Challenges and Opportunities in Utilizing MXenes of Carbides and Nitrides as Electrocatalysts

Wang, Yan; Nian, Yao; Biswas, Akash N.; Li, Wei; Han, You; Chen, Jingguang G.

doi:10.1002/aenm.202002967

Title: Challenges and Opportunities in Utilizing MXenes of Carbides and Nitrides as Electrocatalysts

Journal Article · Sun Dec 13 00:00:00 EST 2020 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.202002967· OSTI ID:1804530

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Chemistry Department Brookhaven National Laboratory Upton NY 11973 USA, School of Chemical Engineering and Technology Tianjin University Tianjin 300072 P. R. China
Department of Chemical Engineering Columbia University New York NY 10027 USA
School of Chemical Engineering and Technology Tianjin University Tianjin 300072 P. R. China
Chemistry Department Brookhaven National Laboratory Upton NY 11973 USA, Department of Chemical Engineering Columbia University New York NY 10027 USA

Abstract Sustainable energy conversion processes often require electrochemical reactions powered by renewable energy sources. 2D transition metal carbides and nitrides (MXenes), an important and growing class of 2D materials, have been demonstrated to be promising candidates for heterogeneous electrocatalysis due to their unique electronic, physical, chemical, and mechanical properties. Significant efforts have been made in the development of MXenes and MXene‐derived electrocatalysts for various electrochemical reactions, including the hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, carbon dioxide reduction reaction, nitrogen reduction reaction, and methanol oxidation reaction. MXenes from earth‐abundant metals provide the potential for large‐scale applications, and their well‐defined structures allow for the identification of active sites and catalytic mechanisms. Herein, recent studies of MXenes in electrocatalysis are reviewed, and the challenges and opportunities for the design and fabrication of MXenes and MXene‐based materials with desired electrocatalytic properties are discussed.

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Sponsoring Organization:: USDOE

OSTI ID:: 1804530

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Vol. 11 Journal Issue: 3; ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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An MnO ₂ –Ti ₃ C ₂ T _x MXene nanohybrid: an efficient and durable electrocatalyst toward artificial N ₂ fixation to NH ₃ under ambient conditions Kong, Wenhan; Gong, Feng (Frank); Zhou, Qiang Journal of Materials Chemistry A, Vol. 7, Issue 32 https://doi.org/10.1039/C9TA04902A	journal	January 2019
Oxygen‐Functionalized Ultrathin Ti ₃ C ₂ T _x MXene for Enhanced Electrocatalytic Hydrogen Evolution Jiang, Yanan; Sun, Tao; Xie, Xi ChemSusChem, Vol. 12, Issue 7 https://doi.org/10.1002/cssc.201803032	journal	April 2019

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