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Title: Solid-state vanadium-51 NMR studies of supported V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalysts

Abstract

Solid-state wide-line vanadium-51 NMR spectra of supported V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalysts were obtained under ambient conditions. A distorted tetrahedral vanadium unit is favored at low vanadia loadings in the absence of tungsten oxide. Generally, addition of tungsten oxide to low loadings of vanadia supported on titania promotes the formation of a distorted octahedral vanadium species, while a distorted tetrahedral vanadium unit is also present. A distorted octahedral vanadium unit is favored on the surface at high vanadia loadings in both the presence and absence of tungsten oxide.

Authors:
;
Publication Date:
Research Org.:
Long Island Univ., Brooklyn, NY (US)
OSTI Identifier:
20050862
Resource Type:
Journal Article
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 12; Journal Issue: 3; Other Information: PBD: Mar 2000; Journal ID: ISSN 0897-4756
Country of Publication:
United States
Language:
English
Subject:
33 ADVANCED PROPULSION SYSTEMS; 54 ENVIRONMENTAL SCIENCES; 01 COAL, LIGNITE, AND PEAT; NITROGEN OXIDES; CATALYTIC CONVERTERS; VANADIUM COMPOUNDS; TUNGSTEN OXIDES; AIR POLLUTION ABATEMENT; EXHAUST GASES; FLUE GAS

Citation Formats

Gheorghe, C, and Gee, B. Solid-state vanadium-51 NMR studies of supported V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalysts. United States: N. p., 2000. Web. doi:10.1021/cm990416f.
Gheorghe, C, & Gee, B. Solid-state vanadium-51 NMR studies of supported V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalysts. United States. https://doi.org/10.1021/cm990416f
Gheorghe, C, and Gee, B. 2000. "Solid-state vanadium-51 NMR studies of supported V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalysts". United States. https://doi.org/10.1021/cm990416f.
@article{osti_20050862,
title = {Solid-state vanadium-51 NMR studies of supported V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalysts},
author = {Gheorghe, C and Gee, B},
abstractNote = {Solid-state wide-line vanadium-51 NMR spectra of supported V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} catalysts were obtained under ambient conditions. A distorted tetrahedral vanadium unit is favored at low vanadia loadings in the absence of tungsten oxide. Generally, addition of tungsten oxide to low loadings of vanadia supported on titania promotes the formation of a distorted octahedral vanadium species, while a distorted tetrahedral vanadium unit is also present. A distorted octahedral vanadium unit is favored on the surface at high vanadia loadings in both the presence and absence of tungsten oxide.},
doi = {10.1021/cm990416f},
url = {https://www.osti.gov/biblio/20050862}, journal = {Chemistry of Materials},
issn = {0897-4756},
number = 3,
volume = 12,
place = {United States},
year = {Wed Mar 01 00:00:00 EST 2000},
month = {Wed Mar 01 00:00:00 EST 2000}
}