Synthesis, breathing, and gas sorption study of the first isoreticular mixed-linker phosphonate based metal–organic frameworks

Taddei, Marco; Costantino, Ferdinando; Ienco, Andrea; Comotti, Angiolina; Dau, Phuong V.; Cohen, Seth M.

doi:10.1039/c2cc38092g

Synthesis, breathing, and gas sorption study of the first isoreticular mixed-linker phosphonate based metal–organic frameworks

Journal Article · Thu Dec 20 23:00:00 EST 2012 · ChemComm

DOI:https://doi.org/10.1039/c2cc38092g· OSTI ID:1787640

Taddei, Marco ^[1]; Costantino, Ferdinando ^[2]; Ienco, Andrea ^[3]; Comotti, Angiolina ^[4]; Dau, Phuong V. ^[5]; Cohen, Seth M. ^[5]

Univ. of Perugia (Italy); U.C. San Diego
Univ. of Perugia (Italy); CNR – ICCOM, Sesto Fiorentino (Italy)
CNR – ICCOM, Sesto Fiorentino (Italy)
Univ. of Milano Bicocca (Italy)
Univ. of California, San Diego, La Jolla, CA (United States)

Here, the synthesis of the first water stable isoreticular phosphonate based mixed-linker metal–organic frameworks (MOFs) is achieved via the use of the N-donor heterocyclic co-ligands. Furthermore, these isoreticular phosphonate frameworks show selective CO₂/N₂ uptake at low pressures.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, La Jolla, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1787640

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 13 Vol. 49; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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