Metal Oxide-Induced Instability and Its Mitigation in Halide Perovskite Solar Cells

Thampy, Sampreetha; Xu, Weijie; Hsu, Julia W. P.

doi:10.1021/acs.jpclett.1c02371

Metal Oxide-Induced Instability and Its Mitigation in Halide Perovskite Solar Cells

Journal Article · Fri Aug 27 00:00:00 EDT 2021 · Journal of Physical Chemistry Letters

DOI:https://doi.org/10.1021/acs.jpclett.1c02371· OSTI ID:1826604

Thampy, Sampreetha ^[1]; ^[2]; ^[2]

Univ. of Texas at Dallas, Richardson, TX (United States); University of Texas at Dallas
Univ. of Texas at Dallas, Richardson, TX (United States)

Halide perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology for sustainable energy solutions due to their impressive power conversion efficiency and a path to be manufactured by low-cost, high-throughput methods. To reach PSCs’ full potential for practical implementation, it is crucial to solving the issues related to its long-term operational stability. Furthermore, given that PSCs consist of many layers of dissimilar materials which form multiple internal interfaces, it is prudent to examine whether there exist interfacial interactions, most importantly between transport layers and perovskite absorbers, that can trigger device performance and instability. In this perspective, we bring to the attention of the PSC research community the lesser-known interfacial degradation of halide perovskites promoted by contact with metal oxide transport layers and highlight the deleterious effects on the PSCs’ performance and stability. We also discuss various mitigation strategies that have shown promises to achieve high-performing and stable PSCs.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Texas at Dallas, Richardson, TX (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: EE0009518

OSTI ID:: 1826604

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 35 Vol. 12; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Degradation
Interfaces
Oxides
Perovskites
Power conversion efficiency

Metal Oxide-Induced Instability and Its Mitigation in Halide Perovskite Solar Cells

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