Exploration of Chemically Cross-Linked Metal–Organic Frameworks

Allen, C. A.; Cohen, S. M.

doi:10.1021/ic500951b

Exploration of Chemically Cross-Linked Metal–Organic Frameworks

Journal Article · Thu Jun 19 00:00:00 EDT 2014 · Inorganic Chemistry

DOI:https://doi.org/10.1021/ic500951b· OSTI ID:1787325

Allen, C. A. ^[1]; Cohen, S. M. ^[2]

Univ. of California, San Diego, La Jolla, CA (United States); U.C. San Diego
Univ. of California, San Diego, La Jolla, CA (United States)

A series of geometrically constrained, cross-linked benzene dicarboxylic acid (bdc) derivatives have been synthesized and incorporated into the canonical isoreticular metal–organic framework (IRMOF) lattice. Only certain cross-links, which allow for the proper relative orientation of the bdc subunits, form the desired IRMOF. Design criteria from these cross-linked ligands allowed for the rational design of two oligomeric ligands composed of three bdc monomers tethered together. Furthermore, these oligomeric ligands were also readily incorporated into an IRMOF lattice with a high degree of crystallinity and porosity, providing a new dimension to rational ligand design for metal–organic frameworks.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, La Jolla, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1787325

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 13 Vol. 53; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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