Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent

Hamad, Khaleel I.; Xing, Yangchuan

doi:10.1115/1.4045565

Improving Retention Rate of LiNi0.8Co0.15Al0.05O2 Cathode Material Synthesized Using Glycerol Solvent

Journal Article · Sat Jan 11 04:00:00 EST 2020 · Journal of Electrochemical Energy Conversion and Storage

DOI:https://doi.org/10.1115/1.4045565· OSTI ID:1799291

Hamad, Khaleel I. ^[1]; Xing, Yangchuan ^[2]

Department of Chemical Engineering, University of Missouri, Columbia, MO 65211; OSTI
Department of Chemical Engineering, University of Missouri, Columbia, MO 65211

Abstract

This paper reports an enhanced retention rate of LiNi0.8Co0.15Al0.05O2 (NCA) cathode material for Li-ion batteries synthesized with glycerol as a solvent and a reactant. Glycerol is a fuel and the heat released during synthesis could be considered as an additional free energy source for material preparation. Scanning electron microscopy (SEM) images and X-ray diffraction (XRD) results show an early stage of crystallization of the produced powder. Early crystallization in the NCA material at low temperatures was believed to hinder cationic mixing that would occur at higher temperatures during calcination. As a result, cycling of the NCA material shows a very stable capacity. The NCA material displays 97% capacity retention at 1C (1C = 200 mA/g) after 50 cycles, 87.6% at 0.3C after 100 cycles, and 93.6% at 0.1C after 70 cycles, which are better than those reported previously.

Research Organization:: Univ. of Missouri, Columbia, MO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: EE0007282

OSTI ID:: 1799291

Journal Information:: Journal of Electrochemical Energy Conversion and Storage, Journal Name: Journal of Electrochemical Energy Conversion and Storage Journal Issue: 3 Vol. 17; ISSN 2381-6872

Publisher:: ASME

Country of Publication:: United States

Language:: English

References (22)

Surface modification of LiNi0.8Co0.1Mn0.1O2 with conducting polypyrrole Xiong, Xunhui; Ding, Dong; Wang, Zhixing Journal of Solid State Electrochemistry, Vol. 18, Issue 9 https://doi.org/10.1007/s10008-014-2519-7	journal	May 2014
Facile synthesis of one-dimensional LiNi _0.8 Co _0.15 Al _0.05 O ₂ microrods as advanced cathode materials for lithium ion batteries Wu, Naiteng; Wu, Hao; Yuan, Wei Journal of Materials Chemistry A, Vol. 3, Issue 26 https://doi.org/10.1039/C5TA02767E	journal	January 2015
Effects of fluorine doping on structure, surface chemistry, and electrochemical performance of LiNi_0.8Co_0.15Al_0.05O₂ Li, Xiang; Xie, Zhengwei; Liu, Wenjing Electrochimica Acta, Vol. 174, p. 1122-1130 https://doi.org/10.1016/j.electacta.2015.06.099	journal	August 2015
Degradation analysis of a Ni-based layered positive-electrode active material cycled at elevated temperatures studied by scanning transmission electron microscopy and electron energy-loss spectroscopy Kojima, Y.; Muto, S.; Tatsumi, K. Journal of Power Sources, Vol. 196, Issue 18 https://doi.org/10.1016/j.jpowsour.2011.05.017	journal	September 2011
A facile method for synthesis of LiNi 0.8 Co 0.15 Al 0.05 O 2 cathode material Qiu, Zhenping; Zhang, Yingjie; Dong, Peng Solid State Ionics, Vol. 307 https://doi.org/10.1016/j.ssi.2017.04.011	journal	September 2017
Synthesis cathode material LiNi _0.80 Co _0.15 Al _0.05 O ₂ with two step solid-state method under air stream Xia, Shubiao; Zhang, Yingjie; Dong, Peng The European Physical Journal Applied Physics, Vol. 65, Issue 1 https://doi.org/10.1051/epjap/2013130328	journal	January 2014
Enhanced cycling stability and rate capability of LiNi0.80Co0.15Al0.05O2 cathode material by a facile coating method Tian, Lingyun; Liang, Kui; Wen, Xiaofeng Journal of Electroanalytical Chemistry, Vol. 812 https://doi.org/10.1016/j.jelechem.2018.01.045	journal	March 2018
Synthesis, Structure, and Electrochemical Behavior of Li[Ni[sub x]Li[sub 1/3−2x/3]Mn[sub 2/3−x/3]]O[sub 2] Lu, Zhonghua; Beaulieu, L. Y.; Donaberger, R. A. Journal of The Electrochemical Society, Vol. 149, Issue 6 https://doi.org/10.1149/1.1471541	journal	January 2002
Synthesis and electrochemical properties of LiNi0.80(Co0.20−xAlx)O2 (x=0.0 and 0.05) cathodes for Li ion rechargeable batteries Majumder, S. B.; Nieto, S.; Katiyar, R. S. Journal of Power Sources, Vol. 154, Issue 1 https://doi.org/10.1016/j.jpowsour.2005.03.186	journal	March 2006
Surface-engineering of layered LiNi 0.815 Co 0.15 Al 0.035 O 2 cathode material for high-energy and stable Li-ion batteries Li, Yugang; Yu, Haifeng; Hu, Yanjie Journal of Energy Chemistry, Vol. 27, Issue 2 https://doi.org/10.1016/j.jechem.2017.11.004	journal	March 2018
Synthesis of Layered LiMn _1/3 Ni _1/3 Co _1/3 O ₂ Oxides for Lithium-Ion Batteries using Biomass-Derived Glycerol as Solvent Hamad, Khaleel I.; Liao, Jin-Yun; Smith, Taylor W. Energy Technology, Vol. 6, Issue 4 https://doi.org/10.1002/ente.201700646	journal	December 2017
TiP2O7-coated LiNi0.8Co0.15Al0.05O2 cathode materials with improved thermal stability and superior cycle life Wu, Guan; Zhou, Yingke Journal of Energy Chemistry, Vol. 28 https://doi.org/10.1016/j.jechem.2018.01.018	journal	January 2019
Synthesis, structural characterization and magnetic properties of quasistoichiometric LiNiO2 Bianchi, V. Solid State Ionics, Vol. 140, Issue 1-2 https://doi.org/10.1016/S0167-2738(01)00706-8	journal	March 2001
High rate charge–discharge properties of LiNi1/3Co1/3Mn1/3O2 synthesized via a low temperature solid-state method Tan, Long; Liu, Haowen Solid State Ionics, Vol. 181, Issue 33-34 https://doi.org/10.1016/j.ssi.2010.08.016	journal	October 2010
Effect of Calcination Temperature of Size Controlled Microstructure of LiNi _0.8 Co _0.15 Al _0.05 O ₂ Cathode for Rechargeable Lithium Battery Park, Tae-Jun; Lim, Jung-Bin; Son, Jong-Tae Bulletin of the Korean Chemical Society, Vol. 35, Issue 2 https://doi.org/10.5012/bkcs.2014.35.2.357	journal	February 2014
Electrochemical properties of LiNi0.8Co0.2−xAlxO2 prepared by a sol–gel method Han, Chang Joo; Yoon, Jang Hyuk; Cho, Won Il Journal of Power Sources, Vol. 136, Issue 1 https://doi.org/10.1016/j.jpowsour.2004.05.006	journal	September 2004
Preparation of FePO4 by liquid-phase method and modification on the surface of LiNi0.80Co0.15Al0.05O2 cathode material Xia, Shubiao; Li, Fushao; Chen, Feixiang Journal of Alloys and Compounds, Vol. 731 https://doi.org/10.1016/j.jallcom.2017.10.047	journal	January 2018
Electrochemical characterization of zirconium-doped LiNi0.8Co0.2O2 cathode materials and investigations on deterioration mechanism Oh, Si Hyoung; Lee, Sang Myung; Cho, Won Il Electrochimica Acta, Vol. 51, Issue 18 https://doi.org/10.1016/j.electacta.2005.10.023	journal	May 2006
Effect of Cobalt and Nickel Contents on the Performance of Lithium Rich Materials Synthesized in Glycerol Solvent Hamad, Khaleel I.; Xing, Yangchuan Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0311811jes	journal	January 2018
Synthesis of spherical LiNi0.8Co0.15Al0.05O2 cathode materials for lithium-ion batteries by a co-oxidation-controlled crystallization method Liu, Wan Min; Hu, Guo Rong; Peng, Zhong Dong Chinese Chemical Letters, Vol. 22, Issue 9 https://doi.org/10.1016/j.cclet.2011.01.041	journal	September 2011
Study of full concentration-gradient Li(Ni0.8Co0.1Mn0.1)O2 cathode material for lithium ion batteries Hua, Chuanshan; Du, Ke; Tan, Chaopu Journal of Alloys and Compounds, Vol. 614 https://doi.org/10.1016/j.jallcom.2014.06.049	journal	November 2014
Enhanced elevated-temperature performance of Li(Ni0.8Co0.15Al0.05)O2 electrodes coated with Li2O-2B2O3 glass Lim, Sung Nam; Ahn, Wook; Yeon, Sun-Hwa Electrochimica Acta, Vol. 136 https://doi.org/10.1016/j.electacta.2014.05.056	journal	August 2014

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