Calcium–Based Metal–Organic Frameworks and Their Potential Applications

Xian, Shikai; Lin, Yuhan; Wang, Hao; Li, Jing

doi:10.1002/smll.202005165

Calcium–Based Metal–Organic Frameworks and Their Potential Applications

Journal Article · Tue Nov 03 00:00:00 EST 2020 · Small

DOI:https://doi.org/10.1002/smll.202005165· OSTI ID:1787570

Xian, Shikai ^[1]; Lin, Yuhan ^[2]; Wang, Hao ^[2]; ^[3]

Shenzhen Polytechnic, Guangdong (China); Rutgers Univ., Piscataway, NJ (United States); Rutgers University
Shenzhen Polytechnic, Guangdong (China)
Shenzhen Polytechnic, Guangdong (China); Rutgers Univ., Piscataway, NJ (United States)

Metal–organic frameworks (MOFs) built on calcium metal (Ca-MOFs) represent a unique subclass of MOFs featuring high stability, low toxicity, and relatively low density. Ca-MOFs show considerable potential for molecular separations, electronic, magnetic, and biomedical applications, although they are not investigated as extensively as transition metal-based MOFs. Compared to MOFs made of other groups of metals, Ca-MOFs may be particularly advantageous for certain applications such as adsorption and storage of light molecules because of their gravimetric benefit, and drug delivery due to their high biocompatibility. This review intends to provide an overview on the recent development of Ca-MOFs, including their synthesis, crystal structures, important properties, and related applications. Here, various synthetic methods and techniques, types of building blocks, structure and porosity features, selected physical properties, and potential uses will be discussed and summarized. Representative examples will be illustrated for each type of important applications with a focus on their structure–property relations.

View Accepted Manuscript (DOE)

Research Organization:: Rutgers Univ., Piscataway, NJ (United States)

Sponsoring Organization:: National Natural Science Foundation of China; Natural Science Foundation of Guangdong Province; USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: SC0019902

OSTI ID:: 1787570

Alternate ID(s):: OSTI ID: 1785580

Journal Information:: Small, Journal Name: Small Journal Issue: 22 Vol. 17; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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