Fluorescent Detection of Carbon Disulfide by a Highly Emissive and Robust Isoreticular Series of Zr-Based Luminescent Metal Organic Frameworks (LMOFs)

Velasco, Ever; Osumi, Yuki; Teat, Simon J.; Jensen, Stephanie; Tan, Kui; Thonhauser, Timo; Li, Jing

doi:10.3390/chemistry3010024

Fluorescent Detection of Carbon Disulfide by a Highly Emissive and Robust Isoreticular Series of Zr-Based Luminescent Metal Organic Frameworks (LMOFs)

Journal Article · Mon Mar 01 00:00:00 EST 2021 · Chemistry

DOI:https://doi.org/10.3390/chemistry3010024· OSTI ID:1787550

Velasco, Ever ^[1]; Osumi, Yuki ^[2]; Teat, Simon J. ^[3]; Jensen, Stephanie ^[4]; Tan, Kui ^[5]; Thonhauser, Timo ^[4]; ^[2]

Rutgers Univ., Piscataway, NJ (United States); Rutgers University
Rutgers Univ., Piscataway, NJ (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Wake Forest Univ., Winston-Salem, NC (United States)
Univ. of Texas at Dallas, Richardson, TX (United States)

Carbon disulfide (CS₂) is a highly volatile neurotoxic species. It is known to cause atherosclerosis and coronary artery disease and contributes significantly to sulfur-based pollutants. Therefore, effective detection and capture of carbon disulfide represents an important aspect of research efforts for the protection of human and environmental health. In this study, we report the synthesis and characterization of two strongly luminescent and robust isoreticular metal organic frameworks (MOFs) Zr₆(µ_3-O)₄(OH)₈(tcbpe)₂(H₂O)₄ (here termed 1) and Zr₆(µ_3-O)₄(OH)₈(tcbpe-f)₂(H₂O)₄ (here termed 2) and their use as fluorescent sensors for the detection of carbon disulfide. Both MOFs demonstrate a calorimetric bathochromic shift in the optical bandgap and strong luminescence quenching upon exposure to carbon disulfide. The interactions between carbon disulfide and the frameworks are analyzed by in-situ infrared spectroscopy and computational modelling by density functional theory. These results reveal that both the Zr metal node and organic ligand act as the preferential binding sites and interact strongly with carbon disulfide.

View Accepted Manuscript (DOE)

Research Organization:: Rutgers Univ., Piscataway, NJ (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-05CH11231; SC0019902

OSTI ID:: 1787550

Journal Information:: Chemistry, Journal Name: Chemistry Journal Issue: 1 Vol. 3; ISSN 2624-8549

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
carbon disulfide
coordination polymers (CP)
luminescent sensing
metal organic frameworks (MOFs)

Fluorescent Detection of Carbon Disulfide by a Highly Emissive and Robust Isoreticular Series of Zr-Based Luminescent Metal Organic Frameworks (LMOFs)

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