Dual functionality of over-lithiated NMC for high energy silicon-based lithium-ion batteries

Dose, Wesley M.; Kim, Soojeong; Liu, Qian; Trask, Stephen E.; Dunlop, Alison R.; Ren, Yang; Zhang, Zhengcheng; Fister, Timothy T.; Johnson, Christopher S.

doi:10.1039/d1ta01290h

Dual functionality of over-lithiated NMC for high energy silicon-based lithium-ion batteries

Journal Article · Fri May 21 00:00:00 EDT 2021 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/d1ta01290h· OSTI ID:1798133

^[1]; Kim, Soojeong ^[2]; Liu, Qian ^[2]; ^[2]; Dunlop, Alison R. ^[2]; Ren, Yang ^[2]; ^[2]; ^[2]; ^[2]

Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Cambridge (United Kingdom)
Argonne National Lab. (ANL), Argonne, IL (United States)

Owing to their high specific capacity and suitably low operating potential, silicon-based anodes are an attractive alternative to graphite in next-generation lithium-ion batteries. However, silicon anodes suffer from low initial coulombic efficiency and fast capacity decay, limiting their widespread application. Pre-lithiation strategies are highly appealing to compensate for irreversible active lithium loss and to boost the cell energy density. In this work, we maximize the cell energy density by direct pre-lithiation of the NMC (LiNi_0.5Mn_0.3Co_0.2O₂) cathode to Li_1+xNMCO₂ without introducing inactive deadweight to either electrode. First, we demonstrate that Li_1+xNMCO₂ can be synthesized chemically, via reaction between NMC and lithium napthalide, and electrochemically. The NMC cathode is tolerant of a one-time over-lithiation up to 60 mA h g_NMC^-1, giving capacity retention on par with untreated NMC in half cell electrochemical cycling. Using synchrotron X-ray absorption spectroscopy (ex situ) and diffraction (in situ), we demonstrate that higher amounts of over-lithiation lead to local structure distortion – driven by transition metal reduction to Jahn–Teller active Mn³⁺ and Co²⁺ – as well as bulk structural hysteresis during over-lithiation and layer “buckling” that increases the amount of lithium extracted from the structure in the charged state. The Li_1+xNMCO₂ with low-to-moderate over-lithiation capacity (23, 46, and 70 mA h g_NMC^-1) is proven to be a highly effective dual-purpose lithium source and cathode material in full cell tests with a commercially relevant Si–graphite anode. These cells show higher capacity, superior cycle life, and improved coulombic efficiencies when compared to those with stoichiometric NMC cathodes. Finally, this study introduces a new and simple method to pre-lithiate layered transition metal oxide cathodes, opening up new possibilities for the development of high energy density lithium-ion batteries with next-generation anodes.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1798133

Alternate ID(s):: OSTI ID: 1784357

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 21 Vol. 9; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (77)

Understanding the Degradation Mechanisms of LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Material in Lithium Ion Batteries Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun Advanced Energy Materials, Vol. 4, Issue 1 https://doi.org/10.1002/aenm.201300787	journal	August 2013
Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review Su, Xin; Wu, Qingliu; Li, Juchuan Advanced Energy Materials, Vol. 4, Issue 1 https://doi.org/10.1002/aenm.201300882	journal	October 2013
Li ₃ N as a Cathode Additive for High-Energy-Density Lithium-Ion Batteries Park, Kyusung; Yu, Byeong-Chul; Goodenough, John B. Advanced Energy Materials, Vol. 6, Issue 10 https://doi.org/10.1002/aenm.201502534	journal	March 2016
Lithium Sulfide/Metal Nanocomposite as a High-Capacity Cathode Prelithiation Material Sun, Yongming; Lee, Hyun-Wook; Seh, Zhi Wei Advanced Energy Materials, Vol. 6, Issue 12 https://doi.org/10.1002/aenm.201600154	journal	May 2016
Best Practices for Mitigating Irreversible Capacity Loss of Negative Electrodes in Li-Ion Batteries Aravindan, Vanchiappan; Lee, Yun-Sung; Madhavi, Srinivasan Advanced Energy Materials, Vol. 7, Issue 17 https://doi.org/10.1002/aenm.201602607	journal	April 2017
Li-Metal-Free Prelithiation of Si-Based Negative Electrodes for Full Li-Ion Batteries Zhou, Haitao; Wang, Xuehang; Chen, De ChemSusChem, Vol. 8, Issue 16 https://doi.org/10.1002/cssc.201500287	journal	July 2015
A High-Voltage and High-Capacity Li _{1+ x} Ni _0.5 Mn _1.5 O ₄ Cathode Material: From Synthesis to Full Lithium-Ion Cells Mancini, Marilena; Axmann, Peter; Gabrielli, Giulio ChemSusChem, Vol. 9, Issue 14 https://doi.org/10.1002/cssc.201600365	journal	June 2016
Short Range and Long Range Magnetic Order in 1T-Li2NiO2 Davidson, I. J.; Greedan, J. E.; Von Sacken, U. Journal of Solid State Chemistry, Vol. 105, Issue 2 https://doi.org/10.1006/jssc.1993.1233	journal	August 1993
Investigating the first-cycle irreversibility of lithium metal oxide cathodes for Li batteries Kang, Sun-Ho; Yoon, Won-Sub; Nam, Kyung-Wan Journal of Materials Science, Vol. 43, Issue 14 https://doi.org/10.1007/s10853-007-2355-6	journal	July 2008
Structure refinement of the spinel-related phases Li2Mn2O4 and Li0.2Mn2O4 David, W. I. F.; Thackeray, M. M.; De Picciotto, L. A. Journal of Solid State Chemistry, Vol. 67, Issue 2 https://doi.org/10.1016/0022-4596(87)90369-0	journal	April 1987
Structure and electrochemistry of Li1±yNiO2 and a new Li2NiO2 phase with the Ni (OH)2 structure Dahn, J. Solid State Ionics, Vol. 44, Issue 1-2 https://doi.org/10.1016/0167-2738(90)90049-W	journal	December 1990
Will advanced lithium-alloy anodes have a chance in lithium-ion batteries? Besenhard, J. O.; Yang, J.; Winter, M. Journal of Power Sources, Vol. 68, Issue 1 https://doi.org/10.1016/S0378-7753(96)02547-5	journal	September 1997
The role of Li2MO2 structures (M=metal ion) in the electrochemistry of (x)LiMn0.5Ni0.5O2·(1−x)Li2TiO3 electrodes for lithium-ion batteries Johnson, Christopher S.; Kim, Jeom-Soo; Jeremy Kropf, A. Electrochemistry Communications, Vol. 4, Issue 6 https://doi.org/10.1016/S1388-2481(02)00346-6	journal	June 2002
First-cycle irreversibility of layered Li–Ni–Co–Mn oxide cathode in Li-ion batteries Kang, Sun-Ho; Abraham, Daniel P.; Yoon, Won-Sub Electrochimica Acta, Vol. 54, Issue 2 https://doi.org/10.1016/j.electacta.2008.07.007	journal	December 2008
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries Verma, Pallavi; Maire, Pascal; Novák, Petr Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341 https://doi.org/10.1016/j.electacta.2010.05.072	journal	September 2010
The influence of different conducting salts on the metal dissolution and capacity fading of NCM cathode material Gallus, Dennis Roman; Schmitz, René; Wagner, Ralf Electrochimica Acta, Vol. 134 https://doi.org/10.1016/j.electacta.2014.04.091	journal	July 2014
Electrochemical behaviors of LiCo1/3Ni1/3Mn1/3O2 in lithium batteries at elevated temperatures Yabuuchi, Naoaki; Ohzuku, Tsutomu Journal of Power Sources, Vol. 146, Issue 1-2 https://doi.org/10.1016/j.jpowsour.2005.03.080	journal	August 2005
A prelithiated carbon anode for lithium-ion battery applications Jarvis, C. R.; Lain, M. J.; Yakovleva, M. V. Journal of Power Sources, Vol. 162, Issue 2, p. 800-802 https://doi.org/10.1016/j.jpowsour.2005.07.051	journal	November 2006
Correlation between dissolution behavior and electrochemical cycling performance for LiNi1/3Co1/3Mn1/3O2-based cells Zheng, Honghe; Sun, Qingna; Liu, Gao Journal of Power Sources, Vol. 207 https://doi.org/10.1016/j.jpowsour.2012.01.122	journal	June 2012
Application of Stabilized Lithium Metal Powder (SLMP^®) in graphite anode – A high efficient prelithiation method for lithium-ion batteries Wang, Zhihui; Fu, Yanbao; Zhang, Zhengcheng Journal of Power Sources, Vol. 260, p. 57-61 https://doi.org/10.1016/j.jpowsour.2014.02.112	journal	August 2014
Effect of LiPF6 concentration in Li[Ni0.4Mn0.4Co0.2]O2/graphite pouch cells operated at 4.5 V Petibon, R.; Madec, L.; Abarbanel, D. W. Journal of Power Sources, Vol. 300 https://doi.org/10.1016/j.jpowsour.2015.09.090	journal	December 2015
A new strategy to mitigate the initial capacity loss of lithium ion batteries Su, Xin; Lin, Chikai; Wang, Xiaoping Journal of Power Sources, Vol. 324 https://doi.org/10.1016/j.jpowsour.2016.05.063	journal	August 2016
A new approach for compensating the irreversible capacity loss of high-energy Si/C\|LiNi 0.5 Mn 1.5 O 4 lithium-ion batteries Gabrielli, Giulio; Marinaro, Mario; Mancini, Marilena Journal of Power Sources, Vol. 351 https://doi.org/10.1016/j.jpowsour.2017.03.051	journal	May 2017
Singlet oxygen evolution from layered transition metal oxide cathode materials and its implications for lithium-ion batteries Wandt, Johannes; Freiberg, Anna T. S.; Ogrodnik, Alexander Materials Today, Vol. 21, Issue 8 https://doi.org/10.1016/j.mattod.2018.03.037	journal	October 2018
Enabling high energy density Li-ion batteries through Li2O activation Abouimrane, Ali; Cui, Yanjie; Chen, Zonghai Nano Energy, Vol. 27 https://doi.org/10.1016/j.nanoen.2016.06.050	journal	September 2016
Evolution of the Electrode–Electrolyte Interface of LiNi _0.8 Co _0.15 Al _0.05 O ₂ Electrodes Due to Electrochemical and Thermal Stress Lebens-Higgins, Zachary W.; Sallis, Shawn; Faenza, Nicholas V. Chemistry of Materials, Vol. 30, Issue 3 https://doi.org/10.1021/acs.chemmater.7b04782	journal	January 2018
Switch of the Charge Storage Mechanism of Li _x Ni _0.80 Co _0.15 Al _0.05 O ₂ at Overdischarge Conditions Robert, Rosa; Novák, Petr Chemistry of Materials, Vol. 30, Issue 6 https://doi.org/10.1021/acs.chemmater.7b04784	journal	March 2018
Evolution of Structure and Lithium Dynamics in LiNi _0.8 Mn _0.1 Co _0.1 O ₂ (NMC811) Cathodes during Electrochemical Cycling Märker, Katharina; Reeves, Philip J.; Xu, Chao Chemistry of Materials, Vol. 31, Issue 7 https://doi.org/10.1021/acs.chemmater.9b00140	journal	March 2019
Charge-Transfer-Induced Lattice Collapse in Ni-Rich NCM Cathode Materials during Delithiation Kondrakov, Aleksandr O.; Geßwein, Holger; Galdina, Kristina The Journal of Physical Chemistry C, Vol. 121, Issue 44 https://doi.org/10.1021/acs.jpcc.7b06598	journal	October 2017
Chemical versus Electrochemical Electrolyte Oxidation on NMC111, NMC622, NMC811, LNMO, and Conductive Carbon Jung, Roland; Metzger, Michael; Maglia, Filippo The Journal of Physical Chemistry Letters, Vol. 8, Issue 19 https://doi.org/10.1021/acs.jpclett.7b01927	journal	September 2017
Electrolyte-Induced Surface Transformation and Transition-Metal Dissolution of Fully Delithiated LiNi _0.8 Co _0.15 Al _0.05 O ₂ Faenza, Nicholas V.; Lebens-Higgins, Zachary W.; Mukherjee, Pinaki Langmuir, Vol. 33, Issue 37 https://doi.org/10.1021/acs.langmuir.7b00863	journal	June 2017
Controlled Prelithiation of Silicon Monoxide for High Performance Lithium-Ion Rechargeable Full Cells Kim, Hye Jin; Choi, Sunghun; Lee, Seung Jong Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b03776	journal	December 2015
In Situ Chemical Synthesis of Lithium Fluoride/Metal Nanocomposite for High Capacity Prelithiation of Cathodes Sun, Yongming; Lee, Hyun-Wook; Zheng, Guangyuan Nano Letters, Vol. 16, Issue 2 https://doi.org/10.1021/acs.nanolett.5b05228	journal	January 2016
Ambient-Air Stable Lithiated Anode for Rechargeable Li-Ion Batteries with High Energy Density Cao, Zeyuan; Xu, Pengyu; Zhai, Haowei Nano Letters, Vol. 16, Issue 11 https://doi.org/10.1021/acs.nanolett.6b03655	journal	October 2016
Intergranular Cracking as a Major Cause of Long-Term Capacity Fading of Layered Cathodes Liu, Hao; Wolf, Mark; Karki, Khim Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b00379	journal	May 2017
Liquid Ammonia Chemical Lithiation: An Approach for High-Energy and High-Voltage Si–Graphite\|Li _{1+ x} Ni _0.5 Mn _1.5 O ₄ Li-Ion Batteries Dose, Wesley M.; Blauwkamp, James; Piernas-Muñoz, María José ACS Applied Energy Materials, Vol. 2, Issue 7 https://doi.org/10.1021/acsaem.9b00695	journal	June 2019
Structural Characterization of Layered Li _x Ni _0.5 Mn _0.5 O ₂ (0 < x ≤ 2) Oxide Electrodes for Li Batteries Johnson, Christopher S.; Kim, Jeom-Soo; Kropf, A. Jeremy Chemistry of Materials, Vol. 15, Issue 12 https://doi.org/10.1021/cm0204728	journal	June 2003
X-ray/Neutron Diffraction and Electrochemical Studies of Lithium De/Re-Intercalation in Li ₁ _- _x Co _1/ ₃ Ni _1/3 Mn _1/3 O ₂ ( x = 0 → 1) Yin, S. -C.; Rho, Y. -H.; Swainson, I. Chemistry of Materials, Vol. 18, Issue 7 https://doi.org/10.1021/cm0511769	journal	April 2006
In Situ Mitigation of First-Cycle Anode Irreversibility in a New Spinel/FeSb Lithium-Ion Cell Enabled via a Microwave-Assisted Chemical Lithiation Process Moorhead-Rosenberg, Zachary; Allcorn, Eric; Manthiram, Arumugam Chemistry of Materials, Vol. 26, Issue 20 https://doi.org/10.1021/cm5024426	journal	October 2014
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Alloy Negative Electrodes for Li-Ion Batteries Obrovac, M. N.; Chevrier, V. L. Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500207g	journal	October 2014
⁶ Li and ⁷ Li MAS NMR Studies of Lithium Manganate Cathode Materials Lee, Young Joo; Wang, Francis; Grey, Clare P. Journal of the American Chemical Society, Vol. 120, Issue 48 https://doi.org/10.1021/ja9817794	journal	December 1998
Solid Electrolyte Interphase Growth and Capacity Loss in Silicon Electrodes Michan, Alison L.; Divitini, Giorgio; Pell, Andrew J. Journal of the American Chemical Society, Vol. 138, Issue 25 https://doi.org/10.1021/jacs.6b02882	journal	June 2016
Intrinsic Kinetic Limitations in Substituted Lithium-Layered Transition-Metal Oxide Electrodes Grenier, Antonin; Reeves, Philip J.; Liu, Hao Journal of the American Chemical Society, Vol. 142, Issue 15 https://doi.org/10.1021/jacs.9b13551	journal	March 2020
Prelithiation of Silicon–Carbon Nanotube Anodes for Lithium Ion Batteries by Stabilized Lithium Metal Powder (SLMP) Forney, Michael W.; Ganter, Matthew J.; Staub, Jason W. Nano Letters, Vol. 13, Issue 9, p. 4158-4163 https://doi.org/10.1021/nl401776d	journal	August 2013
Prelithiated Silicon Nanowires as an Anode for Lithium Ion Batteries Liu, Nian; Hu, Liangbing; McDowell, Matthew T. ACS Nano, Vol. 5, Issue 8 https://doi.org/10.1021/nn2017167	journal	July 2011
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries Lin, Feng; Markus, Isaac M.; Nordlund, Dennis Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4529	journal	March 2014
Failure mechanisms of nano-silicon anodes upon cycling: an electrode porosity evolution model Radvanyi, Etienne; Porcher, Willy; De Vito, Eric Phys. Chem. Chem. Phys., Vol. 16, Issue 32 https://doi.org/10.1039/C4CP02324B	journal	January 2014
Abuse tolerance behavior of layered oxide-based Li-ion battery during overcharge and over-discharge Qian, Kun; Li, Yiyang; He, Yan-Bing RSC Advances, Vol. 6, Issue 80 https://doi.org/10.1039/C6RA11288A	journal	January 2016
Lithium rhenium( vii ) oxide as a novel material for graphite pre-lithiation in high performance lithium-ion capacitors Jeżowski, P.; Fic, K.; Crosnier, O. Journal of Materials Chemistry A, Vol. 4, Issue 32 https://doi.org/10.1039/C6TA03810G	journal	January 2016
Transition metal dissolution and deposition in Li-ion batteries investigated by operando X-ray absorption spectroscopy Wandt, Johannes; Freiberg, Anna; Thomas, Rowena Journal of Materials Chemistry A, Vol. 4, Issue 47 https://doi.org/10.1039/C6TA08865A	journal	January 2016
Li ₂ O ₂ as a cathode additive for the initial anode irreversibility compensation in lithium-ion batteries Bie, Yitian; Yang, Jun; Wang, Jiulin Chemical Communications, Vol. 53, Issue 59 https://doi.org/10.1039/C7CC04646D	journal	January 2017
Running out of lithium? A route to differentiate between capacity losses and active lithium losses in lithium-ion batteries Holtstiege, Florian; Wilken, Andrea; Winter, Martin Physical Chemistry Chemical Physics, Vol. 19, Issue 38 https://doi.org/10.1039/C7CP05405J	journal	January 2017
The failure mechanism of nano-sized Si-based negative electrodes for lithium ion batteries Oumellal, Y.; Delpuech, N.; Mazouzi, D. Journal of Materials Chemistry, Vol. 21, Issue 17 https://doi.org/10.1039/c1jm10213c	journal	January 2011
Mechanism of capacity fade of MCMB/Li1.1[Ni1/3Mn1/3Co1/3]0.9O2 cell at elevated temperature and additives to improve its cycle life Amine, Khalil; Chen, Zonghai; Zhang, Z. Journal of Materials Chemistry, Vol. 21, Issue 44 https://doi.org/10.1039/c1jm11584g	journal	January 2011
Factors that affect Li mobility in layered lithium transition metal oxides Kang, Kisuk; Ceder, Gerbrand Physical Review B, Vol. 74, Issue 9 https://doi.org/10.1103/PhysRevB.74.094105	journal	September 2006
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries Kang, Kisuk; Shirley Meng, Ying; Breger, Julien Science, Vol. 311, Issue 5763, p. 977-980 https://doi.org/10.1126/science.1122152	journal	February 2006
Colossal Reversible Volume Changes in Lithium Alloys Beaulieu, L. Y.; Eberman, K. W.; Turner, R. L. Electrochemical and Solid-State Letters, Vol. 4, Issue 9 https://doi.org/10.1149/1.1388178	journal	January 2001
Microscopy and Spectroscopy of Lithium Nickel Oxide-Based Particles Used in High Power Lithium-Ion Cells Abraham, D. P.; Twesten, R. D.; Balasubramanian, M. Journal of The Electrochemical Society, Vol. 150, Issue 11 https://doi.org/10.1149/1.1613291	journal	January 2003
CoO₂, The End Member of the Li_xCoO₂ Solid Solution Amatucci, G. G.; Tarascon, J. M.; Klein, L. C. Journal of The Electrochemical Society, Vol. 143, Issue 3, p. 1114-1123 https://doi.org/10.1149/1.1836594	journal	January 1996
Lithium Intercalation from Aqueous Solutions Li, W. Journal of The Electrochemical Society, Vol. 141, Issue 9 https://doi.org/10.1149/1.2055118	journal	January 1994
Li Metal-Free Rechargeable Batteries Based on Li[sub 1+x]Mn[sub 2]O[sub 4] Cathodes (0 ≤ x ≤ 1) and Carbon Anodes Tarascon, J. M. Journal of The Electrochemical Society, Vol. 138, Issue 10 https://doi.org/10.1149/1.2085331	journal	January 1991
Reversible Cycling of Crystalline Silicon Powder Obrovac, M. N.; Krause, L. J. Journal of The Electrochemical Society, Vol. 154, Issue 2 https://doi.org/10.1149/1.2402112	journal	January 2007
Electrochemical Modeling of Lithium-Ion Positive Electrodes during Hybrid Pulse Power Characterization Tests Dees, Dennis; Gunen, Evren; Abraham, Daniel Journal of The Electrochemical Society, Vol. 155, Issue 8 https://doi.org/10.1149/1.2939211	journal	January 2008
Beneficial Effect of Li ₅ FeO ₄ Lithium Source for Li-Ion Batteries with a Layered NMC Cathode and Si Anode Dose, Wesley M.; Villa, Cesar; Hu, Xiaobing Journal of The Electrochemical Society, Vol. 167, Issue 16 https://doi.org/10.1149/1945-7111/abd1ef	journal	December 2020
Oxygen Release and Its Effect on the Cycling Stability of LiNi _x Mn _y Co _z O ₂ (NMC) Cathode Materials for Li-Ion Batteries Jung, Roland; Metzger, Michael; Maglia, Filippo Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.0021707jes	journal	January 2017
Electrochemical Performance and Phase Transitions between 1.5 and 4.9 V of Highly-Ordered LiNi _0.5 Mn _1.5 O ₄ with Tailored Morphology: Influence of the Lithiation Method Mancini, M.; Gabrielli, G.; Axmann, P. Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0291701jes	journal	December 2016
Review—Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes: I. Nickel-Rich, LiNi Schipper, Florian; Erickson, Evan M.; Erk, Christoph Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0351701jes	journal	December 2016
Learning from Overpotentials in Lithium Ion Batteries: A Case Study on the LiNi _1/3 Co _1/3 Mn _1/3 O ₂ (NCM) Cathode Kasnatscheew, Johannes; Rodehorst, Uta; Streipert, Benjamin Journal of The Electrochemical Society, Vol. 163, Issue 14 https://doi.org/10.1149/2.0461614jes	journal	January 2016
Lithium Oxalate as Capacity and Cycle-Life Enhancer in LNMO/Graphite and LNMO/SiG Full Cells Solchenbach, Sophie; Wetjen, Morten; Pritzl, Daniel Journal of The Electrochemical Society, Vol. 165, Issue 3 https://doi.org/10.1149/2.0611803jes	journal	January 2018
Effects of Upper Cutoff Potential on LaPO ₄ -Coated and Uncoated Li[Ni _0.42 Mn _0.42 Co _0.16 ]O ₂ /Graphite Pouch Cells Nelson, K. J.; Abarbanel, D. W.; Xia, Jian Journal of The Electrochemical Society, Vol. 163, Issue 2 https://doi.org/10.1149/2.0691602jes	journal	November 2015
Aging Analysis of Graphite/LiNi _1/3 Mn _1/3 Co _1/3 O ₂ Cells Using XRD, PGAA, and AC Impedance Buchberger, Irmgard; Seidlmayer, Stefan; Pokharel, Aneil Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0721514jes	journal	January 2015
Microstructural Observation of LiNi _0.8 Co _0.15 Al _0.05 O ₂ after Charge and Discharge by Scanning Transmission Electron Microscopy Makimura, Yoshinari; Zheng, Shijian; Ikuhara, Yuichi Journal of The Electrochemical Society, Vol. 159, Issue 7 https://doi.org/10.1149/2.073207jes	journal	January 2012
Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells Gilbert, James A.; Shkrob, Ilya A.; Abraham, Daniel P. Journal of The Electrochemical Society, Vol. 164, Issue 2 https://doi.org/10.1149/2.1111702jes	journal	December 2016
Assessment of Li-Inventory in Cycled Si-Graphite Anodes Using LiFePO ₄ as a Diagnostic Cathode Dose, Wesley M.; Maroni, Victor A.; Piernas-Muñoz, Maria Jose Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.1271810jes	journal	January 2018

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