Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Room temperature synthesis of high-entropy Prussian blue analogues

Journal Article · · Nano Energy
 [1];  [2];  [3];  [3];  [3];  [4];  [4];  [5]
  1. Jiangsu Univ., Zhenjiang (China); Univ. of Tennessee, Knoxville, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Univ. of Tennessee, Knoxville, TN (United States)
  4. Jiangsu Univ., Zhenjiang (China)
  5. Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
High-entropy Prussian blue analogues (HEPBAs) integrating the highly dispersed active sites of high-entropy materials with intrinsic 3D diffusion channels and the redox-active sites of Prussian blue analogues have great potential in electrochemical applications but have not been realized. Herein, a series of HEPBAs were successfully synthesized under room temperature combining mechanochemistry with wet chemistry for the first time.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
National Natural Science Foundation of China (NNSFC); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1731040
Alternate ID(s):
OSTI ID: 1780467
Journal Information:
Nano Energy, Journal Name: Nano Energy Journal Issue: N/A Vol. 79; ISSN 2211-2855
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (37)

Potassium Prussian Blue Nanoparticles: A Low-Cost Cathode Material for Potassium-Ion Batteries journal December 2016
Hollow Multivoid Nanocuboids Derived from Ternary Ni-Co-Fe Prussian Blue Analog for Dual-Electrocatalysis of Oxygen and Hydrogen Evolution Reactions journal June 2018
Hierarchical Assembly of Prussian Blue Derivatives for Superior Oxygen Evolution Reaction journal August 2019
Formation of Ni-Fe Mixed Diselenide Nanocages as a Superior Oxygen Evolution Electrocatalyst journal September 2017
Hollow Structures Based on Prussian Blue and Its Analogs for Electrochemical Energy Storage and Conversion journal July 2018
Mechanochemical-Assisted Synthesis of High-Entropy Metal Nitride via a Soft Urea Strategy journal April 2018
High‐Entropy Oxides: Fundamental Aspects and Electrochemical Properties journal March 2019
Prussian Blue MgLi Hybrid Batteries journal April 2016
Fe-CoP Electrocatalyst Derived from a Bimetallic Prussian Blue Analogue for Large-Current-Density Oxygen Evolution and Overall Water Splitting journal August 2018
Core–Shell Prussian Blue Analogs with Compositional Heterogeneity and Open Cages for Oxygen Evolution Reaction journal February 2019
Prussian Blue Cathode Materials for Sodium-Ion Batteries and Other Ion Batteries journal January 2018
Boosting Electrochemical Water Oxidation with Metal Hydroxide Carbonate Templated Prussian Blue Analogues journal December 2017
Entropy-Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO 2 Fixation journal March 2019
High‐Entropy Layered Oxide Cathodes for Sodium‐Ion Batteries journal January 2020
Hierarchically Superstructured Prussian Blue Analogues: Spontaneous Assembly Synthesis and Applications as Pseudocapacitive Materials journal November 2014
Recent advances in Prussian blue and Prussian blue analogues: synthesis and thermal treatments journal December 2017
Multifunctional Prussian blue-based nanomaterials: Preparation, modification, and theranostic applications journal September 2020
A flexible and high voltage symmetric supercapacitor based on hybrid configuration of cobalt hexacyanoferrate/reduced graphene oxide hydrogels journal March 2018
Prussian Blue Analogs as Battery Materials journal October 2018
Electrochemically anchored manganese hexacyanoferrate nanocubes on three-dimensional porous graphene scaffold: Towards a potential application in high-performance asymmetric supercapacitors journal February 2020
Cation exchange formation of prussian blue analogue submicroboxes for high-performance Na-ion hybrid supercapacitors journal September 2017
Self-Templating Synthesis of Cobalt Hexacyanoferrate Hollow Structures with Superior Performance for Na-Ion Hybrid Supercapacitors journal July 2018
Prussian blue, an inorganic evergreen journal December 1981
Fast and Persistent Electrocatalytic Water Oxidation by Co–Fe Prussian Blue Coordination Polymers
  • Pintado, Sara; Goberna-Ferrón, Sara; Escudero-Adán, Eduardo C.
  • Journal of the American Chemical Society, Vol. 135, Issue 36, p. 13270-13273 https://doi.org/10.1021/ja406242y
journal August 2013
Enhanced Activity and Acid pH Stability of Prussian Blue-type Oxygen Evolution Electrocatalysts Processed by Chemical Etching journal December 2016
Operando Spectroscopic Identification of Active Sites in NiFe Prussian Blue Analogues as Electrocatalysts: Activation of Oxygen Atoms for Oxygen Evolution Reaction journal August 2018
High-Entropy Perovskite Fluorides: A New Platform for Oxygen Evolution Catalysis journal February 2020
Entropy-stabilized oxides journal September 2015
High entropy oxides for reversible energy storage journal August 2018
Unconventional CN vacancies suppress iron-leaching in Prussian blue analogue pre-catalyst for boosted oxygen evolution catalysis journal June 2019
Highly efficient decomposition of ammonia using high-entropy alloy catalysts journal September 2019
Diffusion-free Grotthuss topochemistry for high-rate and long-life proton batteries journal January 2019
Hidden diversity of vacancy networks in Prussian blue analogues journal February 2020
High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries journal January 2014
Uniform manganese hexacyanoferrate hydrate nanocubes featuring superior performance for low-cost supercapacitors and nonenzymatic electrochemical sensors journal January 2015
Prussian blue: a new framework of electrode materials for sodium batteries journal January 2012
Carbothermal shock synthesis of high-entropy-alloy nanoparticles journal March 2018

Similar Records

Hierarchically Superstructured Prussian Blue Analogues: Spontaneous Assembly Synthesis and Applications as Pseudocapacitive Materials
Journal Article · Sun Nov 09 19:00:00 EST 2014 · ChemSusChem (Online) · OSTI ID:1286909

Multifunctional Prussian blue analogue magnets: Emerging opportunities
Journal Article · Thu Nov 26 19:00:00 EST 2020 · Applied Materials Today · OSTI ID:1830696

Mechanochemically Assisted Synthesis of High-Entropy Layer-Structured Dittmarite Analogues
Journal Article · Tue Mar 08 19:00:00 EST 2022 · ACS Applied Energy Materials · OSTI ID:1862122