Chemically crosslinked isoreticular metal–organic frameworks

Allen, Corinne A.; Boissonnault, Jake A.; Cirera, Jordi; Gulland, Ryan; Paesani, Francesco; Cohen, Seth M.

doi:10.1039/c3cc40635k

Chemically crosslinked isoreticular metal–organic frameworks

Journal Article · Tue Mar 05 23:00:00 EST 2013 · ChemComm

DOI:https://doi.org/10.1039/c3cc40635k· OSTI ID:1787642

Allen, Corinne A. ^[1]; Boissonnault, Jake A. ^[2]; Cirera, Jordi ^[2]; Gulland, Ryan ^[2]; Paesani, Francesco ^[2]; Cohen, Seth M. ^[2]

Univ. of California, San Diego, La Jolla, CA (United States); U.C. San Diego
Univ. of California, San Diego, La Jolla, CA (United States)

Herein we report the synthesis of canonical isoreticular metal–organic frameworks (IRMOFs) containing interligand crosslinks. Here, chemically crosslinking two molecules of 2-amino-1,4-benzene dicarboxylic acid (NH₂-BDC) gives ligands that readily form IRMOF-1 analogs, producing crosslinked MOFs that may be designed to have novel properties.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, La Jolla, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1787642

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 31 Vol. 49; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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polyMOFs: A Class of Interconvertible Polymer-Metal-Organic-Framework Hybrid Materials Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A. Angewandte Chemie, Vol. 127, Issue 21 https://doi.org/10.1002/ange.201502733	journal	April 2015
polyMOFs: A Class of Interconvertible Polymer-Metal-Organic-Framework Hybrid Materials Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A. Angewandte Chemie International Edition, Vol. 54, Issue 21 https://doi.org/10.1002/anie.201502733	journal	April 2015
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Acid-functionalized UiO-66(Zr) MOFs and their evolution after intra-framework cross-linking: structural features and sorption properties Ragon, Florence; Campo, Betiana; Yang, Qingyuan Journal of Materials Chemistry A, Vol. 3, Issue 7 https://doi.org/10.1039/c4ta03992k	journal	January 2015
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Hybridization of MOFs and polymers Kitao, Takashi; Zhang, Yuanyuan; Kitagawa, Susumu Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/c7cs00041c	journal	January 2017
Block co-polyMOFs: assembly of polymer–polyMOF hybrids via iterative exponential growth and “click” chemistry MacLeod, M. J.; Johnson, J. A. Polymer Chemistry, Vol. 8, Issue 31 https://doi.org/10.1039/c7py00922d	journal	January 2017
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials Kirchon, Angelo; Feng, Liang; Drake, Hannah F. Chemical Society Reviews, Vol. 47, Issue 23 https://doi.org/10.1039/c8cs00688a	journal	January 2018
A collection of forcefield precursors for metal–organic frameworks Chen, Taoyi; Manz, Thomas A. RSC Advances, Vol. 9, Issue 63 https://doi.org/10.1039/c9ra07327b	journal	January 2019
Three-dimensional metal-organic framework based on pentanuclear manganese clusters as building blocks Li, Xin-Xiong; Wei, Kun-Yu; Zhuang, Ting-Ting Journal of Coordination Chemistry, Vol. 69, Issue 11-13 https://doi.org/10.1080/00958972.2016.1193167	journal	June 2016

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Chemically crosslinked isoreticular metal–organic frameworks

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