Recent Progress in Understanding Solid Electrolyte Interphase on Lithium Metal Anodes

Wu, Haiping; Jia, Hao; Wang, Chongmin; Zhang, Ji‐Guang; Xu, Wu

doi:10.1002/aenm.202003092

Recent Progress in Understanding Solid Electrolyte Interphase on Lithium Metal Anodes

Journal Article · Mon Dec 28 00:00:00 EST 2020 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.202003092· OSTI ID:1804553

Wu, Haiping ^[1]; Jia, Hao ^[1]; Wang, Chongmin ^[2]; Zhang, Ji‐Guang ^[1]; ^[1]

Energy and Environment Directorate Pacific Northwest National Laboratory Richland WA 99354 USA
Environmental and Molecular Sciences Laboratory Pacific Northwest National Laboratory Richland WA 99354 USA

Abstract

Lithium metal batteries (LMBs) are one of the most promising candidates for next‐generation high‐energy‐density rechargeable batteries. Solid electrolyte interphase (SEI) on Li metal anodes plays a significant role in influencing the Li deposition morphology and the cycle life of LMBs. However, a thorough understanding on the mechanisms of SEI formation and evolution is still inadequate. In this review, the progress in understanding structures, properties, and influencing factors of SEI, as well as efficient strategies of tailoring SEI are focused upon. First, the compositions, models, and recent progress in characterizing atomic structures of SEI are summarized. Second, the properties of SEI, including electronic conduction, ionic conduction, stability, and mechanical properties are elucidated. Structures and properties of SEI are greatly affected by multiple factors, thus interactions between these factors and SEI are systematically discussed. Correlations of SEI with Li deposition morphology, rate capability, and cycle life are further summarized. Moreover, efficient strategies of tailoring SEI with desired properties, including in situ SEI and ex situ SEI, are also reviewed. Finally, future directions, including in‐operando techniques, multi‐modality approaches for characterization of SEI, and artificial intelligence assisted understanding of correlations between electrolyte components and SEI properties are proposed.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1804553

Alternate ID(s):: OSTI ID: 1764981

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 5 Vol. 11; ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (180)

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang Advanced Functional Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adfm.201605989	journal	January 2017
Building Artificial Solid‐Electrolyte Interphase with Uniform Intermolecular Ionic Bonds toward Dendrite‐Free Lithium Metal Anodes Wang, Zhijie; Wang, Yanyan; Zhang, Zihe Advanced Functional Materials, Vol. 30, Issue 30 https://doi.org/10.1002/adfm.202002414	journal	May 2020
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng Advanced Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adma.201504526	journal	December 2015
An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes Liu, Yayuan; Lin, Dingchang; Yuen, Pak Yan Advanced Materials, Vol. 29, Issue 10 https://doi.org/10.1002/adma.201605531	journal	December 2016
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes Chen, Shuru; Zheng, Jianming; Mei, Donghai Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706102	journal	March 2018
In Situ Solid Electrolyte Interphase from Spray Quenching on Molten Li: A New Way to Construct High‐Performance Lithium‐Metal Anodes Liu, Sufu; Xia, Xinhui; Deng, Shengjue Advanced Materials, Vol. 31, Issue 3 https://doi.org/10.1002/adma.201806470	journal	September 2018
A Novel Organic “Polyurea” Thin Film for Ultralong-Life Lithium-Metal Anodes via Molecular-Layer Deposition Sun, Yipeng; Zhao, Yang; Wang, Jiwei Advanced Materials, Vol. 31, Issue 4 https://doi.org/10.1002/adma.201806541	journal	December 2018
Research Progress towards Understanding the Unique Interfaces between Concentrated Electrolytes and Electrodes for Energy Storage Applications Zheng, Jianming; Lochala, Joshua A.; Kwok, Alexander Advanced Science, Vol. 4, Issue 8 https://doi.org/10.1002/advs.201700032	journal	March 2017
Highly Stable Operation of Lithium Metal Batteries Enabled by the Formation of a Transient High-Concentration Electrolyte Layer Zheng, Jianming; Yan, Pengfei; Mei, Donghai Advanced Energy Materials, Vol. 6, Issue 8 https://doi.org/10.1002/aenm.201502151	journal	February 2016
Cross Talk between Transition Metal Cathode and Li Metal Anode: Unraveling Its Influence on the Deposition/Dissolution Behavior and Morphology of Lithium Betz, Johannes; Brinkmann, Jan‐Paul; Nölle, Roman Advanced Energy Materials, Vol. 9, Issue 21 https://doi.org/10.1002/aenm.201900574	journal	April 2019
Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode Chen, Hao; Pei, Allen; Lin, Dingchang Advanced Energy Materials, Vol. 9, Issue 22 https://doi.org/10.1002/aenm.201900858	journal	April 2019
The Failure of Solid Electrolyte Interphase on Li Metal Anode: Structural Uniformity or Mechanical Strength? Shen, Xin; Zhang, Rui; Chen, Xiang Advanced Energy Materials, Vol. 10, Issue 10 https://doi.org/10.1002/aenm.201903645	journal	March 2020
Galvanic Corrosion of Lithium‐Powder‐Based Electrodes Kolesnikov, Aleksei; Kolek, Martin; Dohmann, Jan Frederik Advanced Energy Materials, Vol. 10, Issue 15 https://doi.org/10.1002/aenm.202000017	journal	March 2020
Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range Zhang, Xianhui; Zou, Lianfeng; Xu, Yaobin Advanced Energy Materials, Vol. 10, Issue 22 https://doi.org/10.1002/aenm.202000368	journal	April 2020
Lithium Azide as an Electrolyte Additive for All-Solid-State Lithium-Sulfur Batteries Eshetu, Gebrekidan Gebresilassie; Judez, Xabier; Li, Chunmei Angewandte Chemie International Edition, Vol. 56, Issue 48 https://doi.org/10.1002/anie.201709305	journal	October 2017
A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes Li, Nian-Wu; Shi, Yang; Yin, Ya-Xia Angewandte Chemie International Edition, Vol. 57, Issue 6 https://doi.org/10.1002/anie.201710806	journal	January 2018
Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High-Voltage Lithium Metal Batteries Yan, Chong; Yao, Yu-Xing; Chen, Xiang Angewandte Chemie International Edition, Vol. 57, Issue 43 https://doi.org/10.1002/anie.201807034	journal	September 2018
Fluorine and Lithium: Ideal Partners for High‐Performance Rechargeable Battery Electrolytes Aspern, N.; Röschenthaler, G. ‐V.; Winter, M. Angewandte Chemie International Edition, Vol. 58, Issue 45 https://doi.org/10.1002/anie.201901381	journal	November 2019
Self‐Stabilized and Strongly Adhesive Supramolecular Polymer Protective Layer Enables Ultrahigh‐Rate and Large‐Capacity Lithium‐Metal Anode Wang, Gang; Chen, Chao; Chen, Yunhua Angewandte Chemie International Edition, Vol. 59, Issue 5 https://doi.org/10.1002/anie.201913351	journal	January 2020
Dendrite-Free Lithium Deposition via Flexible-Rigid Coupling Composite Network for LiNi _0.5 Mn _1.5 O ₄ /Li Metal Batteries Chai, Jingchao; Chen, Bingbing; Xian, Fang Small, Vol. 14, Issue 37 https://doi.org/10.1002/smll.201802244	journal	August 2018
The electrochemical behaviour of 1,3-dioxolane—LiClO4 solutions—I. Uncontaminated solutions Aurbach, Doron; Youngman, Orit; Gofer, Yosef Electrochimica Acta, Vol. 35, Issue 3 https://doi.org/10.1016/0013-4686(90)87055-7	journal	March 1990
The behaviour of lithium electrodes in propylene and ethylene carbonate: Te major factors that influence Li cycling efficiency Aurbach, Doron; Gofer, Yosef; Ben-Zion, Moshe Journal of Electroanalytical Chemistry, Vol. 339, Issue 1-2 https://doi.org/10.1016/0022-0728(92)80467-I	journal	November 1992
Spectroscopic studies of lithium in an ultrahigh vacuum system Aurbach, D.; Daroux, M.; McDougall, G. Journal of Electroanalytical Chemistry, Vol. 358, Issue 1-2 https://doi.org/10.1016/0022-0728(93)80431-G	journal	November 1993
What is special about fast ionic conductors? Huggins, R. A.; Rabenau, A. Materials Research Bulletin, Vol. 13, Issue 12 https://doi.org/10.1016/0025-5408(78)90122-8	journal	December 1978
Solutions of LiAsF6 in 1,3-dioxolane for secondary lithium batteries Gofer, Y.; Ben-Zion, M.; Aurbach, D. Journal of Power Sources, Vol. 39, Issue 2 https://doi.org/10.1016/0378-7753(92)80135-X	journal	January 1992
Recent studies of the lithium-liquid electrolyte interface Electrochemical, morphological and spectral studies of a few important systems Aurbach, Doron; Zaban, Arie; Gofer, Yosef Journal of Power Sources, Vol. 54, Issue 1 https://doi.org/10.1016/0378-7753(94)02044-4	journal	March 1995
Influence of manganese(II), cobalt(II), and nickel(II) additives in electrolyte on performance of graphite anode for lithium-ion batteries Komaba, Shinichi; Kumagai, Naoaki; Kataoka, Yoichi Electrochimica Acta, Vol. 47, Issue 8 https://doi.org/10.1016/S0013-4686(01)00847-7	journal	February 2002
The study of electrolyte solutions based on solvents from the “glyme” family (linear polyethers) for secondary Li battery systems Aurbach, Doron; Granot, Eran Electrochimica Acta, Vol. 42, Issue 4 https://doi.org/10.1016/S0013-4686(96)00231-9	journal	January 1997
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries Aurbach, Doron Journal of Power Sources, Vol. 89, Issue 2 https://doi.org/10.1016/S0378-7753(00)00431-6	journal	August 2000
Recent studies on the correlation between surface chemistry, morphology, three-dimensional structures and performance of Li and Li-C intercalation anodes in several important electrolyte systems Aurbach, D.; Zaban, A.; Ein-Eli, Y. Journal of Power Sources, Vol. 68, Issue 1 https://doi.org/10.1016/S0378-7753(97)02575-5	journal	September 1997
Interaction of Li+ ions with ethylene carbonate (EC): Density functional theory calculations Bhatt, Mahesh Datt; Cho, Maenghyo; Cho, Kyeongjae Applied Surface Science, Vol. 257, Issue 5 https://doi.org/10.1016/j.apsusc.2010.08.073	journal	December 2010
In-situ EC-AFM and ex-situ XPS characterization to investigate the mechanism of SEI formation in highly concentrated aqueous electrolyte for Li-ion batteries Zhang, Haitao; Wang, Deyu; Shen, Cai Applied Surface Science, Vol. 507 https://doi.org/10.1016/j.apsusc.2019.145059	journal	March 2020
Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries Fan, Xiulin; Chen, Long; Ji, Xiao Chem, Vol. 4, Issue 1 https://doi.org/10.1016/j.chempr.2017.10.017	journal	January 2018
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries Ren, Xiaodi; Chen, Shuru; Lee, Hongkyung Chem, Vol. 4, Issue 8 https://doi.org/10.1016/j.chempr.2018.05.002	journal	August 2018
Lithium transport within the solid electrolyte interphase Lu, Peng; Harris, Stephen J. Electrochemistry Communications, Vol. 13, Issue 10 https://doi.org/10.1016/j.elecom.2011.06.026	journal	October 2011
Effect of vinylene carbonate as additive to electrolyte for lithium metal anode Ota, Hitoshi; Shima, Kunihisa; Ue, Makoto Electrochimica Acta, Vol. 49, Issue 4 https://doi.org/10.1016/j.electacta.2003.09.010	journal	February 2004
Phase-field modeling of solid electrolyte interface (SEI) influence on Li dendritic behavior Yurkiv, Vitaliy; Foroozan, Tara; Ramasubramanian, Ajaykrishna Electrochimica Acta, Vol. 265 https://doi.org/10.1016/j.electacta.2018.01.212	journal	March 2018
Rational design of robust-flexible protective layer for safe lithium metal battery Li, Siyuan; Fan, Lei; Lu, Yingying Energy Storage Materials, Vol. 18 https://doi.org/10.1016/j.ensm.2018.09.015	journal	March 2019
Behavior of Lithium Metal Anodes under Various Capacity Utilization and High Current Density in Lithium Metal Batteries Jiao, Shuhong; Zheng, Jianming; Li, Qiuyan Joule, Vol. 2, Issue 1 https://doi.org/10.1016/j.joule.2017.10.007	journal	January 2018
Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions Ren, Xiaodi; Zou, Lianfeng; Cao, Xia Joule, Vol. 3, Issue 7 https://doi.org/10.1016/j.joule.2019.05.006	journal	July 2019
A Dynamic, Electrolyte-Blocking, and Single-Ion-Conductive Network for Stable Lithium-Metal Anodes Yu, Zhiao; Mackanic, David G.; Michaels, Wesley Joule, Vol. 3, Issue 11 https://doi.org/10.1016/j.joule.2019.07.025	journal	November 2019
A review on electrolyte additives for lithium-ion batteries Zhang, Sheng Shui Journal of Power Sources, Vol. 162, Issue 2, p. 1379-1394 https://doi.org/10.1016/j.jpowsour.2006.07.074	journal	November 2006
Effect of the atmosphere on chemical composition and electrochemical properties of solid electrolyte interface on electrodeposited Li metal Momma, Toshiyuki; Nara, Hiroki; Yamagami, Shinpei Journal of Power Sources, Vol. 196, Issue 15 https://doi.org/10.1016/j.jpowsour.2011.03.095	journal	August 2011
Suppression of aluminum corrosion by using high concentration LiTFSI electrolyte Matsumoto, Kazuaki; Inoue, Kazuhiko; Nakahara, Kentaro Journal of Power Sources, Vol. 231 https://doi.org/10.1016/j.jpowsour.2012.12.028	journal	June 2013
Characterization of the solid electrolyte interphase on lithium anode for preventing the shuttle mechanism in lithium–sulfur batteries Xiong, Shizhao; Xie, Kai; Diao, Yan Journal of Power Sources, Vol. 246 https://doi.org/10.1016/j.jpowsour.2013.08.041	journal	January 2014
Novel dual-salts electrolyte solution for dendrite-free lithium-metal based rechargeable batteries with high cycle reversibility Miao, Rongrong; Yang, Jun; Feng, Xuejiao Journal of Power Sources, Vol. 271 https://doi.org/10.1016/j.jpowsour.2014.08.011	journal	December 2014
Component-/structure-dependent elasticity of solid electrolyte interphase layer in Li-ion batteries: Experimental and computational studies Shin, Hosop; Park, Jonghyun; Han, Sangwoo Journal of Power Sources, Vol. 277 https://doi.org/10.1016/j.jpowsour.2014.11.120	journal	March 2015
Natural abundance 17O, 6Li NMR and molecular modeling studies of the solvation structures of lithium bis(fluorosulfonyl)imide/1,2-dimethoxyethane liquid electrolytes Wan, Chuan; Hu, Mary Y.; Borodin, Oleg Journal of Power Sources, Vol. 307 https://doi.org/10.1016/j.jpowsour.2015.12.120	journal	March 2016
Unraveling transition metal dissolution of Li1.04Ni1/3Co1/3Mn1/3O2 (NCM 111) in lithium ion full cells by using the total reflection X-ray fluorescence technique Evertz, Marco; Horsthemke, Fabian; Kasnatscheew, Johannes Journal of Power Sources, Vol. 329 https://doi.org/10.1016/j.jpowsour.2016.08.099	journal	October 2016
Effects of contaminant water on coulombic efficiency of lithium deposition/dissolution reactions in tetraglyme-based electrolytes Koshikawa, Hiroyuki; Matsuda, Shoichi; Kamiya, Kazuhide Journal of Power Sources, Vol. 350 https://doi.org/10.1016/j.jpowsour.2017.03.041	journal	May 2017
A propylene carbonate based gel polymer electrolyte for extended cycle life and improved safety performance of lithium ion batteries Jia, Hao; Onishi, Hitoshi; von Aspern, Natascha Journal of Power Sources, Vol. 397 https://doi.org/10.1016/j.jpowsour.2018.07.039	journal	September 2018
Investigation of solvation in lithium ion battery electrolytes by NMR spectroscopy Yang, Li; Xiao, Ang; Lucht, Brett L. Journal of Molecular Liquids, Vol. 154, Issue 2-3 https://doi.org/10.1016/j.molliq.2010.04.025	journal	July 2010
Liquid cell transmission electron microscopy observation of lithium metal growth and dissolution: Root growth, dead lithium and lithium flotsams Kushima, Akihiro; So, Kang Pyo; Su, Cong Nano Energy, Vol. 32 https://doi.org/10.1016/j.nanoen.2016.12.001	journal	February 2017
Synergism of Al-containing solid electrolyte interphase layer and Al-based colloidal particles for stable lithium anode Ye, Huan; Yin, Ya-Xia; Zhang, Shuai-Feng Nano Energy, Vol. 36 https://doi.org/10.1016/j.nanoen.2017.04.056	journal	June 2017
Atomic Structure of Electrochemically Deposited Lithium Metal and Its Solid Electrolyte Interphases Revealed by Cryo–electron Microscopy Xu, Yaobin; He, Yang; Wu, Haiping Microscopy and Microanalysis, Vol. 25, Issue S2 https://doi.org/10.1017/S1431927619011838	journal	August 2019
Li ₂ O Solid Electrolyte Interphase: Probing Transport Properties at the Chemical Potential of Lithium Guo, Rui; Gallant, Betar M. Chemistry of Materials, Vol. 32, Issue 13 https://doi.org/10.1021/acs.chemmater.0c00333	journal	May 2020
Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation Michan, Alison L.; Parimalam, Bharathy. S.; Leskes, Michal Chemistry of Materials, Vol. 28, Issue 22 https://doi.org/10.1021/acs.chemmater.6b02282	journal	November 2016
Stabilization of Lithium Metal Anodes by Hybrid Artificial Solid Electrolyte Interphase Kozen, Alexander C.; Lin, Chuan-Fu; Zhao, Oliver Chemistry of Materials, Vol. 29, Issue 15 https://doi.org/10.1021/acs.chemmater.7b01496	journal	July 2017
Long-Chain Li and Na Alkyl Carbonates as Solid Electrolyte Interphase Components: Structure, Ion Transport, and Mechanical Properties Schafzahl, Lukas; Ehmann, Heike; Kriechbaum, Manfred Chemistry of Materials, Vol. 30, Issue 10 https://doi.org/10.1021/acs.chemmater.8b00750	journal	May 2018
LiPF ₆ Stabilizer and Transition-Metal Cation Scavenger: A Bifunctional Bipyridine-Based Ligand for Lithium-Ion Battery Application Jia, Hao; Billmann, Bastian; Onishi, Hitoshi Chemistry of Materials, Vol. 31, Issue 11 https://doi.org/10.1021/acs.chemmater.9b00555	journal	May 2019
Operando Gas Monitoring of Solid Electrolyte Interphase Reactions on Lithium Hobold, Gustavo M.; Khurram, Aliza; Gallant, Betar M. Chemistry of Materials, Vol. 32, Issue 6 https://doi.org/10.1021/acs.chemmater.9b04550	journal	February 2020
Before Li Ion Batteries Winter, Martin; Barnett, Brian; Xu, Kang Chemical Reviews, Vol. 118, Issue 23 https://doi.org/10.1021/acs.chemrev.8b00422	journal	November 2018
Changing Established Belief on Capacity Fade Mechanisms: Thorough Investigation of LiNi _1/3 Co _1/3 Mn _1/3 O ₂ (NCM111) under High Voltage Conditions Kasnatscheew, Johannes; Evertz, Marco; Streipert, Benjamin The Journal of Physical Chemistry C, Vol. 121, Issue 3 https://doi.org/10.1021/acs.jpcc.6b11746	journal	January 2017
Conductivity, Viscosity, and Their Correlation of a Super-Concentrated Aqueous Electrolyte Ding, Michael S.; von Cresce, Arthur; Xu, Kang The Journal of Physical Chemistry C, Vol. 121, Issue 4 https://doi.org/10.1021/acs.jpcc.6b12636	journal	January 2017
Lithium Diffusion Mechanism through Solid–Electrolyte Interphase in Rechargeable Lithium Batteries Ramasubramanian, Ajaykrishna; Yurkiv, Vitaliy; Foroozan, Tara The Journal of Physical Chemistry C, Vol. 123, Issue 16 https://doi.org/10.1021/acs.jpcc.9b00436	journal	March 2019
Revealing Nanoscale Passivation and Corrosion Mechanisms of Reactive Battery Materials in Gas Environments Li, Yuzhang; Li, Yanbin; Sun, Yongming Nano Letters, Vol. 17, Issue 8 https://doi.org/10.1021/acs.nanolett.7b02630	journal	July 2017
Evolution of the Solid–Electrolyte Interphase on Carbonaceous Anodes Visualized by Atomic-Resolution Cryogenic Electron Microscopy Huang, William; Attia, Peter M.; Wang, Hansen Nano Letters, Vol. 19, Issue 8 https://doi.org/10.1021/acs.nanolett.9b01515	journal	July 2019
Distinct Nanoscale Interphases and Morphology of Lithium Metal Electrodes Operating at Low Temperatures Thenuwara, Akila C.; Shetty, Pralav P.; McDowell, Matthew T. Nano Letters, Vol. 19, Issue 12 https://doi.org/10.1021/acs.nanolett.9b03330	journal	October 2019
Atomic to Nanoscale Origin of Vinylene Carbonate Enhanced Cycling Stability of Lithium Metal Anode Revealed by Cryo-Transmission Electron Microscopy Xu, Yaobin; Wu, Haiping; He, Yang Nano Letters, Vol. 20, Issue 1 https://doi.org/10.1021/acs.nanolett.9b04111	journal	December 2019
Modeling the Interface between Lithium Metal and Its Native Oxide Lowe, Jeffrey S.; Siegel, Donald J. ACS Applied Materials & Interfaces, Vol. 12, Issue 41 https://doi.org/10.1021/acsami.0c12468	journal	September 2020
In-Depth Interfacial Chemistry and Reactivity Focused Investigation of Lithium–Imide- and Lithium–Imidazole-Based Electrolytes Eshetu, Gebrekidan Gebresilassie; Diemant, Thomas; Grugeon, Sylvie ACS Applied Materials & Interfaces, Vol. 8, Issue 25 https://doi.org/10.1021/acsami.6b04406	journal	June 2016
Li ⁺ -Desolvation Dictating Lithium-Ion Battery’s Low-Temperature Performances Li, Qiuyan; Lu, Dongping; Zheng, Jianming ACS Applied Materials & Interfaces, Vol. 9, Issue 49 https://doi.org/10.1021/acsami.7b13887	journal	November 2017
Suppression of Dendritic Lithium Growth by in Situ Formation of a Chemically Stable and Mechanically Strong Solid Electrolyte Interphase Wan, Guojia; Guo, Feihu; Li, Hui ACS Applied Materials & Interfaces, Vol. 10, Issue 1 https://doi.org/10.1021/acsami.7b14662	journal	December 2017
Flexible Artificial Solid Electrolyte Interphase Formed by 1,3-Dioxolane Oxidation and Polymerization for Metallic Lithium Anodes Li, Cheng; Lan, Qing; Yang, Yifu ACS Applied Materials & Interfaces, Vol. 11, Issue 2 https://doi.org/10.1021/acsami.8b16080	journal	December 2018
Li Alginate-Based Artificial SEI Layer for Stable Lithium Metal Anodes Zhong, Yicheng; Chen, Yuanmao; Cheng, Yifeng ACS Applied Materials & Interfaces, Vol. 11, Issue 41 https://doi.org/10.1021/acsami.9b12634	journal	September 2019
Resolving Nanoscopic and Mesoscopic Heterogeneity of Fluorinated Species in Battery Solid-Electrolyte Interphases by Cryogenic Electron Microscopy Huang, William; Wang, Hansen; Boyle, David T. ACS Energy Letters, Vol. 5, Issue 4 https://doi.org/10.1021/acsenergylett.0c00194	journal	March 2020
Effects of Atmospheric Gases on Li Metal Cyclability and Solid-Electrolyte Interphase Formation Wang, Evelyna; Dey, Sunita; Liu, Tao ACS Energy Letters, Vol. 5, Issue 4 https://doi.org/10.1021/acsenergylett.0c00257	journal	March 2020
High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating Zheng, Guangyuan; Wang, Chao; Pei, Allen ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00456	journal	November 2016
Guided Lithium Metal Deposition and Improved Lithium Coulombic Efficiency through Synergistic Effects of LiAsF ₆ and Cyclic Carbonate Additives Ren, Xiaodi; Zhang, Yaohui; Engelhard, Mark H. ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b00982	journal	November 2017
Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes Zheng, Jianming; Chen, Shuru; Zhao, Wengao ACS Energy Letters, Vol. 3, Issue 2 https://doi.org/10.1021/acsenergylett.7b01213	journal	January 2018
Regulating Anions in the Solvation Sheath of Lithium Ions for Stable Lithium Metal Batteries Zhang, Xue-Qiang; Chen, Xiang; Hou, Li-Peng ACS Energy Letters, Vol. 4, Issue 2 https://doi.org/10.1021/acsenergylett.8b02376	journal	January 2019
High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries Ren, Xiaodi; Zou, Lianfeng; Jiao, Shuhong ACS Energy Letters, Vol. 4, Issue 4 https://doi.org/10.1021/acsenergylett.9b00381	journal	March 2019
Current Density Regulated Atomic to Nanoscale Process on Li Deposition and Solid Electrolyte Interphase Revealed by Cryogenic Transmission Electron Microscopy Xu, Yaobin; Wu, Haiping; Jia, Hao ACS Nano, Vol. 14, Issue 7 https://doi.org/10.1021/acsnano.0c03344	journal	June 2020
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J. ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b02166	journal	May 2015
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme–Lithium Salt Equimolar Complexes Yoshida, Kazuki; Nakamura, Megumi; Kazue, Yuichi Journal of the American Chemical Society, Vol. 133, Issue 33, p. 13121-13129 https://doi.org/10.1021/ja203983r	journal	August 2011
Direct Calculation of Li-Ion Transport in the Solid Electrolyte Interphase Shi, Siqi; Lu, Peng; Liu, Zhongyi Journal of the American Chemical Society, Vol. 134, Issue 37 https://doi.org/10.1021/ja305366r	journal	September 2012
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism Ding, Fei; Xu, Wu; Graff, Gordon L. Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456 https://doi.org/10.1021/ja312241y	journal	March 2013
Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries Yamada, Yuki; Furukawa, Keizo; Sodeyama, Keitaro Journal of the American Chemical Society, Vol. 136, Issue 13, p. 5039-5046 https://doi.org/10.1021/ja412807w	journal	March 2014
Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer Liu, Kai; Pei, Allen; Lee, Hye Ryoung Journal of the American Chemical Society, Vol. 139, Issue 13 https://doi.org/10.1021/jacs.6b13314	journal	March 2017
Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability Zhao, Jie; Liao, Lei; Shi, Feifei Journal of the American Chemical Society, Vol. 139, Issue 33 https://doi.org/10.1021/jacs.7b05251	journal	August 2017
Ultrahigh Performance All Solid-State Lithium Sulfur Batteries: Salt Anion’s Chemistry-Induced Anomalous Synergistic Effect Eshetu, Gebrekidan Gebresilassie; Judez, Xabier; Li, Chunmei Journal of the American Chemical Society, Vol. 140, Issue 31 https://doi.org/10.1021/jacs.8b04612	journal	July 2018
Conductivity and Solvation of Li ⁺ Ions of LiPF ₆ in Propylene Carbonate Solutions Kondo, Kazutaka; Sano, Mitsuru; Hiwara, Akio The Journal of Physical Chemistry B, Vol. 104, Issue 20 https://doi.org/10.1021/jp000142f	journal	May 2000
Characterization of Lithium Alkyl Carbonates by X-ray Photoelectron Spectroscopy: Experimental and Theoretical Study Dedryvère, R.; Gireaud, L.; Grugeon, S. The Journal of Physical Chemistry B, Vol. 109, Issue 33 https://doi.org/10.1021/jp051626k	journal	August 2005
Lithium Ethylene Dicarbonate Identified as the Primary Product of Chemical and Electrochemical Reduction of EC in 1.2 M LiPF ₆ /EC:EMC Electrolyte Zhuang, Guorong V.; Xu, Kang; Yang, Hui The Journal of Physical Chemistry B, Vol. 109, Issue 37 https://doi.org/10.1021/jp052474w	journal	September 2005
Syntheses and Characterization of Lithium Alkyl Mono- and Dicarbonates as Components of Surface Films in Li-Ion Batteries Xu, Kang; Zhuang, Guorong V.; Allen, Jan L. The Journal of Physical Chemistry B, Vol. 110, Issue 15 https://doi.org/10.1021/jp0601522	journal	March 2006
Electrical and Lithium Ion Dynamics in Three Main Components of Solid Electrolyte Interphase from Density Functional Theory Study Chen, Y. C.; Ouyang, C. Y.; Song, L. J. The Journal of Physical Chemistry C, Vol. 115, Issue 14 https://doi.org/10.1021/jp112202s	journal	March 2011
Change from Glyme Solutions to Quasi-ionic Liquids for Binary Mixtures Consisting of Lithium Bis(trifluoromethanesulfonyl)amide and Glymes Yoshida, Kazuki; Tsuchiya, Mizuho; Tachikawa, Naoki The Journal of Physical Chemistry C, Vol. 115, Issue 37 https://doi.org/10.1021/jp206881t	journal	August 2011
Correlating Li ⁺ Solvation Sheath Structure with Interphasial Chemistry on Graphite von Wald Cresce, Arthur; Borodin, Oleg; Xu, Kang The Journal of Physical Chemistry C, Vol. 116, Issue 50 https://doi.org/10.1021/jp303610t	journal	December 2012
Defect Thermodynamics and Diffusion Mechanisms in Li ₂ CO ₃ and Implications for the Solid Electrolyte Interphase in Li-Ion Batteries Shi, Siqi; Qi, Yue; Li, Hong The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp310591u	journal	March 2013
Molecular Dynamics Simulations and Experimental Study of Lithium Ion Transport in Dilithium Ethylene Dicarbonate Borodin, Oleg; Zhuang, Guorong V.; Ross, Philip N. The Journal of Physical Chemistry C, Vol. 117, Issue 15 https://doi.org/10.1021/jp4000494	journal	April 2013
Understanding Transition-Metal Dissolution Behavior in LiNi _0.5 Mn _1.5 O ₄ High-Voltage Spinel for Lithium Ion Batteries Pieczonka, Nicholas P. W.; Liu, Zhongyi; Lu, Peng The Journal of Physical Chemistry C, Vol. 117, Issue 31 https://doi.org/10.1021/jp405158m	journal	July 2013
Why Bis(fluorosulfonyl)imide Is a “Magic Anion” for Electrochemistry Shkrob, Ilya A.; Marin, Timothy W.; Zhu, Ye The Journal of Physical Chemistry C, Vol. 118, Issue 34 https://doi.org/10.1021/jp506567p	journal	August 2014
Manganese in Graphite Anode and Capacity Fade in Li Ion Batteries Shkrob, Ilya A.; Kropf, A. Jeremy; Marin, Timothy W. The Journal of Physical Chemistry C, Vol. 118, Issue 42 https://doi.org/10.1021/jp507833u	journal	October 2014
Differentiating Contributions to “Ion Transfer” Barrier from Interphasial Resistance and Li ⁺ Desolvation at Electrolyte/Graphite Interface Xu, Kang; von Cresce, Arthur; Lee, Unchul Langmuir, Vol. 26, Issue 13 https://doi.org/10.1021/la1009994	journal	July 2010
Ultrathin Two-Dimensional Atomic Crystals as Stable Interfacial Layer for Improvement of Lithium Metal Anode Yan, Kai; Lee, Hyun-Wook; Gao, Teng Nano Letters, Vol. 14, Issue 10 https://doi.org/10.1021/nl503125u	journal	September 2014
Superconcentrated electrolytes for a high-voltage lithium-ion battery Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12032	journal	June 2016
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems Zhan, Chun; Lu, Jun; Jeremy Kropf, A. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3437	journal	September 2013
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth Li, Weiyang; Yao, Hongbin; Yan, Kai Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8436	journal	June 2015
Design principles for electrolytes and interfaces for stable lithium-metal batteries Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.114	journal	September 2016
A facile surface chemistry route to a stabilized lithium metal anode Liang, Xiao; Pang, Quan; Kochetkov, Ivan R. Nature Energy, Vol. 2, Issue 9 https://doi.org/10.1038/nenergy.2017.119	journal	July 2017
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.12	journal	March 2017
Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode Liu, Yayuan; Lin, Dingchang; Li, Yuzhang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06077-5	journal	September 2018
Identifying the components of the solid–electrolyte interphase in Li-ion batteries Wang, Luning; Menakath, Anjali; Han, Fudong Nature Chemistry, Vol. 11, Issue 9 https://doi.org/10.1038/s41557-019-0304-z	journal	August 2019
Stable cycling of high-voltage lithium metal batteries in ether electrolytes Jiao, Shuhong; Ren, Xiaodi; Cao, Ruiguo Nature Energy, Vol. 3, Issue 9 https://doi.org/10.1038/s41560-018-0199-8	journal	July 2018
Langmuir–Blodgett artificial solid-electrolyte interphases for practical lithium metal batteries Kim, Mun Sek; Ryu, Ji-Hyun Nature Energy, Vol. 3, Issue 10 https://doi.org/10.1038/s41560-018-0237-6	journal	September 2018
High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes Han, Fudong; Westover, Andrew S.; Yue, Jie Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-018-0312-z	journal	January 2019
Advances and issues in developing salt-concentrated battery electrolytes Yamada, Yuki; Wang, Jianhui; Ko, Seongjae Nature Energy https://doi.org/10.1038/s41560-019-0336-z	journal	March 2019
High-energy lithium metal pouch cells with limited anode swelling and long stable cycles Niu, Chaojiang; Lee, Hongkyung; Chen, Shuru Nature Energy, Vol. 4, Issue 7 https://doi.org/10.1038/s41560-019-0390-6	journal	May 2019
Improving cyclability of Li metal batteries at elevated temperatures and its origin revealed by cryo-electron microscopy Wang, Jiangyan; Huang, William; Pei, Allen Nature Energy, Vol. 4, Issue 8 https://doi.org/10.1038/s41560-019-0413-3	journal	July 2019
Long cycle life and dendrite-free lithium morphology in anode-free lithium pouch cells enabled by a dual-salt liquid electrolyte Weber, Rochelle; Genovese, Matthew; Louli, A. J. Nature Energy, Vol. 4, Issue 8 https://doi.org/10.1038/s41560-019-0428-9	journal	July 2019
Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization Cao, Xia; Ren, Xiaodi; Zou, Lianfeng Nature Energy, Vol. 4, Issue 9 https://doi.org/10.1038/s41560-019-0464-5	journal	September 2019
All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents Fan, Xiulin; Ji, Xiao; Chen, Long Nature Energy, Vol. 4, Issue 10 https://doi.org/10.1038/s41560-019-0474-3	journal	October 2019
Molecular design for electrolyte solvents enabling energy-dense and long-cycling lithium metal batteries Yu, Zhiao; Wang, Hansen; Kong, Xian Nature Energy, Vol. 5, Issue 7 https://doi.org/10.1038/s41560-020-0634-5	journal	June 2020
Understanding and applying coulombic efficiency in lithium metal batteries Xiao, Jie; Li, Qiuyan; Bi, Yujing Nature Energy, Vol. 5, Issue 8 https://doi.org/10.1038/s41560-020-0648-z	journal	June 2020
Polymer–inorganic solid–electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions Gao, Yue; Yan, Zhifei; Gray, Jennifer L. Nature Materials, Vol. 18, Issue 4 https://doi.org/10.1038/s41563-019-0305-8	journal	March 2019
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries Fan, Xiulin; Chen, Long; Borodin, Oleg Nature Nanotechnology, Vol. 13, Issue 8 https://doi.org/10.1038/s41565-018-0183-2	journal	July 2018
Real-time mass spectrometric characterization of the solid–electrolyte interphase of a lithium-ion battery Zhou, Yufan; Su, Mao; Yu, Xiaofei Nature Nanotechnology, Vol. 15, Issue 3 https://doi.org/10.1038/s41565-019-0618-4	journal	January 2020
Quantifying inactive lithium in lithium metal batteries Fang, Chengcheng; Li, Jinxing; Zhang, Minghao Nature, Vol. 572, Issue 7770 https://doi.org/10.1038/s41586-019-1481-z	journal	August 2019
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
3D visualization of inhomogeneous multi-layered structure and Young's modulus of the solid electrolyte interphase (SEI) on silicon anodes for lithium ion batteries Zheng, Jieyun; Zheng, Hao; Wang, Rui Phys. Chem. Chem. Phys., Vol. 16, Issue 26 https://doi.org/10.1039/C4CP01968G	journal	January 2014
Decomposition of the fluoroethylene carbonate additive and the glue effect of lithium fluoride products for the solid electrolyte interphase: an ab initio study Okuno, Yukihiro; Ushirogata, Keisuke; Sodeyama, Keitaro Physical Chemistry Chemical Physics, Vol. 18, Issue 12 https://doi.org/10.1039/C5CP07583A	journal	January 2016
Dynamics and morphology of solid electrolyte interphase (SEI) Single, Fabian; Horstmann, Birger; Latz, Arnulf Physical Chemistry Chemical Physics, Vol. 18, Issue 27 https://doi.org/10.1039/C6CP02816K	journal	January 2016
Effect of electrolyte on the nanostructure of the solid electrolyte interphase (SEI) and performance of lithium metal anodes Jurng, Sunhyung; Brown, Zachary L.; Kim, Jiyeon Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/C8EE00364E	journal	January 2018
An artificial solid interphase with polymers of intrinsic microporosity for highly stable Li metal anodes Moon, Gi Hyeon; Kim, Hyun Jong; Chae, Il Seok Chemical Communications, Vol. 55, Issue 44 https://doi.org/10.1039/C9CC01329F	journal	January 2019
Customizing a Li–metal battery that survives practical operating conditions for electric vehicle applications Hwang, Jang-Yeon; Park, Seong-Jin; Yoon, Chong S. Energy & Environmental Science, Vol. 12, Issue 7 https://doi.org/10.1039/C9EE00716D	journal	January 2019
FSI-inspired solvent and “full fluorosulfonyl” electrolyte for 4 V class lithium-metal batteries Xue, Weijiang; Shi, Zhe; Huang, Mingjun Energy & Environmental Science, Vol. 13, Issue 1 https://doi.org/10.1039/C9EE02538C	journal	January 2020
Single-ion conducting artificial solid electrolyte interphase layers for dendrite-free and highly stable lithium metal anodes Deng, Kuirong; Han, Dongmei; Ren, Shan Journal of Materials Chemistry A, Vol. 7, Issue 21 https://doi.org/10.1039/C9TA02407G	journal	January 2019
Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries Suo, Liumin; Xue, Weijiang; Gobet, Mallory Proceedings of the National Academy of Sciences, Vol. 115, Issue 6 https://doi.org/10.1073/pnas.1712895115	journal	January 2018
High-capacity rechargeable batteries based on deeply cyclable lithium metal anodes Shi, Qiuwei; Zhong, Yiren; Wu, Min Proceedings of the National Academy of Sciences, Vol. 115, Issue 22 https://doi.org/10.1073/pnas.1803634115	journal	May 2018
Lithium metal stripping beneath the solid electrolyte interphase Shi, Feifei; Pei, Allen; Boyle, David Thomas Proceedings of the National Academy of Sciences, Vol. 115, Issue 34 https://doi.org/10.1073/pnas.1806878115	journal	August 2018
The intrinsic behavior of lithium fluoride in solid electrolyte interphases on lithium He, Mingfu; Guo, Rui; Hobold, Gustavo M. Proceedings of the National Academy of Sciences, Vol. 117, Issue 1 https://doi.org/10.1073/pnas.1911017116	journal	December 2019
General method to predict voltage-dependent ionic conduction in a solid electrolyte coating on electrodes Pan, Jie; Cheng, Yang-Tse; Qi, Yue Physical Review B, Vol. 91, Issue 13 https://doi.org/10.1103/PhysRevB.91.134116	journal	April 2015
Stitching h-BN by atomic layer deposition of LiF as a stable interface for lithium metal anode Xie, Jin; Liao, Lei; Gong, Yongji Science Advances, Vol. 3, Issue 11 https://doi.org/10.1126/sciadv.aao3170	journal	November 2017
An Efficient Polymer Molecular Sieve for Membrane Gas Separations Carta, M.; Malpass-Evans, R.; Croad, M. Science, Vol. 339, Issue 6117, p. 303-307 https://doi.org/10.1126/science.1228032	journal	January 2013
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries Suo, L.; Borodin, O.; Gao, T. Science, Vol. 350, Issue 6263 https://doi.org/10.1126/science.aab1595	journal	November 2015
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
Electrochemical and Infrared Studies of the Reduction of Organic Carbonates Zhang, Xuerong; Kostecki, Robert; Richardson, Thomas J. Journal of The Electrochemical Society, Vol. 148, Issue 12 https://doi.org/10.1149/1.1415547	journal	January 2001
Chemical Analysis of Graphite/Electrolyte Interface Formed in LiBOB-Based Electrolytes Xu, Kang; Lee, Unchul; Zhang, Shengshui Electrochemical and Solid-State Letters, Vol. 6, Issue 7 https://doi.org/10.1149/1.1576049	journal	January 2003
Structural and Functional Analysis of Surface Film on Li Anode in Vinylene Carbonate-Containing Electrolyte Ota, Hitoshi; Sakata, Yuuichi; Otake, Yumiko Journal of The Electrochemical Society, Vol. 151, Issue 11 https://doi.org/10.1149/1.1798411	journal	January 2004
Electrochemical Deposition of Very Smooth Lithium Using Nonaqueous Electrolytes Containing HF Kanamura, Kiyoshi Journal of The Electrochemical Society, Vol. 143, Issue 7 https://doi.org/10.1149/1.1836979	journal	January 1996
Nonaqueous Electrolytes for Electrochemical Capacitors: Imidazolium Cations and Inorganic Fluorides with Organic Carbonates McEwen, Alan B.; McDevitt, Stephen F.; Koch, Victor R. Journal of The Electrochemical Society, Vol. 144, Issue 4 https://doi.org/10.1149/1.1837561	journal	April 1997
Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes Peled, E. Journal of The Electrochemical Society, Vol. 144, Issue 8 https://doi.org/10.1149/1.1837858	journal	January 1997
The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces Monroe, Charles; Newman, John Journal of The Electrochemical Society, Vol. 152, Issue 2 https://doi.org/10.1149/1.1850854	journal	January 2005
XPS Analysis of Lithium Surfaces Following Immersion in Various Solvents Containing LiBF[sub 4] Kanamura, Kiyoshi Journal of The Electrochemical Society, Vol. 142, Issue 2 https://doi.org/10.1149/1.2044000	journal	January 1995
The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries Aurbach, Doron Journal of The Electrochemical Society, Vol. 142, Issue 9 https://doi.org/10.1149/1.2048658	journal	January 1995
The Surface Chemistry of Lithium Electrodes in Alkyl Carbonate Solutions Aurbach, Doron Journal of The Electrochemical Society, Vol. 141, Issue 1 https://doi.org/10.1149/1.2054718	journal	January 1994
Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells Fong, Rosamaría Journal of The Electrochemical Society, Vol. 137, Issue 7 https://doi.org/10.1149/1.2086855	journal	January 1990
Identification of Surface Films Formed on Lithium in Propylene Carbonate Solutions Aurbach, D. Journal of The Electrochemical Society, Vol. 134, Issue 7 https://doi.org/10.1149/1.2100722	journal	January 1987
Lithium Cycling in Polymethoxymethane Solvents Foos, J. S.; McVeigh, J. Journal of The Electrochemical Society, Vol. 130, Issue 3 https://doi.org/10.1149/1.2119767	journal	March 1983
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model Peled, E. Journal of The Electrochemical Society, Vol. 126, Issue 12 https://doi.org/10.1149/1.2128859	journal	January 1979
Structure‐Reactivity Relationships of Methylated Tetrahydrofurans with Lithium Goldman, J. L.; Mank, R. M.; Young, J. H. Journal of The Electrochemical Society, Vol. 127, Issue 7 https://doi.org/10.1149/1.2129931	journal	July 1980
The Effect of Vinylene Carbonate Additive on Surface Film Formation on Both Electrodes in Li-Ion Batteries El Ouatani, L.; Dedryvère, R.; Siret, C. Journal of The Electrochemical Society, Vol. 156, Issue 2 https://doi.org/10.1149/1.3029674	journal	January 2009
Examining the Solid Electrolyte Interphase on Binder-Free Graphite Electrodes Xiao, Ang; Yang, Li; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 156, Issue 4 https://doi.org/10.1149/1.3078020	journal	January 2009
On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries Aurbach, Doron; Pollak, Elad; Elazari, Ran Journal of The Electrochemical Society, Vol. 156, Issue 8, p. A694-A702 https://doi.org/10.1149/1.3148721	journal	January 2009
Transport and Electrochemical Properties and Spectral Features of Non-Aqueous Electrolytes Containing LiFSI in Linear Carbonate Solvents Li, Lifei; Zhou, Sisi; Han, Hongbo Journal of The Electrochemical Society, Vol. 158, Issue 2 https://doi.org/10.1149/1.3514705	journal	January 2011
A High Precision Coulometry Study of the SEI Growth in Li/Graphite Cells Smith, A. J.; Burns, J. C.; Zhao, Xuemei Journal of The Electrochemical Society, Vol. 158, Issue 5 https://doi.org/10.1149/1.3557892	journal	January 2011
Investigation of the Solid Electrolyte Interphase Formed by Fluoroethylene Carbonate on Si Electrodes Nakai, Hideki; Kubota, Tadahiko; Kita, Akinori Journal of The Electrochemical Society, Vol. 158, Issue 7 https://doi.org/10.1149/1.3589300	journal	January 2011
Preferential Solvation of Li+ Directs Formation of Interphase on Graphitic Anode von Cresce, Arthur; Xu, Kang Electrochemical and Solid-State Letters, Vol. 14, Issue 10 https://doi.org/10.1149/1.3615828	journal	January 2011
How Transition Metals Enable Electron Transfer through the SEI: Part I. Experiments and Butler-Volmer Modeling Harris, Oliver C.; Lin, Yuxiao; Qi, Yue Journal of The Electrochemical Society, Vol. 167, Issue 1 https://doi.org/10.1149/2.0022001JES	journal	August 2019
How Transition Metals Enable Electron Transfer through the SEI: Part II. Redox-Cycling Mechanism Model and Experiment Harris, Oliver C.; Leung, Kevin; Tang, Maureen H. Journal of The Electrochemical Society, Vol. 167, Issue 1 https://doi.org/10.1149/2.0032001JES	journal	August 2019
Exploring the Impact of Mechanical Pressure on the Performance of Anode-Free Lithium Metal Cells Louli, A. J.; Genovese, Matthew; Weber, Rochelle Journal of The Electrochemical Society, Vol. 166, Issue 8 https://doi.org/10.1149/2.0091908jes	journal	January 2019
Resolution of the Modulus versus Adhesion Dilemma in Solid Polymer Electrolytes for Rechargeable Lithium Metal Batteries Stone, G. M.; Mullin, S. A.; Teran, A. A. Journal of The Electrochemical Society, Vol. 159, Issue 3 https://doi.org/10.1149/2.030203jes	journal	January 2012
Solvent Oligomerization during SEI Formation on Model Systems for Li-Ion Battery Anodes Tavassol, Hadi; Buthker, Joseph W.; Ferguson, Glen A. Journal of The Electrochemical Society, Vol. 159, Issue 6 https://doi.org/10.1149/2.067206jes	journal	January 2012
Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF ₆ , LiBF ₄ , LiDFOB, LiBOB, and LiTFSI Parimalam, Bharathy S.; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.0901802jes	journal	January 2018
Effects of Carbonate Solvents and Lithium Salts on Morphology and Coulombic Efficiency of Lithium Electrode Ding, Fei; Xu, Wu; Chen, Xilin Journal of The Electrochemical Society, Vol. 160, Issue 10 https://doi.org/10.1149/2.100310jes	journal	January 2013
Transport and Charge Carrier Chemistry in Lithium Oxide Lorger, Simon; Usiskin, Robert; Maier, Joachim Journal of The Electrochemical Society, Vol. 166, Issue 10 https://doi.org/10.1149/2.1121910jes	journal	January 2019
The Solid Electrolyte Interphase – The Most Important and the Least Understood Solid Electrolyte in Rechargeable Li Batteries Winter, Martin Zeitschrift für Physikalische Chemie, Vol. 223, Issue 10-11 https://doi.org/10.1524/zpch.2009.6086	journal	December 2009

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Recent progress in understanding solid electrolyte interphase on lithium metal anode

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Recent Progress in Understanding Solid Electrolyte Interphase on Lithium Metal Anodes

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