Polymerization-Induced Phase Separation in Rubber-Toughened Amine-Cured Epoxy Resins: Tuning Morphology from the Nano- to Macro-scale

Leguizamon, Samuel C.; Powers, Jackson; Ahn, Juhong; Dickens, Sara; Lee, Sangwoo; Jones, Brad H.

doi:10.1021/acs.macromol.1c01208

Polymerization-Induced Phase Separation in Rubber-Toughened Amine-Cured Epoxy Resins: Tuning Morphology from the Nano- to Macro-scale

Journal Article · Tue Aug 17 00:00:00 EDT 2021 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.1c01208· OSTI ID:1813640

^[1]; Powers, Jackson ^[1]; Ahn, Juhong ^[2]; Dickens, Sara ^[1]; ^[2]; ^[1]

Material, Physical, and Chemical Sciences Center, Sandia National Laboratories, Albuquerque, New Mexico 87185, United States
Department of Chemical and Biological Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180, United States

Not Available

View Journal Article

Sponsoring Organization:: USDOE

OSTI ID:: 1813640

Alternate ID(s):: OSTI ID: 1817710
OSTI ID: 1820096
OSTI ID: 1821726
OSTI ID: 1823154
OSTI ID: 1823004

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 17 Vol. 54; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (69)

Effect of network structure of epoxy DGEBA-poly(oxypropylene)diamines on tensile behavior Shan, L.; Verghese, K. N. E.; Robertson, C. G. Journal of Polymer Science Part B: Polymer Physics, Vol. 37, Issue 19 https://doi.org/10.1002/(sici)1099-0488(19991001)37:19<2815::aid-polb11>3.0.co;2-t	journal	October 1999
Wavelength‐Selective Photopolymerization of Hybrid Acrylate‐Oxetane Liquid Crystals Hoekstra, Davey C.; Lubbe, Bodine P. A. C.; Bus, Tom Angewandte Chemie International Edition, Vol. 60, Issue 19 https://doi.org/10.1002/anie.202101322	journal	March 2021
Mechanical properties of epoxy networks based on DGEBA and aliphatic amines Garcia, Filiberto González; Soares, Bluma G.; Pita, Victor J. R. R. Journal of Applied Polymer Science, Vol. 106, Issue 3 https://doi.org/10.1002/app.24895	journal	January 2007
Study of epoxy toughened by in situ formed rubber nanoparticles Ma, Jun; Mo, Mao-Song; Du, Xu-Sheng Journal of Applied Polymer Science, Vol. 110, Issue 1 https://doi.org/10.1002/app.27882	journal	October 2008
Mechanical and tribological properties of epoxy modified by liquid carboxyl terminated poly(butadiene-co-acrylonitrile) rubber Chonkaew, Wunpen; Sombatsompop, Narongrit Journal of Applied Polymer Science, Vol. 125, Issue 1 https://doi.org/10.1002/app.35580	journal	December 2011
Dynamic heterogeneity in epoxy networks for protection applications Masser, Kevin A.; Knorr, Daniel B.; Yu, Jian H. Journal of Applied Polymer Science, Vol. 133, Issue 45 https://doi.org/10.1002/app.43566	journal	March 2016
Stability of Nanoporous Materials Muralidharan, Vijayanand; Hui, Chung-Yuen Macromolecular Rapid Communications, Vol. 25, Issue 16 https://doi.org/10.1002/marc.200400190	journal	August 2004
Mechanical properties and fracture behaviors of epoxy composites with phase-separation formed liquid rubber and preformed powdered rubber nanoparticles: A comparative study Guan, Li-Zhi; Gong, Li-Xiu; Tang, Long-Cheng Polymer Composites, Vol. 36, Issue 5 https://doi.org/10.1002/pc.22995	journal	April 2014
Functionalization of hydroxyl groups in segmented polyhydroxyurethane eliminates nanophase separation Beniah, Goliath; Heath, William H.; Torkelson, John M. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 55, Issue 20 https://doi.org/10.1002/pola.28722	journal	July 2017
Gradient copolymers with broad glass transition temperature regions: Design of purely interphase compositions for damping applications Mok, Michelle M.; Kim, Jungki; Torkelson, John M. Journal of Polymer Science Part B: Polymer Physics, Vol. 46, Issue 1 https://doi.org/10.1002/polb.21341	journal	January 2007
Small angle X-ray scattering from amorphous polymers arising from heterogeneities Wendorff, J. H.; Fischer, E. W. Kolloid-Zeitschrift und Zeitschrift für Polymere, Vol. 251, Issue 11 https://doi.org/10.1007/BF01498915	journal	November 1973
Cure kinetics of several epoxy–amine systems at ambient and high temperatures Pramanik, Monoj; Fowler, Eric W.; Rawlins, James W. Journal of Coatings Technology and Research, Vol. 11, Issue 2 https://doi.org/10.1007/s11998-013-9565-4	journal	January 2014
Phase structure and adhesion in polymer blends: A criterion for rubber toughening Wu, Souheng Polymer, Vol. 26, Issue 12 https://doi.org/10.1016/0032-3861(85)90015-1	journal	November 1985
Reaction-induced phase decomposition in polymer blends Inoue, T. Progress in Polymer Science, Vol. 20, Issue 1 https://doi.org/10.1016/0079-6700(94)00032-w	journal	January 1995
Computational simulation of polymerization-induced phase separation under a temperature gradient Oh, J.; Rey, A. D. Computational and Theoretical Polymer Science, Vol. 11, Issue 3 https://doi.org/10.1016/S1089-3156(00)00013-1	journal	June 2001
In-situ construction of “octopus”-like nanostructure to achieve high performance epoxy thermosets Heng, Zhengguang; Zhang, Xueqin; Chen, Yang Chemical Engineering Journal, Vol. 360 https://doi.org/10.1016/j.cej.2018.12.020	journal	March 2019
Novel thermoplastic polyhydroxyurethane elastomers as effective damping materials over broad temperature ranges Beniah, Goliath; Liu, Kun; Heath, William H. European Polymer Journal, Vol. 84 https://doi.org/10.1016/j.eurpolymj.2016.05.031	journal	November 2016
Properties of epoxy-amine networks containing nanostructured ether-crosslinked domains Hsu, Ying-Gev; Lin, Kuan-Hung; Lin, Tse-Yu Materials Chemistry and Physics, Vol. 132, Issue 2-3 https://doi.org/10.1016/j.matchemphys.2011.11.087	journal	February 2012
Mechanical properties and fracture behaviors of epoxy composites with multi-scale rubber particles Tang, Long-Cheng; Wang, Xu; Wan, Yan-Jun Materials Chemistry and Physics, Vol. 141, Issue 1 https://doi.org/10.1016/j.matchemphys.2013.05.018	journal	August 2013
Structure–property relations of 55nm particle-toughened epoxy Le, Quyen-Huyen; Kuan, Hsu-Chiang; Dai, Jia-Bin Polymer, Vol. 51, Issue 21 https://doi.org/10.1016/j.polymer.2010.08.038	journal	October 2010
A new approach to network heterogeneity: Polymerization induced phase separation in photo-initiated, free-radical methacrylic systems Szczepanski, Caroline R.; Pfeifer, Carmem S.; Stansbury, Jeffrey W. Polymer, Vol. 53, Issue 21 https://doi.org/10.1016/j.polymer.2012.08.010	journal	September 2012
Notched impact behaviour of polymer blends: Part 2: Dependence of critical particle size on rubber particle volume fraction Bucknall, C. B.; Paul, D. R. Polymer, Vol. 54, Issue 1 https://doi.org/10.1016/j.polymer.2012.11.019	journal	January 2013
Relating structure and chain dynamics to ballistic performance in transparent epoxy networks exhibiting nanometer scale heterogeneity Masser, Kevin A.; Knorr, Daniel B.; Hindenlang, Mark D. Polymer, Vol. 58 https://doi.org/10.1016/j.polymer.2014.12.027	journal	February 2015
Influence of nano-scale morphology on impact toughness of epoxy blends Masser, Kevin A.; Bain, Erich D.; Beyer, Frederick L. Polymer, Vol. 103 https://doi.org/10.1016/j.polymer.2016.09.076	journal	October 2016
Curing behavior, chain dynamics, and microstructure of high Tg thiol-acrylate networks with systematically varied network heterogeneity Jones, Brad H.; Alam, Todd M.; Lee, Sangwoo Polymer, Vol. 205 https://doi.org/10.1016/j.polymer.2020.122783	journal	September 2020
Advances in toughened polymer materials by structured rubber particles Wang, Jianfeng; Zhang, Xiaohong; Jiang, Lei Progress in Polymer Science, Vol. 98 https://doi.org/10.1016/j.progpolymsci.2019.101160	journal	November 2019
Fabrication of Elastic Macroporous Polymers with Enhanced Oil Absorbability and Antiwaxing Performance Wang, Guangyan; Zhao, Tianyi; Chen, Lie Langmuir, Vol. 36, Issue 36 https://doi.org/10.1021/acs.langmuir.0c01655	journal	August 2020
Influence of Added Salt on Chain Conformations in Poly(ethylene oxide) Melts: SANS Analysis with Complications Xie, Shuyi; Zhang, Bo; Mao, Yimin Macromolecules, Vol. 53, Issue 16 https://doi.org/10.1021/acs.macromol.0c01194	journal	August 2020
Tuning Mesoporosity in Cross-Linked Nanostructured Thermosets via Polymerization-Induced Microphase Separation Schulze, Morgan W.; Hillmyer, Marc A. Macromolecules, Vol. 50, Issue 3 https://doi.org/10.1021/acs.macromol.6b02570	journal	January 2017
Deciphering the Complex Phase Behavior during Polymerization-Induced Nanostructural Transitions of a Block Polymer/Monomer Blend Zofchak, Everett S.; LaNasa, Jacob A.; Torres, Vincent M. Macromolecules, Vol. 53, Issue 3 https://doi.org/10.1021/acs.macromol.9b01695	journal	January 2020
Tricontinuous Nanostructured Polymers via Polymerization-Induced Microphase Separation Saba, Stacey A.; Lee, Bongjoon; Hillmyer, Marc A. ACS Macro Letters, Vol. 6, Issue 11 https://doi.org/10.1021/acsmacrolett.7b00677	journal	October 2017
The Cleavage of Ethers. Burwell, Robert L. Chemical Reviews, Vol. 54, Issue 4 https://doi.org/10.1021/cr60170a003	journal	August 1954
Glycidyl Ether Reactions with Amines Shechter, Leon; Wynstra, John; Kurkjy, Raymond P. Industrial & Engineering Chemistry, Vol. 48, Issue 1 https://doi.org/10.1021/ie50553a029	journal	January 1956
Some Properties of Solutions of Long-chain Compounds. Huggins, Maurice L. The Journal of Physical Chemistry, Vol. 46, Issue 1 https://doi.org/10.1021/j150415a018	journal	January 1942
Theory of Solutions of High Polymers ¹ Huggins, Maurice L. Journal of the American Chemical Society, Vol. 64, Issue 7 https://doi.org/10.1021/ja01259a068	journal	July 1942
Structurally Designed Synthesis of Mechanically Stable Poly(benzoxazine-co-resol)-Based Porous Carbon Monoliths and Their Application as High-Performance CO ₂ Capture Sorbents Hao, Guang-Ping; Li, Wen-Cui; Qian, Dan Journal of the American Chemical Society, Vol. 133, Issue 29 https://doi.org/10.1021/ja203857g	journal	July 2011
Self-Assembly and Polymerization of Epoxy Resin-Amphiphilic Block Copolymer Nanocomposites Hillmyer, Marc A.; Lipic, Paul M.; Hajduk, Damian A. Journal of the American Chemical Society, Vol. 119, Issue 11 https://doi.org/10.1021/ja963622m	journal	March 1997
Nanostructured Thermosets from Self-Assembled Amphiphilic Block Copolymer/Epoxy Resin Mixtures Lipic, Paul M.; Bates, Frank S.; Hillmyer, Marc A. Journal of the American Chemical Society, Vol. 120, Issue 35 https://doi.org/10.1021/ja981544s	journal	September 1998
Phase Separation Induced by Polymerization of 2-Chlorostyrene in a Polystyrene/Dibutyl Phthalate Mixture Okada, Mamoru; Fujimoto, Koji; Nose, Takuhei Macromolecules, Vol. 28, Issue 6 https://doi.org/10.1021/ma00110a011	journal	November 1995
Reactive Block Copolymers for Modification of Thermosetting Epoxy Grubbs, Robert B.; Dean, Jennifer M.; Broz, Margaret E. Macromolecules, Vol. 33, Issue 26 https://doi.org/10.1021/ma001414f	journal	December 2000
Rubber-Modified Glassy Amorphous Polymers Prepared via Chemically Induced Phase Separation. 1. Morphology Development and Mechanical Properties Jansen, B. J. P.; Rastogi, S.; Meijer, H. E. H. Macromolecules, Vol. 34, Issue 12 https://doi.org/10.1021/ma001809z	journal	May 2001
Polymer-Dispersed Liquid Crystals with Co-continuous Structures Generated by Polymerization-Induced Phase Separation of EBBA−Epoxy Solutions Hoppe, C. E.; Galante, M. J.; Oyanguren, P. A. Macromolecules, Vol. 35, Issue 16 https://doi.org/10.1021/ma0200120	journal	July 2002
Chemistry and Mechanical Properties of Epoxy-Based Thermosets Reinforced by Reactive and Nonreactive SBMX Block Copolymers Rebizant, Valéry; Venet, Anne-Sophie; Tournilhac, François Macromolecules, Vol. 37, Issue 21 https://doi.org/10.1021/ma0490754	journal	October 2004
Nanoporous Polystyrene by Chemical Etching of Poly(ethylene oxide) from Ordered Block Copolymers Mao, Huiming; Hillmyer, Marc A. Macromolecules, Vol. 38, Issue 9 https://doi.org/10.1021/ma050008z	journal	May 2005
Nanostructured Thermosetting Blends of Epoxy Resin and Amphiphilic Poly(ε-caprolactone)- b lock -polybutadiene- b lock -poly(ε-caprolactone) Triblock Copolymer Meng, Fanliang; Zheng, Sixun; Zhang, Weian Macromolecules, Vol. 39, Issue 2 https://doi.org/10.1021/ma0518499	journal	December 2005
Uniquely Broad Glass Transition Temperatures of Gradient Copolymers Relative to Random and Block Copolymers Containing Repulsive Comonomers Kim, Jungki; Mok, Michelle M.; Sandoval, Robert W. Macromolecules, Vol. 39, Issue 18 https://doi.org/10.1021/ma061241f	journal	September 2006
Cross-Linked Nanoporous Materials from Reactive and Multifunctional Block Polymers Seo, Myungeun; Amendt, Mark A.; Hillmyer, Marc A. Macromolecules, Vol. 44, Issue 23 https://doi.org/10.1021/ma2013942	journal	December 2011
Reaction-Induced Microphase Separation in Epoxy Thermosets Containing Block Copolymers Composed of Polystyrene and Poly(ε-caprolactone): Influence of Copolymer Architectures on Formation of Nanophases Yu, Rentong; Zheng, Sixun; Li, Xiuhong Macromolecules, Vol. 45, Issue 22 https://doi.org/10.1021/ma3017212	journal	November 2012
Bicontinuous Alkaline Fuel Cell Membranes from Strongly Self-Segregating Block Copolymers Price, Samuel C.; Ren, Xiaoming; Jackson, Aaron C. Macromolecules, Vol. 46, Issue 18 https://doi.org/10.1021/ma400995n	journal	August 2013
Glass Transition Breadths and Composition Profiles of Weakly, Moderately, and Strongly Segregating Gradient Copolymers: Experimental Results and Calculations from Self-Consistent Mean-Field Theory Mok, Michelle M.; Kim, Jungki; Wong, Christopher L. H. Macromolecules, Vol. 42, Issue 20 https://doi.org/10.1021/ma9009802	journal	October 2009
Highly Selective Polymer Electrolyte Membranes from Reactive Block Polymers Chen, Liang; Hallinan, Daniel T.; Elabd, Yossef A. Macromolecules, Vol. 42, Issue 16 https://doi.org/10.1021/ma901272s	journal	July 2009
High-Modulus, High-Conductivity Nanostructured Polymer Electrolyte Membranes via Polymerization-Induced Phase Separation Schulze, Morgan W.; McIntosh, Lucas D.; Hillmyer, Marc A. Nano Letters, Vol. 14, Issue 1 https://doi.org/10.1021/nl4034818	journal	December 2013
Formation of metastable phases by spinodal decomposition Alert, Ricard; Tierno, Pietro; Casademunt, Jaume Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13067	journal	October 2016
3D printing of inherently nanoporous polymers via polymerization-induced phase separation Dong, Zheqin; Cui, Haijun; Zhang, Haodong Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-020-20498-1	journal	January 2021
Reaction-induced phase transitions with block copolymers in solution and bulk Lequieu, Joshua; Magenau, Andrew J. D. Polymer Chemistry, Vol. 12, Issue 1 https://doi.org/10.1039/D0PY00722F	journal	January 2021
Thermodynamics of High Polymer Solutions Flory, Paul J. The Journal of Chemical Physics, Vol. 10, Issue 1 https://doi.org/10.1063/1.1723621	journal	January 1942
Methods of X-Ray and Neutron Scattering in Polymer Science Methods of X-Ray and Neutron Scattering in Polymer Science , Ryong-Joon Roe Oxford U. Press, New York, 2000. $80.00 (331 pp.). ISBN 0-19-511321-7 Glinka, Charles J. Physics Today, Vol. 54, Issue 3 https://doi.org/10.1063/1.4761820	journal	March 2001
Morphology and Fracture Toughness of Nanostructured Epoxy Resin Containing Amino-Terminated Poly(propylene oxide) Zhang, Chongyin; Zheng, Sixun Journal of Macromolecular Science, Part B, Vol. 49, Issue 3 https://doi.org/10.1080/00222341003595709	journal	April 2010
PDMS Nanodomains in DGEBA Epoxy Induce High Flexibility and Toughness Romo-Uribe, Angel; Arcos-Casarrubias, Jose Antonio; Reyes-Mayer, Adriana Polymer-Plastics Technology and Engineering, Vol. 56, Issue 1 https://doi.org/10.1080/03602559.2016.1211691	journal	September 2016
Theory of first-order phase transitions Binder, K. Reports on Progress in Physics, Vol. 50, Issue 7 https://doi.org/10.1088/0034-4885/50/7/001	journal	July 1987
Nucleation Initiated Spinodal Decomposition in a Polymerizing System Kyu, Thein; Lee, Jae-Hyung Physical Review Letters, Vol. 76, Issue 20 https://doi.org/10.1103/PhysRevLett.76.3746	journal	May 1996
Development of combined microstructure and structure characterization facility for in situ and operando studies at the Advanced Photon Source Ilavsky, Jan; Zhang, Fan; Andrews, Ross N. Journal of Applied Crystallography, Vol. 51, Issue 3 https://doi.org/10.1107/S160057671800643X	journal	June 2018
Reticulated Nanoporous Polymers by Controlled Polymerization-Induced Microphase Separation Seo, M.; Hillmyer, M. A. Science, Vol. 336, Issue 6087 https://doi.org/10.1126/science.1221383	journal	June 2012
Thermal processing of diblock copolymer melts mimics metallurgy Kim, Kyungtae; Schulze, Morgan W.; Arora, Akash Science, Vol. 356, Issue 6337 https://doi.org/10.1126/science.aam7212	journal	May 2017
The brittle-ductile transition in rubber-filled polymers Serenko, O. A.; Goncharuk, G. P.; Obolonkova, E. S. Polymer Science Series A, Vol. 48, Issue 3 https://doi.org/10.1134/S0965545X06030114	journal	March 2006
Living Polymerization Induced Macro- and Microdomain Investigated by Focusing Ultra-small-angle Neutron Scattering Motokawa, Ryuhei; Iida, You; Zhao, Yue Polymer Journal, Vol. 39, Issue 12 https://doi.org/10.1295/polymj.PJ2007099	journal	November 2007
Bioinspired high-scattering polymer films fabricated by polymerization-induced phase separation Tang, Yong; Wu, Kejian; Yu, Shudong Optics Letters, Vol. 45, Issue 10 https://doi.org/10.1364/OL.390639	journal	January 2020
Toughening polymer adhesives using nanosized elastomeric particles Meng, Qingshi; Araby, Sherif; Saber, Nasser Journal of Materials Research, Vol. 29, Issue 5 https://doi.org/10.1557/jmr.2014.34	journal	March 2014
Using the Cahn–Hilliard Theory in Metastable Binary Solutions Tran Duc, Viet-Nhien; Chan, Philip K. ChemEngineering, Vol. 3, Issue 3 https://doi.org/10.3390/chemengineering3030075	journal	September 2019

Similar Records

Polymerization-Induced Phase Separation in Rubber-Toughened Amine-Cured Epoxy Resins: Tuning Morphology from the Nano- to Macro-scale

Journal Article · Fri Dec 31 23:00:00 EST 2021 · Macromolecules · OSTI ID:1823004

Polymerization-Induced Phase Separation in Rubber-Toughened Amine-Cured Epoxy Resins: Tuning Morphology from the Nano- to Macro-scale

Citation Formats

References (69)

Similar Records

Related Subjects