Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent

Hamad, Khaleel I.; Xing, Yangchuan

doi:10.1115/1.4045565

Improving Retention Rate of LiNi_0.8Co_0.15Al_0.05O₂ Cathode Material Synthesized Using Glycerol Solvent

Journal Article · Sat Jan 11 00:00:00 EST 2020 · Journal of Electrochemical Energy Conversion and Storage

DOI:https://doi.org/10.1115/1.4045565· OSTI ID:1822916

Hamad, Khaleel I. ^[1]; Xing, Yangchuan ^[2]

Univ. of Missouri, Columbia, MO (United States); University of Missouri
Univ. of Missouri, Columbia, MO (United States)

This paper reports an enhanced retention rate of LiNi_0.8Co_0.15Al_0.05O₂ (NCA) cathode material for Li-ion batteries synthesized with glycerol as a solvent and a reactant. Glycerol is a fuel and the heat released during synthesis could be considered as an additional free energy source for material preparation. Scanning electron microscopy (SEM) images and X-ray diffraction (XRD) results show an early stage of crystallization of the produced powder. Early crystallization in the NCA material at low temperatures was believed to hinder cationic mixing that would occur at higher temperatures during calcination. As a result, cycling of the NCA material shows a very stable capacity. The NCA material displays 97% capacity retention at 1C (1C = 200 mA/g) after 50 cycles, 87.6% at 0.3C after 100 cycles, and 93.6% at 0.1C after 70 cycles, which are better than those reported previously.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Missouri, Columbia, MO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: EE0007282

OSTI ID:: 1822916

Alternate ID(s):: OSTI ID: 1799291

Journal Information:: Journal of Electrochemical Energy Conversion and Storage, Journal Name: Journal of Electrochemical Energy Conversion and Storage Journal Issue: 3 Vol. 17; ISSN 2381-6872

Publisher:: ASMECopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
36 MATERIALS SCIENCE
Li-ion battery
NCA cathode material
batteries
capacity retention
glycerol
innovative material synthesis and manufacturing methods

Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent

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Improving Retention Rate of LiNi_0.8Co_0.15Al_0.05O₂ Cathode Material Synthesized Using Glycerol Solvent