Responsive Interfacial Assemblies Based on Charge‐Transfer Interactions

Sun, Shuyi; Xie, Chenxia; Chen, Jie; Yang, Yang; Li, Hui; Russell, Thomas P.; Shi, Shaowei

doi:10.1002/anie.202111252

Responsive Interfacial Assemblies Based on Charge‐Transfer Interactions

Journal Article · Wed Nov 10 00:00:00 EST 2021 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202111252· OSTI ID:1829754

Sun, Shuyi ^[1]; Xie, Chenxia ^[1]; Chen, Jie ^[1]; Yang, Yang ^[1]; Li, Hui ^[1]; ^[2]; ^[1]

Beijing Advanced Innovation Center for Soft Matter Science and Engineering College of Materials Science and Engineering Beijing University of Chemical Technology Beijing 100029 China
Department of Polymer Science and Engineering University of Massachusetts Amherst Massachusetts 01003 USA, Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley California 94720 USA

Abstract

Charge transfer (CT) interactions have been widely used to construct supramolecular systems, such as functional nanostructures and gels. However, to date, there is no report on the generation of CT complexes at the liquid–liquid interface. Here, by using an electron‐deficient acceptor dissolved in water and an electron‐rich donor dissolved in oil, we present the in situ formation and assembly of CT complex surfactants (CTCSs) at the oil–water interface. With time, CTCSs can assemble into higher‐order nanofilms with exceptional mechanical properties, allowing the stabilization of liquids and offering the possibility to structure liquids into nonequilibrium shapes. Moreover, due to the redox‐responsiveness of the electron‐deficient acceptor, the association and dissociation of CTCSs can be reversibly manipulated in a redox process, leading to the switchable assembly and disassembly of the resultant constructs.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1829754

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 50 Vol. 60; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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