian blue and its derivatives as electrode materials for electrochemical energy storage Xu, Yuxia; Zheng, Shasha; Tang, Hanfei Energy Storage Materials, Vol. 9 https://doi.org/10.1016/j.ensm.2017.06.002	journal	October 2017
Prussian Blue Analogs for Rechargeable Batteries Wang, Baoqi; Han, Yu; Wang, Xiao iScience, Vol. 3 https://doi.org/10.1016/j.isci.2018.04.008	journal	May 2018
Morphology syntheses and properties of well-defined Prussian Blue nanocrystals by a facile solution approach Shen, Xiaoping; Wu, Shikui; Liu, Yan Journal of Colloid and Interface Science, Vol. 329, Issue 1 https://doi.org/10.1016/j.jcis.2008.09.067	journal	January 2009
Review of pore network modelling of porous media: Experimental characterisations, network constructions and applications to reactive transport Xiong, Qingrong; Baychev, Todor G.; Jivkov, Andrey P. Journal of Contaminant Hydrology, Vol. 192 https://doi.org/10.1016/j.jconhyd.2016.07.002	journal	September 2016
Organic- and molecule-based magnets Miller, Joel S. Materials Today, Vol. 17, Issue 5 https://doi.org/10.1016/j.mattod.2014.04.023	journal	June 2014
Growth Mechanisms of Mesoscale Prussian Blue Analogue Particles in Modifier-free Synthesis Liang, Jiamin; Li, Carissa H.; Talham, Daniel R. Crystal Growth & Design, Vol. 20, Issue 4 https://doi.org/10.1021/acs.cgd.0c00115	journal	March 2020
Neutron Diffraction and EXAFS Studies of K _{2 x /3} Cu[Fe(CN) ₆ ] _2/3 · n H ₂ O Wardecki, Dariusz; Ojwang, Dickson O.; Grins, Jekabs Crystal Growth & Design, Vol. 17, Issue 3 https://doi.org/10.1021/acs.cgd.6b01684	journal	January 2017
Low-Frequency Phonon Driven Negative Thermal Expansion in Cubic GaFe(CN) ₆ Prussian Blue Analogues Gao, Qilong; Shi, Naike; Sun, Qiang Inorganic Chemistry, Vol. 57, Issue 17 https://doi.org/10.1021/acs.inorgchem.8b01526	journal	August 2018
Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN) ₆ Gao, Qilong; Shi, Naike; Sanson, Andrea Inorganic Chemistry, Vol. 57, Issue 22 https://doi.org/10.1021/acs.inorgchem.8b02428	journal	October 2018
Intramolecular Electron Transfers in a Series of [Co ₂ Fe ₂ ] Tetranuclear Complexes Nihei, Masayuki; Shiroyanagi, Karin; Kato, Marina Inorganic Chemistry, Vol. 58, Issue 18 https://doi.org/10.1021/acs.inorgchem.9b00776	journal	June 2019
Negative Thermal Expansion and Phase Transitions in the ZrV2-xPxO7 Series Korthuis, V.; Khosrovani, N.; Sleight, A. W. Chemistry of Materials, Vol. 7, Issue 2 https://doi.org/10.1021/cm00050a028	journal	February 1995
Metal Hexacyanoferrates: Electrosynthesis, in Situ Characterization, and Applications de Tacconi, Norma R.; Rajeshwar, Krishnan; Lezna, Reynaldo O. Chemistry of Materials, Vol. 15, Issue 16 https://doi.org/10.1021/cm0341540	journal	July 2003
Light- and Temperature-Induced Electron Transfer in Single Crystals of RbMn[Fe(CN) ₆ ]·H ₂ O Vertelman, Esther J. M.; Lummen, Tom T. A.; Meetsma, Auke Chemistry of Materials, Vol. 20, Issue 4 https://doi.org/10.1021/cm7032965	journal	January 2008
Hydrogen Storage in Prussian Blue Analogues: H ₂ Interaction with the Metal Found at the Cavity Surface Krap, C. P.; Balmaseda, J.; del Castillo, L. F. Energy & Fuels, Vol. 24, Issue 1 https://doi.org/10.1021/ef900823s	journal	January 2010
A Prussian-Blue Type Ferrimagnet Na[MnCr(CN) ₆ ]: Single Crystal Structure and Magnetic Properties Dong, Wen; Zhu, Li-Na; Song, Hai-Bin Inorganic Chemistry, Vol. 43, Issue 8 https://doi.org/10.1021/ic0352710	journal	April 2004
Size and Surface Effects of Prussian Blue Nanoparticles Protected by Organic Polymers Uemura, Takashi; Ohba, Masaaki; Kitagawa, Susumu Inorganic Chemistry, Vol. 43, Issue 23 https://doi.org/10.1021/ic0488435	journal	November 2004
Tuning the Magnetic Behavior via Dehydration/Hydration Treatment of a New Ferrimagnet with the Composition of K _0.2 Mn _1.4 Cr(CN) ₆ ·6H ₂ O Lü, Zhengliang; Wang, Xinyi; Liu, Zhiliang Inorganic Chemistry, Vol. 45, Issue 3 https://doi.org/10.1021/ic051145f	journal	February 2006
Photomagnetic K _0.25 Ni _{1– x} Co _x [Fe(CN) ₆ ]· n H ₂ O and K _0.25 Co[Fe(CN) ₆ ] _{0.75 y} [Cr(CN) ₆ ] _{0.75(1– y )} · n H ₂ O Prussian Blue Analogue Solid Solutions Pajerowski, Daniel M.; Yamamoto, Takashi; Einaga, Yasuaki Inorganic Chemistry, Vol. 51, Issue 6 https://doi.org/10.1021/ic202571d	journal	March 2012
Structural chemistry of Prussian blue analogs. Single-crystal study of manganese(II) hexacyanocobaltate(III), Mn3[Co(DcN)6]2.xH2O Ludi, Andreas; Guedel, Hans U.; Ruegg, Max Inorganic Chemistry, Vol. 9, Issue 10 https://doi.org/10.1021/ic50092a005	journal	October 1970
Prussian blues Wilde, Richard E.; Ghosh, Surendra Nath; Marshall, Billy J. Inorganic Chemistry, Vol. 9, Issue 11 https://doi.org/10.1021/ic50093a027	journal	November 1970
The crystal structure of Prussian Blue: Fe4[Fe(CN)6]3.xH2O Buser, H. J.; Schwarzenbach, D.; Petter, W. Inorganic Chemistry, Vol. 16, Issue 11, p. 2704-2710 https://doi.org/10.1021/ic50177a008	journal	November 1977
Neutron diffraction study of Prussian Blue, Fe4[Fe(CN)6]3.xH2O. Location of water molecules and long-range magnetic order Herren, F.; Fischer, P.; Ludi, A. Inorganic Chemistry, Vol. 19, Issue 4 https://doi.org/10.1021/ic50206a032	journal	April 1980
Ferrimagnetic Mixed-Valency and Mixed-Metal Tris(oxalato)iron(III) Compounds: Synthesis, Structure, and Magnetism Mathonière, Corine; Nuttall, Christopher J.; Carling, Simon G. Inorganic Chemistry, Vol. 35, Issue 5 https://doi.org/10.1021/ic950703v	journal	January 1996
X-ray Diffraction Studies on Heavy-metal Iron-cyanides Weiser, Harry B.; Milligan, W. O.; Bates, J. B. The Journal of Physical Chemistry, Vol. 46, Issue 1 https://doi.org/10.1021/j150415a013	journal	January 1942
Photoinduced Ferrimagnetic Systems in Prussian Blue Analogues C ^I _x Co ₄ [Fe(CN) ₆ ] _y (C ^I = Alkali Cation). 1. Conditions to Observe the Phenomenon Bleuzen, Anne; Lomenech, Claire; Escax, Virginie Journal of the American Chemical Society, Vol. 122, Issue 28 https://doi.org/10.1021/ja000348u	journal	July 2000
High-TC molecular-based magnets: a ferromagnetic bimetallic chromium(III)-nickel(II) cyanide with TC = 90 K Gadet, V.; Mallah, T.; Castro, I. Journal of the American Chemical Society, Vol. 114, Issue 23 https://doi.org/10.1021/ja00049a078	journal	November 1992
Expanded Prussian Blue Analogues Incorporating [Re ₆ Se ₈ (CN) ₆ ] ^3-/4- Clusters: Adjusting Porosity via Charge Balance Bennett, Miriam V.; Beauvais, Laurance G.; Shores, Matthew P. Journal of the American Chemical Society, Vol. 123, Issue 33 https://doi.org/10.1021/ja0110473	journal	August 2001
Photoinduced Ferrimagnetic Systems in Prussian Blue Analogues C ^I _x Co ₄ [Fe(CN) ₆ ] _y (C ^I = Alkali Cation). 4. Characterization of the Ferrimagnetism of the Photoinduced Metastable State in Rb _1.8 Co ₄ [Fe(CN) ₆ ] _3.3 ·13H ₂ O by K Edges X-ray Magnetic Circular Dichroism Champion, Guillaume; Escax, Virginie; Cartier dit Moulin, Christophe Journal of the American Chemical Society, Vol. 123, Issue 50 https://doi.org/10.1021/ja011297j	journal	November 2001
Molecule-Based Room-Temperature Magnets: Catalytic Role of V(III) in the Synthesis of Vanadium−Chromium Prussian Blue Analogues Garde, Raquel; Villain, Françoise; Verdaguer, Michel Journal of the American Chemical Society, Vol. 124, Issue 35 https://doi.org/10.1021/ja020528z	journal	August 2002
Pressure-Tuning of Magnetism and Linkage Isomerism in Iron(II) Hexacyanochromate Coronado, Eugenio; Giménez-López, Mari Carmen; Levchenko, Georgiy Journal of the American Chemical Society, Vol. 127, Issue 13 https://doi.org/10.1021/ja043166z	journal	April 2005
Zero Thermal Expansion in a Prussian Blue Analogue Margadonna, Serena; Prassides, Kosmas; Fitch, Andrew N. Journal of the American Chemical Society, Vol. 126, Issue 47 https://doi.org/10.1021/ja044959o	journal	December 2004
Crystalline, Mixed-Valence Manganese Analogue of Prussian Blue: Magnetic, Spectroscopic, X-ray and Neutron Diffraction Studies Franz, Patrick; Ambrus, Christina; Hauser, Andreas Journal of the American Chemical Society, Vol. 126, Issue 50 https://doi.org/10.1021/ja0465451	journal	December 2004
Hydrogen Storage in the Dehydrated Prussian Blue Analogues M ₃ [Co(CN) ₆ ] ₂ (M = Mn, Fe, Co, Ni, Cu, Zn) Kaye, Steven S.; Long, Jeffrey R. Journal of the American Chemical Society, Vol. 127, Issue 18 https://doi.org/10.1021/ja051168t	journal	May 2005
Guest-Dependent Negative Thermal Expansion in Nanoporous Prussian Blue Analogues M ^II Pt ^IV (CN) ₆ · x {H ₂ O} (0 ≤ x ≤ 2; M = Zn, Cd) Goodwin, Andrew L.; Chapman, Karena W.; Kepert, Cameron J. Journal of the American Chemical Society, Vol. 127, Issue 51 https://doi.org/10.1021/ja056460f	journal	December 2005
Compositional Dependence of Negative Thermal Expansion in the Prussian Blue Analogues M ^II Pt ^IV (CN) ₆ (M = Mn, Fe, Co, Ni, Cu, Zn, Cd) Chapman, Karena W.; Chupas, Peter J.; Kepert, Cameron J. Journal of the American Chemical Society, Vol. 128, Issue 21 https://doi.org/10.1021/ja060916r	journal	May 2006
Pressure-Induced Sequential Magnetic Pole Inversion and Antiferromagnetic−Ferromagnetic Crossover in a Trimetallic Prussian Blue Analogue Egan, Lindsay; Kamenev, Konstantin; Papanikolaou, Dionisis Journal of the American Chemical Society, Vol. 128, Issue 18 https://doi.org/10.1021/ja061514m	journal	May 2006
Reversible Water-Induced Magnetic and Structural Conversion of a Flexible Microporous Ni(II)Fe(III) Ferromagnet Yanai, Nobuhiro; Kaneko, Wakako; Yoneda, Ko Journal of the American Chemical Society, Vol. 129, Issue 12 https://doi.org/10.1021/ja069166b	journal	March 2007
Magnetic and Optical Bistability Driven by Thermally and Photoinduced Intramolecular Electron Transfer in a Molecular Cobalt−Iron Prussian Blue Analogue Li, Dongfeng; Clérac, Rodolphe; Roubeau, Olivier Journal of the American Chemical Society, Vol. 130, Issue 1 https://doi.org/10.1021/ja0757632	journal	January 2008
Persistent Photoinduced Magnetism in Heterostructures of Prussian Blue Analogues Pajerowski, Daniel M.; Andrus, Matthew J.; Gardner, Justin E. Journal of the American Chemical Society, Vol. 132, Issue 12 https://doi.org/10.1021/ja100246n	journal	March 2010
Generation and O ₂ Adsorption Studies of the Microporous Magnets CsNi[Cr(CN) ₆ ] ( T _C = 75 K) and Cr ₃ [Cr(CN) ₆ ] ₂ ·6H ₂ O ( T _N = 219 K) Kaye, Steven S.; Choi, Hye Jin; Long, Jeffrey R. Journal of the American Chemical Society, Vol. 130, Issue 50 https://doi.org/10.1021/ja803926y	journal	November 2008
Tuning the Sign of Photoinduced Changes in Magnetization: Spin Transitions in the Ternary Metal Prussian Blue Analogue Na _α Ni _{1− x} Co _x [Fe(CN) ₆ ] _β · n H ₂ O Pajerowski, Daniel M.; Gardner, Justin E.; Talham, Daniel R. Journal of the American Chemical Society, Vol. 131, Issue 36 https://doi.org/10.1021/ja9012672	journal	August 2009
Electric-Field-Induced Charge-Transfer Phase Transition: A Promising Approach Toward Electrically Switchable Devices Mahfoud, Tarik; Molnár, Gábor; Bonhommeau, Sébastien Journal of the American Chemical Society, Vol. 131, Issue 41 https://doi.org/10.1021/ja9055855	journal	October 2009
Zero Thermal Expansion in a Flexible, Stable Framework: Tetramethylammonium Copper(I) Zinc(II) Cyanide Phillips, Anthony E.; Halder, Gregory J.; Chapman, Karena W. Journal of the American Chemical Society, Vol. 132, Issue 1 https://doi.org/10.1021/ja906895j	journal	January 2010
Sol−Gel Synthesis of KV ^II [Cr ^III (CN) ₆ ]·2H ₂ O: A Crystalline Molecule-Based Magnet with a Magnetic Ordering Temperature above 100 °C Holmes, Stephen M.; Girolami, Gregory S. Journal of the American Chemical Society, Vol. 121, Issue 23 https://doi.org/10.1021/ja990946c	journal	June 1999
Strong Negative Thermal Expansion in a Low-Cost and Facile Oxide of Cu ₂ P ₂ O ₇ Shi, Naike; Sanson, Andrea; Gao, Qilong Journal of the American Chemical Society, Vol. 142, Issue 6 https://doi.org/10.1021/jacs.9b12442	journal	January 2020
Metal(II) Hexacyanochromate(III) MCr (M = Co, Cu, Fe) Coordination Nanoparticles Stabilized by Alkyl Surface Coordination Ligand: Downsizing Effect on Their Crystal Structure and Magnetic Properties Arai, Masaya; Miyake, Mikio; Yamada, Mami The Journal of Physical Chemistry C, Vol. 112, Issue 6 https://doi.org/10.1021/jp709889v	journal	February 2008
Cation-Driven Electron Transfer Involving a Spin Transition at Room Temperature in a Cobalt Iron Cyanide Thin Film Sato, O.; Einaga, Y.; Iyoda, T. The Journal of Physical Chemistry B, Vol. 101, Issue 20 https://doi.org/10.1021/jp9701451	journal	May 1997
Structures and Formulæ of the Prussian Blues and Related Compounds Keggin, J. F.; Miles, F. D. Nature, Vol. 137, Issue 3466 https://doi.org/10.1038/137577a0	journal	April 1936
Magnetic bistability in a metal-ion cluster Sessoli, R.; Gatteschi, D.; Caneschi, A. Nature, Vol. 365, Issue 6442 https://doi.org/10.1038/365141a0	journal	September 1993
A room-temperature organometallic magnet based on Prussian blue Ferlay, S.; Mallah, T.; Ouahès, R. Nature, Vol. 378, Issue 6558 https://doi.org/10.1038/378701a0	journal	December 1995
Macroscopic quantum tunnelling of magnetization in a single crystal of nanomagnets Thomas, L.; Lionti, F.; Ballou, R. Nature, Vol. 383, Issue 6596 https://doi.org/10.1038/383145a0	journal	September 1996
Zero thermal expansion in YbGaGe due to an electronic valence transition Salvador, James R.; Guo, Fu; Hogan, Tim Nature, Vol. 425, Issue 6959 https://doi.org/10.1038/nature02011	journal	October 2003
Humidity-induced magnetization and magnetic pole inversion in a cyano-bridged metal assembly Ohkoshi, Shin-ichi; Arai, Ken-ichi; Sato, Yusuke Nature Materials, Vol. 3, Issue 12 https://doi.org/10.1038/nmat1260	journal	November 2004
Hidden diversity of vacancy networks in Prussian blue analogues Simonov, Arkadiy; De Baerdemaeker, Trees; Boström, Hanna L. B. Nature, Vol. 578, Issue 7794 https://doi.org/10.1038/s41586-020-1980-y	journal	February 2020
Ferromagnetic properties of one-dimensional decamethylferrocenium tetracyanoethylenide (1 : 1): [Fe(η ⁵ -C ₅ Me ₅ ) ₂ ]˙ ⁺ [TCNE]˙ ^– Miller, Joel S.; Calabrese, Joseph C.; Epstein, Arthur J. J. Chem. Soc., Chem. Commun., Issue 13 https://doi.org/10.1039/C39860001026	journal	January 1986
Switchable Fe/Co Prussian blue networks and molecular analogues Aguilà, David; Prado, Yoann; Koumousi, Evangelia S. Chemical Society Reviews, Vol. 45, Issue 1 https://doi.org/10.1039/C5CS00321K	journal	January 2016
New faces of porous Prussian blue: interfacial assembly of integrated hetero-structures for sensing applications Kong, Biao; Selomulya, Cordelia; Zheng, Gengfeng Chemical Society Reviews, Vol. 44, Issue 22 https://doi.org/10.1039/C5CS00397K	journal	January 2015
Characterization and utilization of Prussian blue and its pigments Grandjean, Fernande; Samain, Louise; Long, Gary J. Dalton Transactions, Vol. 45, Issue 45 https://doi.org/10.1039/C6DT03351B	journal	January 2016
Facile preparation of Prussian blue analogue Co ₃ [Co(CN) ₆ ] ₂ with fine-tuning color transition temperature as thermochromic material Zhang, Hong; Li, Cheng; Chen, Dairong CrystEngComm, Vol. 19, Issue 15 https://doi.org/10.1039/C7CE00384F	journal	January 2017
Negative thermal expansion in cubic FeFe(CN) ₆ Prussian blue analogues Shi, Naike; Gao, Qilong; Sanson, Andrea Dalton Transactions, Vol. 48, Issue 11 https://doi.org/10.1039/C8DT05111A	journal	January 2019
Unveiling Cs-adsorption mechanism of Prussian blue analogs: Cs ⁺ -percolation via vacancies to complete dehydrated state Takahashi, Akira; Tanaka, Hisashi; Minami, Kimitaka RSC Advances, Vol. 8, Issue 61 https://doi.org/10.1039/C8RA06377J	journal	January 2018
Concentration as a trigger to improve electrocatalytic activity of a Prussian blue analogue in glucose oxidation Zhao, Zhimin; Ding, Jiawei; Zhou, Huijie CrystEngComm, Vol. 21, Issue 36 https://doi.org/10.1039/C9CE00947G	journal	January 2019
Spontaneous precipitation pattern formation by crystallites of Mn–Fe-based Prussian blue analogues in agarose gel Hayashi, Hisashi; Aoki, Saya; Suzuki, Tomoko RSC Advances, Vol. 9, Issue 62 https://doi.org/10.1039/C9RA07960B	journal	January 2019
Magnetically ordered molecule-based materials Miller, Joel S. Chemical Society Reviews, Vol. 40, Issue 6 https://doi.org/10.1039/c0cs00166j	journal	January 2011
Single-crystal study of Prussian Blue: Fe4[Fe(CN)6]2, 14H2O Buser, H. J.; Ludi, A.; Petter, W. Journal of the Chemical Society, Chemical Communications, Issue 23 https://doi.org/10.1039/c39720001299	journal	January 1972
Proton-exchange mechanism of specific Cs+ adsorption via lattice defect sites of Prussian blue filled with coordination and crystallization water molecules Ishizaki, M.; Akiba, S.; Ohtani, A. Dalton Transactions, Vol. 42, Issue 45 https://doi.org/10.1039/c3dt51637g	journal	January 2013
Mössbauer Study of Soluble Prussian Blue, Insoluble Prussian Blue, and Turnbull's Blue Ito, A.; Suenaga, M.; Ôno, K. The Journal of Chemical Physics, Vol. 48, Issue 8 https://doi.org/10.1063/1.1669656	journal	April 1968
Zero thermal expansion in a pure-form antiperovskite manganese nitride Takenaka, K.; Takagi, H. Applied Physics Letters, Vol. 94, Issue 13 https://doi.org/10.1063/1.3110046	journal	March 2009
Magnetization behavior of (NBu4)2Mn2[Cu(opba)]3 and related solvated ferromagnets Chavan, S. A.; Ganguly, R.; Jain, V. K. Journal of Applied Physics, Vol. 79, Issue 8 https://doi.org/10.1063/1.361304	journal	January 1996
A study of the ferrimagnetic ordering of the complex bimetallic salt hexaaminechromium (III) hexachloroferrate (III), [Cr (NH ₃ ) ₆ ] [FeCl ₆ ] Helms, Jeffrey H.; Hatfield, William E.; Kwiecien, Michael J. The Journal of Chemical Physics, Vol. 84, Issue 7 https://doi.org/10.1063/1.450109	journal	April 1986
Magnetic field driven transition from an antiferromagnetic ground state to a ferrimagnetic state in Rb _0.19 Ba _0.3 Mn _1.1 [Fe(CN) ₆ ]·0.48H ₂ O Prussian blue analogue Yusuf, S. M.; Thakur, N.; Medarde, M. Journal of Applied Physics, Vol. 112, Issue 9 https://doi.org/10.1063/1.4759361	journal	November 2012
A history of Prussian blue Coleby, L. J. M. Annals of Science, Vol. 4, Issue 2 https://doi.org/10.1080/00033793900201211	journal	April 1939
Morphologies and Magnetic Properties of Cobalt-Iron Prussian Blue Analogues Nanoparticles Synthesized in Microemulsion Liu, Hui; Du, Xianlong; Liang, Chuanhui Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, Vol. 40, Issue 10 https://doi.org/10.1080/15533174.2010.522547	journal	November 2010
A highly alkaline-stable metal oxide@metal–organic framework composite for high-performance electrochemical energy storage Zheng, Shasha; Li, Qing; Xue, Huaiguo National Science Review, Vol. 7, Issue 2 https://doi.org/10.1093/nsr/nwz137	journal	September 2019
Spin-3/2 Iron Ferromagnet: Its Mössbauer and Magnetic Properties Wickman, H. H.; Trozzolo, A. M.; Williams, H. J. Physical Review, Vol. 155, Issue 2 https://doi.org/10.1103/PhysRev.155.563	journal	March 1967
Magnetic properties of mixed ferro-ferrimagnets composed of Prussian blue analogs Ohkoshi, Shin-ichi; Iyoda, Tomokazu; Fujishima, Akira Physical Review B, Vol. 56, Issue 18 https://doi.org/10.1103/PhysRevB.56.11642	journal	November 1997
Photoinduced phase transition of RbMnFe ( CN ) 6 studied by x-ray-absorption fine structure spectroscopy Yokoyama, Toshihiko; Tokoro, Hiroko; Ohkoshi, Shin-ichi Physical Review B, Vol. 66, Issue 18 https://doi.org/10.1103/PhysRevB.66.184111	journal	November 2002
Pressure-induced electron transfer in ferrimagnetic Prussian blue analogs Ksenofontov, Vadim; Levchenko, Georgiy; Reiman, Sergey Physical Review B, Vol. 68, Issue 2 https://doi.org/10.1103/PhysRevB.68.024415	journal	July 2003
Pressure- and photoinduced transformation into a metastable phase in RbMn [ Fe ( CN ) 6 ] Moritomo, Y.; Hanawa, M.; Ohishi, Y. Physical Review B, Vol. 68, Issue 14 https://doi.org/10.1103/PhysRevB.68.144106	journal	October 2003
Negative thermal expansion and low-frequency modes in cyanide-bridged framework materials Goodwin, Andrew L.; Kepert, Cameron J. Physical Review B, Vol. 71, Issue 14 https://doi.org/10.1103/PhysRevB.71.140301	journal	April 2005
Optical control of magnetization in a room-temperature magnet: V-Cr Prussian blue analog Bozdag, K. Deniz; Yoo, Jung-Woo; Raju, N. P. Physical Review B, Vol. 82, Issue 9 https://doi.org/10.1103/PhysRevB.82.094449	journal	September 2010
Microscopic Understanding of Negative Magnetization in Cu, Mn, and Fe Based Prussian Blue Analogues Kumar, Amit; Yusuf, S. M.; Keller, L. Physical Review Letters, Vol. 101, Issue 20 https://doi.org/10.1103/PhysRevLett.101.207206	journal	November 2008
Macroscopic Measurement of Resonant Magnetization Tunneling in High-Spin Molecules Friedman, Jonathan R.; Sarachik, M. P.; Tejada, J. Physical Review Letters, Vol. 76, Issue 20 https://doi.org/10.1103/PhysRevLett.76.3830	journal	May 1996
Quantum Tunneling of the Magnetization in an Iron Cluster Nanomagnet Sangregorio, C.; Ohm, T.; Paulsen, C. Physical Review Letters, Vol. 78, Issue 24 https://doi.org/10.1103/PhysRevLett.78.4645	journal	June 1997
Design and Preparation of a Novel Magnet Exhibiting Two Compensation Temperatures Based on Molecular Field Theory Ohkoshi, Shin-ichi; Abe, Yukinori; Fujishima, Akira Physical Review Letters, Vol. 82, Issue 6 https://doi.org/10.1103/PhysRevLett.82.1285	journal	February 1999
Colossal Positive and Negative Thermal Expansion in the Framework Material Ag3[Co(CN)6] Goodwin, A. L.; Calleja, M.; Conterio, M. J. Science, Vol. 319, Issue 5864 https://doi.org/10.1126/science.1151442	journal	February 2008
A Room-Temperature Molecular/Organic-Based Magnet Manriquez, J. M.; Yee, G. T.; Mclean, R. S. Science, Vol. 252, Issue 5011 https://doi.org/10.1126/science.252.5011.1415	journal	June 1991
Organic Molecular Soft Ferromagnetism in a Fullerene C60 Allemand, P. -M.; Khemani, K. C.; Koch, A. Science, Vol. 253, Issue 5017 https://doi.org/10.1126/science.253.5017.301	journal	July 1991
High-Temperature Molecular Magnets Based on Cyanovanadate Building Blocks: Spontaneous Magnetization at 230 K Entley, W. R.; Girolami, G. S. Science, Vol. 268, Issue 5209 https://doi.org/10.1126/science.268.5209.397	journal	April 1995
Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW2O8 Mary, T. A.; Evans, J. S. O.; Vogt, T. Science, Vol. 272, Issue 5258 https://doi.org/10.1126/science.272.5258.90	journal	April 1996
Photoinduced Magnetization of a Cobalt-Iron Cyanide Sato, O.; Iyoda, T.; Fujishima, A. Science, Vol. 272, Issue 5262 https://doi.org/10.1126/science.272.5262.704	journal	May 1996
Size Dependent Cation Channel in Nanoporous Prussian Blue Lattice Moritomo, Yutaka; Igarashi, Kazuhiro; Kim, Jungeun Applied Physics Express, Vol. 2 https://doi.org/10.1143/APEX.2.085001	journal	July 2009
Anomaly in the χ- T Curve of Galvinoxyl Radical Mukai, Kazuo; Nishiguchi, Hiroaki; Deguchi, Yasuo Journal of the Physical Society of Japan, Vol. 23, Issue 1 https://doi.org/10.1143/JPSJ.23.125	journal	July 1967
Nanoarchitectonics: A New Materials Horizon for Prussian Blue and Its Analogues Azhar, Alowasheeir; Li, Yucen; Cai, Zexing Bulletin of the Chemical Society of Japan, Vol. 92, Issue 4 https://doi.org/10.1246/bcsj.20180368	journal	April 2019
Anomalous Magnetic Properties of Stable Crystalline Phenoxyl Radicals Mukai, Kazuo Bulletin of the Chemical Society of Japan, Vol. 42, Issue 1 https://doi.org/10.1246/bcsj.42.40	journal	January 1969
Magnetic Materials in Promoting Bone Regeneration Peng, Jinfeng; Zhao, Jiajia; Long, Yanlin Frontiers in Materials, Vol. 6 https://doi.org/10.3389/fmats.2019.00268	journal	November 2019
The Effect of Pressure on Magnetic Properties of Prussian Blue Analogues Zentkova, Maria; Mihalik, Marian Crystals, Vol. 9, Issue 2 https://doi.org/10.3390/cryst9020112	journal	February 2019

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