Polymerization-Induced Phase Separation in Rubber-Toughened Amine-Cured Epoxy Resins: Tuning Morphology from the Nano- to Macro-scale

Leguizamon, S; Powers, J.; Ahn, J.; Dickens, S.; Lee, S.; Jones, B.

doi:10.1021/acs.macromol.1c01208

Polymerization-Induced Phase Separation in Rubber-Toughened Amine-Cured Epoxy Resins: Tuning Morphology from the Nano- to Macro-scale

Journal Article · Fri Dec 31 23:00:00 EST 2021 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.1c01208· OSTI ID:1823004

Leguizamon, S; Powers, J.; Ahn, J.; Dickens, S.; Lee, S.; Jones, B.

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: ~OTHER

DOE Contract Number:: SC0012704

OSTI ID:: 1823004

Report Number(s):: BNL-222193-2021-JACI

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 17 Vol. 54; ISSN 0024-9297

Country of Publication:: United States

Language:: English

References (69)

Morphology and Fracture Toughness of Nanostructured Epoxy Resin Containing Amino-Terminated Poly(propylene oxide) Zhang, Chongyin; Zheng, Sixun Journal of Macromolecular Science, Part B, Vol. 49, Issue 3 https://doi.org/10.1080/00222341003595709	journal	April 2010
Wavelength‐Selective Photopolymerization of Hybrid Acrylate‐Oxetane Liquid Crystals Hoekstra, Davey C.; Lubbe, Bodine P. A. C.; Bus, Tom Angewandte Chemie International Edition, Vol. 60, Issue 19 https://doi.org/10.1002/anie.202101322	journal	March 2021
Toughening polymer adhesives using nanosized elastomeric particles Meng, Qingshi; Araby, Sherif; Saber, Nasser Journal of Materials Research, Vol. 29, Issue 5 https://doi.org/10.1557/jmr.2014.34	journal	March 2014
Properties of epoxy-amine networks containing nanostructured ether-crosslinked domains Hsu, Ying-Gev; Lin, Kuan-Hung; Lin, Tse-Yu Materials Chemistry and Physics, Vol. 132, Issue 2-3 https://doi.org/10.1016/j.matchemphys.2011.11.087	journal	February 2012
Cross-Linked Nanoporous Materials from Reactive and Multifunctional Block Polymers Seo, Myungeun; Amendt, Mark A.; Hillmyer, Marc A. Macromolecules, Vol. 44, Issue 23 https://doi.org/10.1021/ma2013942	journal	December 2011
Reaction-induced phase decomposition in polymer blends Inoue, T. Progress in Polymer Science, Vol. 20, Issue 1 https://doi.org/10.1016/0079-6700(94)00032-w	journal	January 1995
Reticulated Nanoporous Polymers by Controlled Polymerization-Induced Microphase Separation Seo, M.; Hillmyer, M. A. Science, Vol. 336, Issue 6087 https://doi.org/10.1126/science.1221383	journal	June 2012
Development of combined microstructure and structure characterization facility for in situ and operando studies at the Advanced Photon Source Ilavsky, Jan; Zhang, Fan; Andrews, Ross N. Journal of Applied Crystallography, Vol. 51, Issue 3 https://doi.org/10.1107/S160057671800643X	journal	June 2018
Reaction-induced phase transitions with block copolymers in solution and bulk Lequieu, Joshua; Magenau, Andrew J. D. Polymer Chemistry, Vol. 12, Issue 1 https://doi.org/10.1039/D0PY00722F	journal	January 2021
Small angle X-ray scattering from amorphous polymers arising from heterogeneities Wendorff, J. H.; Fischer, E. W. Kolloid-Zeitschrift und Zeitschrift für Polymere, Vol. 251, Issue 11 https://doi.org/10.1007/BF01498915	journal	November 1973
High-Modulus, High-Conductivity Nanostructured Polymer Electrolyte Membranes via Polymerization-Induced Phase Separation Schulze, Morgan W.; McIntosh, Lucas D.; Hillmyer, Marc A. Nano Letters, Vol. 14, Issue 1 https://doi.org/10.1021/nl4034818	journal	December 2013
Bioinspired high-scattering polymer films fabricated by polymerization-induced phase separation Tang, Yong; Wu, Kejian; Yu, Shudong Optics Letters, Vol. 45, Issue 10 https://doi.org/10.1364/OL.390639	journal	January 2020
Study of epoxy toughened by in situ formed rubber nanoparticles Ma, Jun; Mo, Mao-Song; Du, Xu-Sheng Journal of Applied Polymer Science, Vol. 110, Issue 1 https://doi.org/10.1002/app.27882	journal	October 2008
Theory of first-order phase transitions Binder, K. Reports on Progress in Physics, Vol. 50, Issue 7 https://doi.org/10.1088/0034-4885/50/7/001	journal	July 1987
A new approach to network heterogeneity: Polymerization induced phase separation in photo-initiated, free-radical methacrylic systems Szczepanski, Caroline R.; Pfeifer, Carmem S.; Stansbury, Jeffrey W. Polymer, Vol. 53, Issue 21 https://doi.org/10.1016/j.polymer.2012.08.010	journal	September 2012
Phase Separation Induced by Polymerization of 2-Chlorostyrene in a Polystyrene/Dibutyl Phthalate Mixture Okada, Mamoru; Fujimoto, Koji; Nose, Takuhei Macromolecules, Vol. 28, Issue 6 https://doi.org/10.1021/ma00110a011	journal	November 1995
Polymer-Dispersed Liquid Crystals with Co-continuous Structures Generated by Polymerization-Induced Phase Separation of EBBA−Epoxy Solutions Hoppe, C. E.; Galante, M. J.; Oyanguren, P. A. Macromolecules, Vol. 35, Issue 16 https://doi.org/10.1021/ma0200120	journal	July 2002
Glycidyl Ether Reactions with Amines Shechter, Leon; Wynstra, John; Kurkjy, Raymond P. Industrial & Engineering Chemistry, Vol. 48, Issue 1 https://doi.org/10.1021/ie50553a029	journal	January 1956
In-situ construction of “octopus”-like nanostructure to achieve high performance epoxy thermosets Heng, Zhengguang; Zhang, Xueqin; Chen, Yang Chemical Engineering Journal, Vol. 360 https://doi.org/10.1016/j.cej.2018.12.020	journal	March 2019
The Cleavage of Ethers. Burwell, Robert L. Chemical Reviews, Vol. 54, Issue 4 https://doi.org/10.1021/cr60170a003	journal	August 1954
Fabrication of Elastic Macroporous Polymers with Enhanced Oil Absorbability and Antiwaxing Performance Wang, Guangyan; Zhao, Tianyi; Chen, Lie Langmuir, Vol. 36, Issue 36 https://doi.org/10.1021/acs.langmuir.0c01655	journal	August 2020
Curing behavior, chain dynamics, and microstructure of high Tg thiol-acrylate networks with systematically varied network heterogeneity Jones, Brad H.; Alam, Todd M.; Lee, Sangwoo Polymer, Vol. 205 https://doi.org/10.1016/j.polymer.2020.122783	journal	September 2020
Nanoporous Polystyrene by Chemical Etching of Poly(ethylene oxide) from Ordered Block Copolymers Mao, Huiming; Hillmyer, Marc A. Macromolecules, Vol. 38, Issue 9 https://doi.org/10.1021/ma050008z	journal	May 2005
Structure–property relations of 55nm particle-toughened epoxy Le, Quyen-Huyen; Kuan, Hsu-Chiang; Dai, Jia-Bin Polymer, Vol. 51, Issue 21 https://doi.org/10.1016/j.polymer.2010.08.038	journal	October 2010
Uniquely Broad Glass Transition Temperatures of Gradient Copolymers Relative to Random and Block Copolymers Containing Repulsive Comonomers Kim, Jungki; Mok, Michelle M.; Sandoval, Robert W. Macromolecules, Vol. 39, Issue 18 https://doi.org/10.1021/ma061241f	journal	September 2006
Influence of nano-scale morphology on impact toughness of epoxy blends Masser, Kevin A.; Bain, Erich D.; Beyer, Frederick L. Polymer, Vol. 103 https://doi.org/10.1016/j.polymer.2016.09.076	journal	October 2016
Thermal processing of diblock copolymer melts mimics metallurgy Kim, Kyungtae; Schulze, Morgan W.; Arora, Akash Science, Vol. 356, Issue 6337 https://doi.org/10.1126/science.aam7212	journal	May 2017
Mechanical properties and fracture behaviors of epoxy composites with phase-separation formed liquid rubber and preformed powdered rubber nanoparticles: A comparative study Guan, Li-Zhi; Gong, Li-Xiu; Tang, Long-Cheng Polymer Composites, Vol. 36, Issue 5 https://doi.org/10.1002/pc.22995	journal	April 2014
Computational simulation of polymerization-induced phase separation under a temperature gradient Oh, J.; Rey, A. D. Computational and Theoretical Polymer Science, Vol. 11, Issue 3 https://doi.org/10.1016/S1089-3156(00)00013-1	journal	June 2001
Novel thermoplastic polyhydroxyurethane elastomers as effective damping materials over broad temperature ranges Beniah, Goliath; Liu, Kun; Heath, William H. European Polymer Journal, Vol. 84 https://doi.org/10.1016/j.eurpolymj.2016.05.031	journal	November 2016
3D printing of inherently nanoporous polymers via polymerization-induced phase separation Dong, Zheqin; Cui, Haijun; Zhang, Haodong Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-020-20498-1	journal	January 2021
Bicontinuous Alkaline Fuel Cell Membranes from Strongly Self-Segregating Block Copolymers Price, Samuel C.; Ren, Xiaoming; Jackson, Aaron C. Macromolecules, Vol. 46, Issue 18 https://doi.org/10.1021/ma400995n	journal	August 2013
Rubber-Modified Glassy Amorphous Polymers Prepared via Chemically Induced Phase Separation. 1. Morphology Development and Mechanical Properties Jansen, B. J. P.; Rastogi, S.; Meijer, H. E. H. Macromolecules, Vol. 34, Issue 12 https://doi.org/10.1021/ma001809z	journal	May 2001
Mechanical properties and fracture behaviors of epoxy composites with multi-scale rubber particles Tang, Long-Cheng; Wang, Xu; Wan, Yan-Jun Materials Chemistry and Physics, Vol. 141, Issue 1 https://doi.org/10.1016/j.matchemphys.2013.05.018	journal	August 2013
Cure kinetics of several epoxy–amine systems at ambient and high temperatures Pramanik, Monoj; Fowler, Eric W.; Rawlins, James W. Journal of Coatings Technology and Research, Vol. 11, Issue 2 https://doi.org/10.1007/s11998-013-9565-4	journal	January 2014
Methods of X-Ray and Neutron Scattering in Polymer Science Methods of X-Ray and Neutron Scattering in Polymer Science , Ryong-Joon Roe Oxford U. Press, New York, 2000. $80.00 (331 pp.). ISBN 0-19-511321-7 Glinka, Charles J. Physics Today, Vol. 54, Issue 3 https://doi.org/10.1063/1.4761820	journal	March 2001
Some Properties of Solutions of Long-chain Compounds. Huggins, Maurice L. The Journal of Physical Chemistry, Vol. 46, Issue 1 https://doi.org/10.1021/j150415a018	journal	January 1942
Self-Assembly and Polymerization of Epoxy Resin-Amphiphilic Block Copolymer Nanocomposites Hillmyer, Marc A.; Lipic, Paul M.; Hajduk, Damian A. Journal of the American Chemical Society, Vol. 119, Issue 11 https://doi.org/10.1021/ja963622m	journal	March 1997
Functionalization of hydroxyl groups in segmented polyhydroxyurethane eliminates nanophase separation Beniah, Goliath; Heath, William H.; Torkelson, John M. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 55, Issue 20 https://doi.org/10.1002/pola.28722	journal	July 2017
Nanostructured Thermosetting Blends of Epoxy Resin and Amphiphilic Poly(ε-caprolactone)- b lock -polybutadiene- b lock -poly(ε-caprolactone) Triblock Copolymer Meng, Fanliang; Zheng, Sixun; Zhang, Weian Macromolecules, Vol. 39, Issue 2 https://doi.org/10.1021/ma0518499	journal	December 2005
Gradient copolymers with broad glass transition temperature regions: Design of purely interphase compositions for damping applications Mok, Michelle M.; Kim, Jungki; Torkelson, John M. Journal of Polymer Science Part B: Polymer Physics, Vol. 46, Issue 1 https://doi.org/10.1002/polb.21341	journal	January 2007
Living Polymerization Induced Macro- and Microdomain Investigated by Focusing Ultra-small-angle Neutron Scattering Motokawa, Ryuhei; Iida, You; Zhao, Yue Polymer Journal, Vol. 39, Issue 12 https://doi.org/10.1295/polymj.PJ2007099	journal	November 2007
Glass Transition Breadths and Composition Profiles of Weakly, Moderately, and Strongly Segregating Gradient Copolymers: Experimental Results and Calculations from Self-Consistent Mean-Field Theory Mok, Michelle M.; Kim, Jungki; Wong, Christopher L. H. Macromolecules, Vol. 42, Issue 20 https://doi.org/10.1021/ma9009802	journal	October 2009
Deciphering the Complex Phase Behavior during Polymerization-Induced Nanostructural Transitions of a Block Polymer/Monomer Blend Zofchak, Everett S.; LaNasa, Jacob A.; Torres, Vincent M. Macromolecules, Vol. 53, Issue 3 https://doi.org/10.1021/acs.macromol.9b01695	journal	January 2020
Nanostructured Thermosets from Self-Assembled Amphiphilic Block Copolymer/Epoxy Resin Mixtures Lipic, Paul M.; Bates, Frank S.; Hillmyer, Marc A. Journal of the American Chemical Society, Vol. 120, Issue 35 https://doi.org/10.1021/ja981544s	journal	September 1998
PDMS Nanodomains in DGEBA Epoxy Induce High Flexibility and Toughness Romo-Uribe, Angel; Arcos-Casarrubias, Jose Antonio; Reyes-Mayer, Adriana Polymer-Plastics Technology and Engineering, Vol. 56, Issue 1 https://doi.org/10.1080/03602559.2016.1211691	journal	September 2016
Phase structure and adhesion in polymer blends: A criterion for rubber toughening Wu, Souheng Polymer, Vol. 26, Issue 12 https://doi.org/10.1016/0032-3861(85)90015-1	journal	November 1985
Advances in toughened polymer materials by structured rubber particles Wang, Jianfeng; Zhang, Xiaohong; Jiang, Lei Progress in Polymer Science, Vol. 98 https://doi.org/10.1016/j.progpolymsci.2019.101160	journal	November 2019
Thermodynamics of High Polymer Solutions Flory, Paul J. The Journal of Chemical Physics, Vol. 10, Issue 1 https://doi.org/10.1063/1.1723621	journal	January 1942
Structurally Designed Synthesis of Mechanically Stable Poly(benzoxazine-co-resol)-Based Porous Carbon Monoliths and Their Application as High-Performance CO ₂ Capture Sorbents Hao, Guang-Ping; Li, Wen-Cui; Qian, Dan Journal of the American Chemical Society, Vol. 133, Issue 29 https://doi.org/10.1021/ja203857g	journal	July 2011
Nucleation Initiated Spinodal Decomposition in a Polymerizing System Kyu, Thein; Lee, Jae-Hyung Physical Review Letters, Vol. 76, Issue 20 https://doi.org/10.1103/PhysRevLett.76.3746	journal	May 1996
Mechanical properties of epoxy networks based on DGEBA and aliphatic amines Garcia, Filiberto González; Soares, Bluma G.; Pita, Victor J. R. R. Journal of Applied Polymer Science, Vol. 106, Issue 3 https://doi.org/10.1002/app.24895	journal	January 2007
Reactive Block Copolymers for Modification of Thermosetting Epoxy Grubbs, Robert B.; Dean, Jennifer M.; Broz, Margaret E. Macromolecules, Vol. 33, Issue 26 https://doi.org/10.1021/ma001414f	journal	December 2000
Stability of Nanoporous Materials Muralidharan, Vijayanand; Hui, Chung-Yuen Macromolecular Rapid Communications, Vol. 25, Issue 16 https://doi.org/10.1002/marc.200400190	journal	August 2004
Using the Cahn–Hilliard Theory in Metastable Binary Solutions Tran Duc, Viet-Nhien; Chan, Philip K. ChemEngineering, Vol. 3, Issue 3 https://doi.org/10.3390/chemengineering3030075	journal	September 2019
Formation of metastable phases by spinodal decomposition Alert, Ricard; Tierno, Pietro; Casademunt, Jaume Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13067	journal	October 2016
Influence of Added Salt on Chain Conformations in Poly(ethylene oxide) Melts: SANS Analysis with Complications Xie, Shuyi; Zhang, Bo; Mao, Yimin Macromolecules, Vol. 53, Issue 16 https://doi.org/10.1021/acs.macromol.0c01194	journal	August 2020
Tuning Mesoporosity in Cross-Linked Nanostructured Thermosets via Polymerization-Induced Microphase Separation Schulze, Morgan W.; Hillmyer, Marc A. Macromolecules, Vol. 50, Issue 3 https://doi.org/10.1021/acs.macromol.6b02570	journal	January 2017
The brittle-ductile transition in rubber-filled polymers Serenko, O. A.; Goncharuk, G. P.; Obolonkova, E. S. Polymer Science Series A, Vol. 48, Issue 3 https://doi.org/10.1134/S0965545X06030114	journal	March 2006
Dynamic heterogeneity in epoxy networks for protection applications Masser, Kevin A.; Knorr, Daniel B.; Yu, Jian H. Journal of Applied Polymer Science, Vol. 133, Issue 45 https://doi.org/10.1002/app.43566	journal	March 2016
Effect of network structure of epoxy DGEBA-poly(oxypropylene)diamines on tensile behavior Shan, L.; Verghese, K. N. E.; Robertson, C. G. Journal of Polymer Science Part B: Polymer Physics, Vol. 37, Issue 19 https://doi.org/10.1002/(sici)1099-0488(19991001)37:19<2815::aid-polb11>3.0.co;2-t	journal	October 1999
Theory of Solutions of High Polymers ¹ Huggins, Maurice L. Journal of the American Chemical Society, Vol. 64, Issue 7 https://doi.org/10.1021/ja01259a068	journal	July 1942
Relating structure and chain dynamics to ballistic performance in transparent epoxy networks exhibiting nanometer scale heterogeneity Masser, Kevin A.; Knorr, Daniel B.; Hindenlang, Mark D. Polymer, Vol. 58 https://doi.org/10.1016/j.polymer.2014.12.027	journal	February 2015
Highly Selective Polymer Electrolyte Membranes from Reactive Block Polymers Chen, Liang; Hallinan, Daniel T.; Elabd, Yossef A. Macromolecules, Vol. 42, Issue 16 https://doi.org/10.1021/ma901272s	journal	July 2009
Reaction-Induced Microphase Separation in Epoxy Thermosets Containing Block Copolymers Composed of Polystyrene and Poly(ε-caprolactone): Influence of Copolymer Architectures on Formation of Nanophases Yu, Rentong; Zheng, Sixun; Li, Xiuhong Macromolecules, Vol. 45, Issue 22 https://doi.org/10.1021/ma3017212	journal	November 2012
Tricontinuous Nanostructured Polymers via Polymerization-Induced Microphase Separation Saba, Stacey A.; Lee, Bongjoon; Hillmyer, Marc A. ACS Macro Letters, Vol. 6, Issue 11 https://doi.org/10.1021/acsmacrolett.7b00677	journal	October 2017
Mechanical and tribological properties of epoxy modified by liquid carboxyl terminated poly(butadiene-co-acrylonitrile) rubber Chonkaew, Wunpen; Sombatsompop, Narongrit Journal of Applied Polymer Science, Vol. 125, Issue 1 https://doi.org/10.1002/app.35580	journal	December 2011
Chemistry and Mechanical Properties of Epoxy-Based Thermosets Reinforced by Reactive and Nonreactive SBMX Block Copolymers Rebizant, Valéry; Venet, Anne-Sophie; Tournilhac, François Macromolecules, Vol. 37, Issue 21 https://doi.org/10.1021/ma0490754	journal	October 2004
Notched impact behaviour of polymer blends: Part 2: Dependence of critical particle size on rubber particle volume fraction Bucknall, C. B.; Paul, D. R. Polymer, Vol. 54, Issue 1 https://doi.org/10.1016/j.polymer.2012.11.019	journal	January 2013

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