Recent progress in understanding solid electrolyte interphase on lithium metal anode

Wu, Haiping; Jia, Hao; Wang, Chongmin; Zhang, Jiguang; Xu, Wu

doi:10.1002/aenm.202003092

Recent progress in understanding solid electrolyte interphase on lithium metal anode

Journal Article · 04 February 2021 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.202003092· OSTI ID:1764981

Wu, Haiping ^[1]; Jia, Hao ^[1]; ^[1]; ^[1]; ^[1]

BATTELLE (PACIFIC NW LAB)

Lithium (Li) metal batteries (LMBs) are among the most promising candidates of next-generation high-energy-density rechargeable batteries. Solid electrolyte interphase (SEI) on Li metal anode plays a significant role which influences the Li deposition morphology and the cycle life of LMBs. Although SEI is the most important part, a thorough understanding of SEI is inadequate. In this review, we focus on the progresses of understanding on structures, properties and influencing factors of SEI as well as efficient strategies of tailoring SEI. First, the compositions, models and recent progresses on characterizing atomic structure of SEI are summarized. Second, the properties of SEI, including electronic conduction, ionic conduction, stability and mechanical properties are elucidated. Structures and properties of SEI are greatly influenced by multiple factors such as solvent, salt, additive, solvation structure, impurity, current density, temperature, pressure and capacity utilization. Thus, interactions between these factors and SEI are comprehensively discussed. Correlations of SEI with Li deposition morphology, rate capability and cycle life are further summarized. Moreover, efficient strategies of tailoring SEI with desired properties, including in-situ SEI and ex-situ SEI are also reviewed. Despite the significant progresses that have been achieved in the researches of SEI, better understanding of SEI is still highly demand. Finally, future directions especially in-operando techniques, multi-modality approaches for characterization of SEI and artificial intelligence assisted understanding of correlation between electrolyte components and SEI properties are proposed.

Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1764981

Report Number(s):: PNNL-SA-155507

Journal Information:: Advanced Energy Materials, Vol. 11, Issue 5

Country of Publication:: United States

Language:: English

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