Plasmon Energy Transfer in Hybrid Nanoantennas

Collins, Sean E.; Searles, Emily K.; Tauzin, Lawrence J.; Lou, Minhan; Bursi, Luca; Liu, Yawei; Song, Jia; Flatebo, Charlotte; Baiyasi, Rashad; Cai, Yi-Yu; Foerster, Benjamin; Lian, Tianquan; Nordlander, Peter; Link, Stephan; Landes, Christy F.

doi:10.1021/acsnano.0c08982

Plasmon Energy Transfer in Hybrid Nanoantennas

Journal Article · Tue Dec 22 00:00:00 EST 2020 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.0c08982· OSTI ID:1830642

Collins, Sean E. ^[1]; Searles, Emily K. ^[2]; ^[2]; ^[2]; Bursi, Luca ^[2]; Liu, Yawei ^[3]; Song, Jia ^[3]; Flatebo, Charlotte ^[2]; Baiyasi, Rashad ^[2]; ^[2]; ^[4]; ^[3]; ^[2]; ^[2]; ^[2]

Rice Univ., Houston, TX (United States); Rice University
Rice Univ., Houston, TX (United States)
Emory Univ., Atlanta, GA (United States)
BASF SE, Ludwigshafen am Rhein (Germany)

Plasmonic metal nanoparticles exhibit large dipole moments upon photoexcitation and have the potential to induce electronic transitions in nearby materials, but fast internal relaxation has to date limited the spatial range and efficiency of plasmonic mediated processes. In this work, we use photo-electrochemistry to synthesize hybrid nanoantennas comprised of plasmonic nanoparticles with photoconductive polymer coatings. Here, we demonstrate that the formation of the conductive polymer is selective to the nanoparticles and that polymerization is enhanced by photoexcitation. In situ spectroscopy and simulations support a mechanism in which up to 50% efficiency of nonradiative energy transfer is achieved. These hybrid nanoantennas combine the unmatched light-harvesting properties of a plasmonic antenna with the similarly unmatched device processability of a polymer shell.

View Accepted Manuscript (DOE)

Research Organization:: Rice Univ., Houston, TX (United States)

Sponsoring Organization:: Robert A. Welch Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0008798; SC0016534

OSTI ID:: 1830642

Journal Information:: ACS Nano, Journal Name: ACS Nano Journal Issue: 6 Vol. 15; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (59)

Mask-free Localized Grafting of Organic Polymers at the Micrometer or Submicrometer Scale on Composite Conductors or Semiconductor Substrates Charlier, J.; Ameur, S.; Bourgoin, J. P. Advanced Functional Materials, Vol. 14, Issue 2 https://doi.org/10.1002/adfm.200304311	journal	February 2004
Metal/Semiconductor Hybrid Nanostructures for Plasmon-Enhanced Applications Jiang, Ruibin; Li, Benxia; Fang, Caihong Advanced Materials, Vol. 26, Issue 31 https://doi.org/10.1002/adma.201400203	journal	April 2014
Organic Semiconductors based on Dyes and Color Pigments Gsänger, Marcel; Bialas, David; Huang, Lizhen Advanced Materials, Vol. 28, Issue 19 https://doi.org/10.1002/adma.201505440	journal	March 2016
Spectroscopy and High-Resolution Microscopy of Single Nanocrystals by a Focused Ion Beam Registration Method Novo, Carolina; Funston, Alison M.; Pastoriza-Santos, Isabel Angewandte Chemie International Edition, Vol. 46, Issue 19 https://doi.org/10.1002/anie.200700033	journal	May 2007
Plasmon-directed polymerization: Regulating polymer growth with light Wang, Yunxia; Wang, Shuangshuang; Zhang, Shunping Nano Research, Vol. 11, Issue 12 https://doi.org/10.1007/s12274-018-2163-0	journal	August 2018
The work function of gold Sachtler, W. M. H.; Dorgelo, G. J. H.; Holscher, A. A. Surface Science, Vol. 5, Issue 2 https://doi.org/10.1016/0039-6028(66)90083-5	journal	October 1966
Preparation and properties of conductive metallophthalocyanine films Xu, F.; Li, H.; Peng, Q. Synthetic Metals, Vol. 55, Issue 2-3 https://doi.org/10.1016/0379-6779(93)90303-E	journal	March 1993
Fabrication of solid-state dye-sensitized TiO2 solar cells combined with polypyrrole Murakoshi, Kei; Kogure, Ryuichiro; Wada, Yuji Solar Energy Materials and Solar Cells, Vol. 55, Issue 1-2 https://doi.org/10.1016/S0927-0248(98)00052-X	journal	July 1998
Phthalocyanines as medicinal photosensitizers: Developments in the last five years Li, Xingshu; Zheng, Bing-De; Peng, Xiao-Hui Coordination Chemistry Reviews, Vol. 379 https://doi.org/10.1016/j.ccr.2017.08.003	journal	January 2019
Electropolymerization of palladium tetraaminephthalocyanine: Characterization and supercapacitance behavior Lokesh, Koodlur Sannegowda; Adriaens, Annemie Dyes and Pigments, Vol. 112 https://doi.org/10.1016/j.dyepig.2014.06.034	journal	January 2015
Controlling Plasmon-Induced Resonance Energy Transfer and Hot Electron Injection Processes in Metal@TiO ₂ Core–Shell Nanoparticles Cushing, Scott K.; Li, Jiangtian; Bright, Joeseph The Journal of Physical Chemistry C, Vol. 119, Issue 28 https://doi.org/10.1021/acs.jpcc.5b03955	journal	June 2015
Electrodissolution Inhibition of Gold Nanorods with Oxoanions Flatebo, Charlotte; Collins, Sean S. E.; Hoener, Benjamin S. The Journal of Physical Chemistry C, Vol. 123, Issue 22 https://doi.org/10.1021/acs.jpcc.9b01575	journal	May 2019
Double Rabi Splitting in a Strongly Coupled System of Core–Shell Au@Ag Nanorods and J-Aggregates of Multiple Fluorophores Melnikau, Dzmitry; Govyadinov, Alexander A.; Sánchez-Iglesias, Ana The Journal of Physical Chemistry Letters, Vol. 10, Issue 20 https://doi.org/10.1021/acs.jpclett.9b01988	journal	September 2019
Interfacial States Cause Equal Decay of Plasmons and Hot Electrons at Gold–Metal Oxide Interfaces Foerster, Benjamin; Hartelt, Michael; Collins, Sean S. E. Nano Letters, Vol. 20, Issue 5 https://doi.org/10.1021/acs.nanolett.0c00223	journal	March 2020
Spatially Mapping Energy Transfer from Single Plasmonic Particles to Semiconductor Substrates via STEM/EELS Li, Guoliang; Cherqui, Charles; Bigelow, Nicholas W. Nano Letters, Vol. 15, Issue 5 https://doi.org/10.1021/acs.nanolett.5b00802	journal	April 2015
Spectral Screening of the Energy of Hot Holes over a Particle Plasmon Resonance Pensa, Evangelina; Gargiulo, Julian; Lauri, Alberto Nano Letters, Vol. 19, Issue 3 https://doi.org/10.1021/acs.nanolett.8b04950	journal	February 2019
Efficient Plasmon-Mediated Energy Funneling to the Surface of Au@Pt Core–Shell Nanocrystals Engelbrekt, Christian; Crampton, Kevin T.; Fishman, Dmitry A. ACS Nano, Vol. 14, Issue 4 https://doi.org/10.1021/acsnano.0c01653	journal	March 2020
Chemical Interface Damping Depends on Electrons Reaching the Surface Foerster, Benjamin; Joplin, Anneli; Kaefer, Katharina ACS Nano, Vol. 11, Issue 3 https://doi.org/10.1021/acsnano.6b08010	journal	February 2017
Photoluminescence of Gold Nanorods: Purcell Effect Enhanced Emission from Hot Carriers Cai, Yi-Yu; Liu, Jun G.; Tauzin, Lawrence J. ACS Nano, Vol. 12, Issue 2 https://doi.org/10.1021/acsnano.7b07402	journal	January 2018
Plasmon-Induced Energy Transfer: When the Game Is Worth the Candle Moroz, Pavel; Razgoniaeva, Natalia; Vore, Abigail ACS Photonics, Vol. 4, Issue 9 https://doi.org/10.1021/acsphotonics.7b00527	journal	August 2017
Ultrastrong Plasmon–Exciton Coupling by Dynamic Molecular Aggregation Todisco, Francesco; De Giorgi, Milena; Esposito, Marco ACS Photonics, Vol. 5, Issue 1 https://doi.org/10.1021/acsphotonics.7b00554	journal	October 2017
Plasmonic Enhancement of Two-Photon-Excited Luminescence of Single Quantum Dots by Individual Gold Nanorods Zhang, Weichun; Caldarola, Martín; Lu, Xuxing ACS Photonics, Vol. 5, Issue 7 https://doi.org/10.1021/acsphotonics.8b00306	journal	June 2018
Plasmonic Nanoantennas: Fundamentals and Their Use in Controlling the Radiative Properties of Nanoemitters Giannini, Vincenzo; Fernández-Domínguez, Antonio I.; Heck, Susannah C. Chemical Reviews, Vol. 111, Issue 6 https://doi.org/10.1021/cr1002672	journal	June 2011
Ag@Cu ₂ O Core-Shell Nanoparticles as Visible-Light Plasmonic Photocatalysts Li, Jiangtian; Cushing, Scott K.; Bright, Joeseph ACS Catalysis, Vol. 3, Issue 1 https://doi.org/10.1021/cs300672f	journal	December 2012
Photocatalytic Activity Enhanced by Plasmonic Resonant Energy Transfer from Metal to Semiconductor Cushing, Scott K.; Li, Jiangtian; Meng, Fanke Journal of the American Chemical Society, Vol. 134, Issue 36 https://doi.org/10.1021/ja305603t	journal	August 2012
Electronically Transparent Au–N Bonds for Molecular Junctions Zang, Yaping; Pinkard, Andrew; Liu, Zhen-Fei Journal of the American Chemical Society, Vol. 139, Issue 42 https://doi.org/10.1021/jacs.7b08370	journal	October 2017
Plasmonic–Molecular Resonance Coupling: Plasmonic Splitting versus Energy Transfer Chen, Huanjun; Shao, Lei; Woo, Kat Choi The Journal of Physical Chemistry C, Vol. 116, Issue 26 https://doi.org/10.1021/jp303560s	journal	June 2012
Gold Nanorods as Plasmonic Nanotransducers: Distance-Dependent Refractive Index Sensitivity Tian, Limei; Chen, Enze; Gandra, Naveen Langmuir, Vol. 28, Issue 50 https://doi.org/10.1021/la3034534	journal	December 2012
Incident-Angle-Modulated Molecular Plasmonic Switches: A Case of Weak Exciton–Plasmon Coupling Zheng, Yue Bing; Kiraly, Brian; Cheunkar, Sarawut Nano Letters, Vol. 11, Issue 5 https://doi.org/10.1021/nl200524b	journal	May 2011
Using Binary Surfactant Mixtures To Simultaneously Improve the Dimensional Tunability and Monodispersity in the Seeded Growth of Gold Nanorods Ye, Xingchen; Zheng, Chen; Chen, Jun Nano Letters, Vol. 13, Issue 2 https://doi.org/10.1021/nl304478h	journal	January 2013
Single-Particle Absorption Spectroscopy by Photothermal Contrast Yorulmaz, Mustafa; Nizzero, Sara; Hoggard, Anneli Nano Letters, Vol. 15, Issue 5 https://doi.org/10.1021/nl504992h	journal	April 2015
Using the Plasmon Linewidth To Calculate the Time and Efficiency of Electron Transfer between Gold Nanorods and Graphene Hoggard, Anneli; Wang, Lin-Yung; Ma, Lulu ACS Nano, Vol. 7, Issue 12 https://doi.org/10.1021/nn404985h	journal	November 2013
Plasmon–Exciton Interactions in a Core–Shell Geometry: From Enhanced Absorption to Strong Coupling Antosiewicz, Tomasz J.; Apell, S. Peter; Shegai, Timur ACS Photonics, Vol. 1, Issue 5 https://doi.org/10.1021/ph500032d	journal	April 2014
Energy transfer in plasmonic photocatalytic composites Ma, Xiang-Chao; Dai, Ying; Yu, Lin Light: Science & Applications, Vol. 5, Issue 2 https://doi.org/10.1038/lsa.2016.17	journal	February 2016
Plasmonic photoluminescence for recovering native chemical information from surface-enhanced Raman scattering Lin, Kai-Qiang; Yi, Jun; Zhong, Jin-Hui Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14891	journal	March 2017
Plasmonics for improved photovoltaic devices Atwater, Harry A.; Polman, Albert Nature Materials, Vol. 9, Issue 3, p. 205-213 https://doi.org/10.1038/nmat2629	journal	February 2010
Plasmonics for extreme light concentration and manipulation Schuller, Jon A.; Barnard, Edward S.; Cai, Wenshan Nature Materials, Vol. 9, Issue 3 https://doi.org/10.1038/nmat2630	journal	February 2010
Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy Linic, Suljo; Christopher, Phillip; Ingram, David B. Nature Materials, Vol. 10, Issue 12 https://doi.org/10.1038/nmat3151	journal	November 2011
Plasmon-induced hot carrier science and technology Brongersma, Mark L.; Halas, Naomi J.; Nordlander, Peter Nature Nanotechnology, Vol. 10, Issue 1 https://doi.org/10.1038/nnano.2014.311	journal	January 2015
Plasmon-induced hot-electron generation at nanoparticle/metal-oxide interfaces for photovoltaic and photocatalytic devices Clavero, César Nature Photonics, Vol. 8, Issue 2 https://doi.org/10.1038/nphoton.2013.238	journal	January 2014
Plasmon-induced resonance energy transfer for solar energy conversion Li, Jiangtian; Cushing, Scott K.; Meng, Fanke Nature Photonics, Vol. 9, Issue 9 https://doi.org/10.1038/nphoton.2015.142	journal	August 2015
Plasmon-induced selective carbon dioxide conversion on earth-abundant aluminum-cuprous oxide antenna-reactor nanoparticles Robatjazi, Hossein; Zhao, Hangqi; Swearer, Dayne F. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00055-z	journal	June 2017
Efficient plasmon-hot electron conversion in Ag–CsPbBr3 hybrid nanocrystals Huang, Xinyu; Li, Hongbo; Zhang, Chunfeng Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09112-1	journal	March 2019
Plasmonic metal–semiconductor photocatalysts and photoelectrochemical cells: a review Wu, Nianqiang Nanoscale, Vol. 10, Issue 6 https://doi.org/10.1039/C7NR08487K	journal	January 2018
Highly transparent tetraaminophthalocyanine polymer films for DSSC cathodes Klunder, Kevin J.; Elliott, C. Michael; Henry, Charles S. Journal of Materials Chemistry A, Vol. 6, Issue 6 https://doi.org/10.1039/C7TA10167H	journal	January 2018
Electrografting: a powerful method for surface modification Bélanger, Daniel; Pinson, Jean Chemical Society Reviews, Vol. 40, Issue 7 https://doi.org/10.1039/c0cs00149j	journal	January 2011
Formation of electronically conductive thin films of metal phthalocyanines via electropolymerization Li, Huawen; Guarr, Thomas F. Journal of the Chemical Society, Chemical Communications, Issue 13 https://doi.org/10.1039/c39890000832	journal	January 1989
Work function of indium tin oxide transparent conductor measured by photoelectron spectroscopy Park, Y.; Choong, V.; Gao, Y. Applied Physics Letters, Vol. 68, Issue 19 https://doi.org/10.1063/1.116313	journal	May 1996
Compact solar autoclave based on steam generation using broadband light-harvesting nanoparticles Neumann, O.; Feronti, C.; Neumann, A. D. Proceedings of the National Academy of Sciences, Vol. 110, Issue 29 https://doi.org/10.1073/pnas.1310131110	journal	July 2013
Heterometallic antenna−reactor complexes for photocatalysis Swearer, Dayne F.; Zhao, Hangqi; Zhou, Linan Proceedings of the National Academy of Sciences, Vol. 113, Issue 32 https://doi.org/10.1073/pnas.1609769113	journal	July 2016
Drastic Reduction of Plasmon Damping in Gold Nanorods Sönnichsen, C.; Franzl, T.; Wilk, T. Physical Review Letters, Vol. 88, Issue 7 https://doi.org/10.1103/PhysRevLett.88.077402	journal	January 2002
Plasmon damping depends on the chemical nature of the nanoparticle interface Foerster, Benjamin; Spata, Vincent A.; Carter, Emily A. Science Advances, Vol. 5, Issue 3 https://doi.org/10.1126/sciadv.aav0704	journal	March 2019
Photodetection with Active Optical Antennas Knight, M. W.; Sobhani, H.; Nordlander, P. Science, Vol. 332, Issue 6030, p. 702-704 https://doi.org/10.1126/science.1203056	journal	May 2011
Efficient Oxidative Dechlorination and Aromatic Ring Cleavage of Chlorinated Phenols Catalyzed by Iron Sulfophthalocyanine Sorokin, Alexander; Meunier, Bernard; Séris, Jean-Louis Science, Vol. 268, Issue 5214 https://doi.org/10.1126/science.268.5214.1163	journal	May 1995
Efficient hot-electron transfer by a plasmon-induced interfacial charge-transfer transition Wu, K.; Chen, J.; McBride, J. R. Science, Vol. 349, Issue 6248 https://doi.org/10.1126/science.aac5443	journal	August 2015
Optical Characterisation of Thermally Evaporated Nickel Phthalocyanine thin Films El-Nahass, M. M.; Abd-El-Rahman, K. F.; Farag, A. A. M. International Journal of Modern Physics B, Vol. 18, Issue 03 https://doi.org/10.1142/S0217979204023982	journal	January 2004
The renaissance in optical spectroscopy of phthalocyanines and other tetraazaporphyrins Nyokong, Tebello; Isago, Hiroaki Journal of Porphyrins and Phthalocyanines, Vol. 08, Issue 09 https://doi.org/10.1142/S1088424604000453	journal	September 2004
Electrocatalytic Activity of Substituted Metallophthalocyanines Adsorbed on Vitreous Carbon Electrode for Nitric Oxide Oxidation Caro, Claudia A.; Zagal, José H.; Bedioui, Fethi Journal of The Electrochemical Society, Vol. 150, Issue 2 https://doi.org/10.1149/1.1534097	journal	January 2003
Optical properties of metallic films for vertical-cavity optoelectronic devices Rakić, Aleksandar D.; Djurišić, Aleksandra B.; Elazar, Jovan M. Applied Optics, Vol. 37, Issue 22, p. 5271-5283 https://doi.org/10.1364/AO.37.005271	journal	January 1998

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energy transfer
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Plasmon Energy Transfer in Hybrid Nanoantennas

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