Electron emission from fluorene (C13H10) upon 3.5 MeV/u Si8+ ion impact: double differential distributions

Bagdia, Chandan; Mandal, Anuvab; Roy Chowdhury, Madhusree; Bhattacharjee, Shamik; Nrisimha Murty, M.; Misra, Deepankar; Champion, Christophe; Gulyás, László; Weck, Philippe F.; Tribedi, Lokesh C.

doi:10.1088/1361-6455/ac1a1e

Electron emission from fluorene (C₁₃H₁₀) upon 3.5 MeV/u Si⁸⁺ ion impact: double differential distributions

Journal Article · Wed Aug 25 00:00:00 EDT 2021 · Journal of Physics. B, Atomic, Molecular and Optical Physics

DOI:https://doi.org/10.1088/1361-6455/ac1a1e· OSTI ID:1817733

^[1]; Mandal, Anuvab ^[1]; Roy Chowdhury, Madhusree ^[1]; Bhattacharjee, Shamik ^[1]; Nrisimha Murty, M. ^[1]; ^[1]; Champion, Christophe ^[2]; Gulyás, László ^[3]; Weck, Philippe F. ^[4]; ^[1]

Tata Inst. of Fundamental Research, Mumbai (India)
Univ. de Bordeaux, Talence (France). CNRS-CEA, Centre Lasers Intenses et Applications (CELiA)
Inst. of Nuclear Research of the Hungarian Academy of Sciences (ATOMKI), Debrecen (Hungary)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

In this work, we have studied the electron emission from one of the polycyclic aromatic hydrocarbon (PAH) molecules namely, fluorene (C13H10), upon 3.5 MeV/u Si8+ ion impact. The experimentally measured absolute double differential cross sections (DDCS) are compared with the continuum distorted wave-eikonal initial state (CDW-EIS) model and the first Born approximation including correct boundary conditions (CB1). The measurements are carried out in the ejected e⁻-energy range of 1 eV–400 eV and in the angular range of 20°–160°. We have obtained the single differential and the total cross sections (TCSs) of e⁻-emission as well. The CB1 calculation largely underestimates the data. The CDW-EIS model, which is applied for the PAH molecule for the first time, provides an overall better agreement with the double differential, single differential and TCS data. The DDCS data for fluorene has also been compared with that for CH4 molecule, at a few angles. The forward–backward angular asymmetry shows a relatively flatter distribution compared to the theoretical predictions. The contribution due to the giant plasmon resonance could not be clearly observed except a mild indication in the asymmetry parameter. The angular distribution of the carbon KLL Auger electron cross section shows certain variations. The study of the KLL hyper-satellite component indicates the double K-ionization cross section is about 8.6% of the single K-ionization one.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003525

OSTI ID:: 1817733

Alternate ID(s):: OSTI ID: 23185192

Report Number(s):: SAND--2021-9848J; 698220

Journal Information:: Journal of Physics. B, Atomic, Molecular and Optical Physics, Journal Name: Journal of Physics. B, Atomic, Molecular and Optical Physics Journal Issue: 15 Vol. 54; ISSN 0953-4075

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

References (60)

Synthesis of a Giant 222 Carbon Graphite Sheet Simpson, Christopher D.; Brand, J. Diedrich; Berresheim, Alexander J. Chemistry - A European Journal, Vol. 8, Issue 6 https://doi.org/10.1002/1521-3765(20020315)8:6<1424::aid-chem1424>3.0.co;2-z	journal	March 2002
K‐K electron capture from adenine and CO ₂ molecule by fast carbon ions using KLL‐Auger electron technique Bagdia, Chandan; Bhattacharjee, Shamik; Roychowdhury, Madhusree X-Ray Spectrometry, Vol. 49, Issue 1 https://doi.org/10.1002/xrs.3078	journal	April 2019
Plasmon excitation in polycyclic aromatic hydrocarbons studied by photoionization Ling, Yun; Lifshitz, Chava Chemical Physics Letters, Vol. 257, Issue 5-6 https://doi.org/10.1016/0009-2614(96)00592-1	journal	August 1996
Electron capture in high-energy ion-atom collisions Belkic, D. Physics Reports, Vol. 56, Issue 6 https://doi.org/10.1016/0370-1573(79)90035-8	journal	December 1979
Vapor pressure measurements on fluorene and methyl-fluorenes Verevkin, Sergey P. Fluid Phase Equilibria, Vol. 225 https://doi.org/10.1016/j.fluid.2004.08.037	journal	November 2004
Double differential distributions of electron emission in ion–atom and electron–atom collisions using an electron spectrometer Misra, Deepankar; Thulasiram, K. V.; Fernandes, W. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 267, Issue 1 https://doi.org/10.1016/j.nimb.2008.10.091	journal	January 2009
Low-energy ions interacting with anthracene molecules and clusters Rousseau, P.; Ławicki, A.; Holm, A. I. S. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 279 https://doi.org/10.1016/j.nimb.2011.10.050	journal	May 2012
Proton-induced ionization of isolated uracil molecules: A theory/experiment confrontation Champion, C.; Galassi, M. E.; Weck, P. F. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 314 https://doi.org/10.1016/j.nimb.2013.04.063	journal	November 2013
VUV peaks in absorption spectra and photoion yield curves of polycyclic aromatic hydrocarbons and related compounds Jochims, H. W.; Rühl, E.; Baumgärtel, H. International Journal of Mass Spectrometry and Ion Processes, Vol. 167-168 https://doi.org/10.1016/s0168-1176(97)00031-1	journal	November 1997
Differential electron emission from polycyclic aromatic hydrocarbon molecules under fast ion impact Biswas, Shubhadeep; Champion, Christophe; Weck, P. F. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-05149-8	journal	July 2017
Polycyclic aromatic hydrocarbon processing in interstellar shocks Micelotta, E. R.; Jones, A. P.; Tielens, A. G. G. M. Astronomy and Astrophysics, Vol. 510 https://doi.org/10.1051/0004-6361/200911682	journal	February 2010
Polycyclic aromatic hydrocarbon processing by cosmic rays Micelotta, E. R.; Jones, A. P.; Tielens, A. G. G. M. Astronomy & Astrophysics, Vol. 526 https://doi.org/10.1051/0004-6361/201015741	journal	December 2010
Quelques aspects de la théorie des orbitales moléculaires (suite et fin) Mulliken, Robert S. Journal de Chimie Physique, Vol. 46 https://doi.org/10.1051/jcp/1949460675	journal	January 1949
Correlation Effects of π Electrons. III. Oscillator Strength Distribution Gutfreund, H.; Little, W. A. The Journal of Chemical Physics, Vol. 50, Issue 10 https://doi.org/10.1063/1.1670919	journal	May 1969
Photoelectron spectra of polynuclear aromatics. III. The effect of nonplanarity in sterically overcrowded aromatic hydrocarbons Boschi, R.; Clar, E.; Schmidt, W. The Journal of Chemical Physics, Vol. 60, Issue 11 https://doi.org/10.1063/1.1680919	journal	June 1974
Approximate Self‐Consistent Molecular Orbital Theory. III. CNDO Results for AB ₂ and AB ₃ Systems Pople, J. A.; Segal, G. A. The Journal of Chemical Physics, Vol. 44, Issue 9 https://doi.org/10.1063/1.1727227	journal	May 1966
Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen Dunning, Thom H. The Journal of Chemical Physics, Vol. 90, Issue 2 https://doi.org/10.1063/1.456153	journal	January 1989
Quantum-mechanical predictions of electron-induced ionization cross sections of DNA components Champion, Christophe The Journal of Chemical Physics, Vol. 138, Issue 18 https://doi.org/10.1063/1.4802962	journal	May 2013
The photoelectric heating mechanism for very small graphitic grains and polycyclic aromatic hydrocarbons Bakes, E. L. O.; Tielens, A. G. G. M. The Astrophysical Journal, Vol. 427 https://doi.org/10.1086/174188	journal	May 1994
The Effects of Polycyclic Aromatic Hydrocarbons on the Chemistry of Photodissociation Regions Bakes, E. L. O.; Tielens, A. G. G. M. The Astrophysical Journal, Vol. 499, Issue 1 https://doi.org/10.1086/305625	journal	May 1998
Modeling the Unidentified Infrared Emission with Combinations of Polycyclic Aromatic Hydrocarbons Allamandola, L. J.; Hudgins, D. M.; Sandford, S. A. The Astrophysical Journal, Vol. 511, Issue 2 https://doi.org/10.1086/311843	journal	February 1999
IONIZATION AND FRAGMENTATION OF ANTHRACENE UPON INTERACTION WITH keV PROTONS AND α PARTICLES Postma, J.; Bari, S.; Hoekstra, R. The Astrophysical Journal, Vol. 708, Issue 1 https://doi.org/10.1088/0004-637x/708/1/435	journal	December 2009
A tale of two Mysteries in Interstellar Astrophysics: the 2175 Å Extinction bump and Diffuse Interstellar Bands Xiang, F. Y.; Li, Aigen; Zhong, J. X. The Astrophysical Journal, Vol. 733, Issue 2 https://doi.org/10.1088/0004-637x/733/2/91	journal	May 2011
Theoretical study of inner-shell alignment of atoms in electron impact ionisation: angular distribution and polarisation of X-rays and Auger electrons Berezhko, E. G.; Kabachnik, N. M. Journal of Physics B: Atomic and Molecular Physics, Vol. 10, Issue 12 https://doi.org/10.1088/0022-3700/10/12/025	journal	August 1977
The first Born approximation for charge transfer collisions Belkic, D.; Gayet, R.; Hanssen, J. Journal of Physics B: Atomic and Molecular Physics, Vol. 19, Issue 18 https://doi.org/10.1088/0022-3700/19/18/023	journal	September 1986
Ionization of atomic hydrogen by proton impact Salin, A. Journal of Physics B: Atomic and Molecular Physics, Vol. 2, Issue 6 https://doi.org/10.1088/0022-3700/2/6/301	journal	June 1969
Theoretical predictions for ionization cross sections of DNA nucleobases impacted by light ions Champion, C.; Lekadir, H.; Galassi, M. E. Physics in Medicine and Biology, Vol. 55, Issue 20 https://doi.org/10.1088/0031-9155/55/20/002	journal	September 2010
CDW-EIS theory of ionization by ion impact with Hartree-Fock description of the target Gulyas, L.; Fainstein, P. D.; Salin, A. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 28, Issue 2 https://doi.org/10.1088/0953-4075/28/2/013	journal	January 1995
Activation energies for fragmentation channels of anthracene dications—experiment and theory Reitsma, G.; Zettergren, H.; Martin, S. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 45, Issue 21 https://doi.org/10.1088/0953-4075/45/21/215201	journal	September 2012
Absolute total ionization cross sections of uracil (C ₄ H ₄ N ₂ O ₂ ) in collisions with MeV energy highly charged carbon, oxygen and fluorine ions Agnihotri, A. N.; Kasthurirangan, S.; Nandi, S. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 46, Issue 18 https://doi.org/10.1088/0953-4075/46/18/185201	journal	September 2013
Ion–polycyclic aromatic hydrocarbon collisions: kinetic energy releases for specific fragmentation channels Reitsma, G.; Zettergren, H.; Boschman, L. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 46, Issue 24 https://doi.org/10.1088/0953-4075/46/24/245201	journal	November 2013
CDW-EIS calculation for ionization and fragmentation of methane impacted by fast protons Gulyás, L.; Tóth, I.; Nagy, L. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 46, Issue 7 https://doi.org/10.1088/0953-4075/46/7/075201	journal	March 2013
Ionization of water molecules by ion beams. On the relevance of dynamic screening and the influence of the description of the initial state Tachino, C. A.; Monti, J. M.; Fojón, O. A. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 47, Issue 3 https://doi.org/10.1088/0953-4075/47/3/035203	journal	January 2014
Velocity dependence of fragmentation yields in proton–naphthalene collision and comparison with electronic energy loss calculation Mishra, P. M.; Rajput, J.; Safvan, C. P. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 47, Issue 8 https://doi.org/10.1088/0953-4075/47/8/085202	journal	April 2014
Differential electron emission in the ionization of Ne and Xe atoms under fast bare carbon ion impact Biswas, Shubhadeep; Monti, J. M.; Tachino, C. A. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 48, Issue 11 https://doi.org/10.1088/0953-4075/48/11/115206	journal	April 2015
Knockout driven reactions in complex molecules and their clusters Gatchell, Michael; Zettergren, Henning Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 49, Issue 16 https://doi.org/10.1088/0953-4075/49/16/162001	journal	August 2016
Double differential distribution of electron emission in the ionization of water molecules by fast bare oxygen ions Bhattacharjee, Shamik; Biswas, Shubhadeep; Bagdia, Chandan Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 49, Issue 6 https://doi.org/10.1088/0953-4075/49/6/065202	journal	February 2016
Quantum and classical phenomena in photoionization of carbon nanostructures Verkhovtsev, A. V.; Korol, A. V.; Solov'yov, A. V. Journal of Physics: Conference Series, Vol. 490 https://doi.org/10.1088/1742-6596/490/1/012159	journal	March 2014
Auger-electron and x-ray production in 50- to 2000-keV Ne+Ne collisions Stolterfoht, N.; Schneider, D.; Burch, D. Physical Review A, Vol. 12, Issue 4 https://doi.org/10.1103/physreva.12.1313	journal	October 1975
Angular asymmetry of low-energy electron emission in ion-atom collisions Fainstein, P. D.; Gulyás, L.; Martín, F. Physical Review A, Vol. 53, Issue 5 https://doi.org/10.1103/physreva.53.3243	journal	May 1996
Ionization of uracil in collisions with highly charged carbon and oxygen ions of energy 100 keV to 78 MeV Agnihotri, A. N.; Kasthurirangan, S.; Nandi, S. Physical Review A, Vol. 85, Issue 3 https://doi.org/10.1103/physreva.85.032711	journal	March 2012
Statistical fragmentation of doubly charged anthracene induced by fluorine-beam impact at 3 keV Martin, S.; Chen, L.; Brédy, R. Physical Review A, Vol. 85, Issue 5 https://doi.org/10.1103/physreva.85.052715	journal	May 2012
Doubly differential distribution of electron emission in ionization of uracil in collisions with 3.5-MeV/u bare C ions Agnihotri, A. N.; Nandi, S.; Kasthurirangan, S. Physical Review A, Vol. 87, Issue 3 https://doi.org/10.1103/physreva.87.032716	journal	March 2013
Double-differential cross sections for ionization of H 2 O by fast bare O ions: Comparison with continuum-distorted-wave eikonal-initial-state calculations in prior and post forms Nandi, S.; Biswas, S.; Khan, A. Physical Review A, Vol. 87, Issue 5 https://doi.org/10.1103/physreva.87.052710	journal	May 2013
Cross sections for ionization of uracil by MeV-energy-proton impact Itoh, A.; Iriki, Y.; Imai, M. Physical Review A, Vol. 88, Issue 5 https://doi.org/10.1103/physreva.88.052711	journal	November 2013
Energy and angular distribution of electrons in ionization of He and Ne by 6-MeV/u bare carbon ions: Comparison with continuum-distorted-wave eikonal-initial-state calculations in prior and post forms Biswas, Shubhadeep; Misra, D.; Monti, J. M. Physical Review A, Vol. 90, Issue 5 https://doi.org/10.1103/physreva.90.052714	journal	November 2014
Electron emission in ionization of He and Ne by fast dressed oxygen ions and projectile-charge-state dependence Biswas, Shubhadeep; Kasthurirangan, S.; Misra, D. Physical Review A, Vol. 91, Issue 2 https://doi.org/10.1103/physreva.91.022711	journal	February 2015
Plasmon-mediated electron emission from the coronene molecule under fast ion impact Biswas, Shubhadeep; Tribedi, L. C. Physical Review A, Vol. 92, Issue 6 https://doi.org/10.1103/physreva.92.060701	journal	December 2015
Single and multiple electron removal and fragmentation in collisions of protons with water molecules Gulyás, L.; Egri, S.; Ghavaminia, H. Physical Review A, Vol. 93, Issue 3 https://doi.org/10.1103/physreva.93.032704	journal	March 2016
Double-differential cross section for ionization of H 2 O molecules by 4-MeV/u C 6 + and Si 13 + ions Bhattacharjee, Shamik; Biswas, S.; Monti, J. M. Physical Review A, Vol. 96, Issue 5 https://doi.org/10.1103/physreva.96.052707	journal	November 2017
Ions Colliding with Cold Polycyclic Aromatic Hydrocarbon Clusters Holm, A. I. S.; Zettergren, H.; Johansson, H. A. B. Physical Review Letters, Vol. 105, Issue 21 https://doi.org/10.1103/physrevlett.105.213401	journal	November 2010
Angular Distribution of Molecular K -Shell Auger Electrons: Spectroscopy of Photoabsorption Anisotropy Dill, Dan; Swanson, John R.; Wallace, Scott Physical Review Letters, Vol. 45, Issue 17 https://doi.org/10.1103/physrevlett.45.1393	journal	October 1980
Observation of nonisotropic Auger angular distribution in the C(1 s ) shape resonance of CO Hemmers, O.; Heiser, F.; Eiben, J. Physical Review Letters, Vol. 71, Issue 7 https://doi.org/10.1103/physrevlett.71.987	journal	August 1993
The molecular universe Tielens, A. G. G. M. Reviews of Modern Physics, Vol. 85, Issue 3 https://doi.org/10.1103/revmodphys.85.1021	journal	July 2013
Carbon in the Universe Henning, T.; Salama, F. Science, Vol. 282, Issue 5397 https://doi.org/10.1126/science.282.5397.2204	journal	December 1998
Double differential electron emission from N2 under impact of fast C6+ ions and Young-type interference Nandi, Saikat; Biswas, Shubhadeep; Tachino, Carmen A. The European Physical Journal D, Vol. 69, Issue 8 https://doi.org/10.1140/epjd/e2015-60102-0	journal	August 2015
An independent-atom-model description of ion-molecule collisions including geometric screening corrections Lüdde, Hans Jürgen; Achenbach, Alexander; Kalkbrenner, Thilo The European Physical Journal D, Vol. 70, Issue 4 https://doi.org/10.1140/epjd/e2016-70097-5	journal	April 2016
Energy and angular distribution of electrons ejected from water by the impact of fast O8+ ion beams Bhattacharjee, Shamik; Bagdia, Chandan; Chowdhury, Madhusree Roy The European Physical Journal D, Vol. 72, Issue 1 https://doi.org/10.1140/epjd/e2017-80265-8	journal	January 2018
Angular Distributions of K-Shell Auger Electrons for Carbon, Nitrogen, Oxygen and Neon Excited by Energetic Ions Kobayashi, Naoto; Irie, Takatoshi; Maeda, Nobuhiro Journal of the Physical Society of Japan, Vol. 47, Issue 1 https://doi.org/10.1143/jpsj.47.234	journal	July 1979
Large polycyclic aromatic hydrocarbons: Synthesis and discotic organization Feng, Xinliang; Pisula, Wojciech; Müllen, Klaus Pure and Applied Chemistry, Vol. 81, Issue 12 https://doi.org/10.1351/pac-con-09-07-07	journal	October 2009

Similar Records

Doubly differential cross sections of low-energy electrons emitted in the ionization of molecular hydrogen by bare carbon ions

Journal Article · Sun Sep 01 00:00:00 EDT 1996 · Physical Review A · OSTI ID:383145

Double differential distributions of e-emission in ionization of N₂ by 3,4 and 5 keV electron impact

Journal Article · Thu Nov 05 19:00:00 EST 2020 · Journal of Physics. B, Atomic, Molecular and Optical Physics · OSTI ID:1670744

Electron emission from bromouracil and uracil induced by protons and radiosensitization

Journal Article · Wed Jul 20 20:00:00 EDT 2022 · New Journal of Physics · OSTI ID:1877151

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS

Electron emission from fluorene (C13H10) upon 3.5 MeV/u Si8+ ion impact: double differential distributions

Citation Formats

References (60)

Similar Records

Related Subjects

Electron emission from fluorene (C₁₃H₁₀) upon 3.5 MeV/u Si⁸⁺ ion impact: double differential distributions