Impact of Hydration on Supported V2O5/TiO2 Catalysts as Explored by Magnetic Resonance Spectroscopy

Jaegers, Nicholas R.; Wang, Yong; Hu, Jian Zhi; Wachs, Israel E.

doi:10.1021/acs.jpcc.1c04150

Impact of Hydration on Supported V₂O₅/TiO₂ Catalysts as Explored by Magnetic Resonance Spectroscopy

Journal Article · Fri Jul 23 00:00:00 EDT 2021 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.1c04150· OSTI ID:1821593

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Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washington State Univ., Pullman, WA (United States)
Lehigh Univ., Bethlehem, PA (United States)

Supported vanadium oxide catalysts are important industrial materials for a wide array of chemical transformations. The condition of surface hydration is of particular interest as a reflection of the state of a freshly manufactured catalysts prior to its activation in catalytic reactors or under conditions of photocatalysis where surface vandia are exposed to moisture. Under such conditions, the surface vanadia species undergo structural changes as evidenced by ⁵¹V MAS NMR in this study. For low surface vanadia densities on titania, a modest trend towards the formation of dimeric and oligomeric vanadia species was observed under hydrated conditions when compared to the corresponding dehydrated catalyst, which contains a large abundance of monomeric vanadia species. The incorporation of tungsten oxide to the V₂O₅/TiO₂ catalyst with low surface vanadia density, however, is found to better stabilize the surface vanadia species on the titania support upon hydration than its tungsta-free counterpart. This stabilization is not an intrinsic property of more extensively oligomerized surface vanadia species in the presence of tungsten oxide, evidenced by conditions of high concentrations of surface vanadia oligomers on titania that exhibit dramatic structural changes upon hydration. At high surface vanadia coverage under hydrated environments, the simultaneous observation of crystalline V₂O₅ nanoparticles and a mobile phase of surface vanadia species is apparent, where vanadia species are dissolved in the thin hydration layer on the titania support. These new findings have broad implications on the behavior of other metal oxide species on high surface oxide supports under hydrated conditions.

View Accepted Manuscript (DOE)

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1821593

Report Number(s):: PNNL-SA--157476

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 30 Vol. 125; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
51V NMR
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Catalysts
Hydration
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Metal Oxide
Oxides
V2O5/TiO2
Vanadium
Vanadium oxide

Impact of Hydration on Supported V2O5/TiO2 Catalysts as Explored by Magnetic Resonance Spectroscopy

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Impact of Hydration on Supported V₂O₅/TiO₂ Catalysts as Explored by Magnetic Resonance Spectroscopy