Temperature-dependent x-ray fluorescent response from thermographic phosphors under x-ray excitation

Westphal, Eric R.; Brown, Alex D.; Quintana, Enrico C.; Kastengren, Alan L.; Son, Steven F.; Meyer, Terrence R.; Hoffmeister, Kathryn G.

doi:10.1063/5.0053469

Temperature-dependent x-ray fluorescent response from thermographic phosphors under x-ray excitation

Journal Article · Mon Jul 19 00:00:00 EDT 2021 · Applied Physics Letters

DOI:https://doi.org/10.1063/5.0053469· OSTI ID:1810351

^[1]; Brown, Alex D. ^[1]; Quintana, Enrico C. ^[2]; ^[3]; ^[1]; ^[1]; ^[2]

Purdue Univ., West Lafayette, IN (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Phosphor thermometry has been successfully applied within several challenging environments. Typically, the thermographic phosphors are excited by an ultraviolet light source, and the temperature-dependent spectral or temporal response is measured. However, this is challenging or impossible in optically thick environments. In addition, emission from other sources (e.g., a flame) may interfere with the optical phosphor emission. Furthermore, a temperature dependent x-ray excitation/emission could alleviate these issues as x-rays could penetrate obscurants with no interference from flame luminosity. In addition, x-ray emission could allow for thermometry within solids while simultaneously x-ray imaging the structural evolution. In this study, select thermographic phosphors were excited via x-ray radiation, and their x-ray emission characteristics were measured at various temperatures. Several of the phosphors showed varying levels of temperature dependence with the strongest sensitivity occurring for YAG:Dy and ZnGa₂O₄:Mn. This approach opens a path for less intrusive temperature measurements, particularly in optically opaque multiphase and solid phase combustion environments.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); US Office of Naval Research (ONR); US Air Force Office of Scientific Research (AFOSR); National Aeronautic and Space Administration (NASA)

Grant/Contract Number:: AC04-94AL85000; AC02-06CH11357; NA0003525

OSTI ID:: 1810351

Alternate ID(s):: OSTI ID: 1864832

Report Number(s):: SAND--2021-7342J; 697199

Journal Information:: Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 3 Vol. 119; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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