Polyoxometalate‐Surfactant Assemblies: Responsiveness to Orthogonal Stimuli

Xia, Zhiqin; Lin, Chang‐Gen; Yang, Yang; Wang, Yongkang; Wu, Zhanpeng; Song, Yu‐Fei; Russell, Thomas P.; Shi, Shaowei

doi:10.1002/anie.202203741

Polyoxometalate‐Surfactant Assemblies: Responsiveness to Orthogonal Stimuli

Journal Article · Thu Apr 21 00:00:00 EDT 2022 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202203741· OSTI ID:1864384

Xia, Zhiqin ^[1]; Lin, Chang‐Gen ^[2]; Yang, Yang ^[1]; Wang, Yongkang ^[1]; Wu, Zhanpeng ^[3]; Song, Yu‐Fei ^[2]; Russell, Thomas P. ^[4]; ^[1]

Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology Beijing 100029 China
Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology Beijing 100029 China, State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Beijing 100029 China
State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical Technology Beijing 100029 China
Department of Polymer Science and Engineering University of Massachusetts Amherst MA 01003 USA, Materials Sciences Division Lawrence Berkeley National Laboratory 1 Cyclotron Road Berkeley CA 94720 USA

Abstract

Integrating different types of supramolecular interactions opens the possibility to generate nanoparticle surfactants (NPSs) at the liquid–liquid interface that are responsive to multiple stimuli. Here we develop a covalently modified polyoxometalate/β‐cyclodextrin (POM/β‐CD) organic–inorganic hybrid, consisting of a negatively charged POM cluster with β‐CD host groups. The POM/β‐CD hybrid can be dispersed in water and interacts at a water/oil interface with ligands dissolved in an oil phase through electrostatic or host–guest interactions, thereby generating POM‐surfactants (POMSs) having pH, redox, and guest‐competitive responsiveness, respectively. By taking advantage of the jamming of POMSs at the interface, a reconfigurable all‐liquid system could be produced that is responsive to orthogonal changes in the external environment.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1864384

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 25 Vol. 61; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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