Enhancing perovskite electrocatalysis through synergistic functionalization of B-site cation for efficient water splitting

Tang, Lina; Chen, Zhou; Zuo, Fan; Hua, Bin; Zhou, Hua; Li, Meng; Li, Jianhui; Sun, Yifei

doi:10.1016/j.cej.2020.126082

Enhancing perovskite electrocatalysis through synergistic functionalization of B-site cation for efficient water splitting

Journal Article · Tue Jun 30 00:00:00 EDT 2020 · Chemical Engineering Journal

DOI:https://doi.org/10.1016/j.cej.2020.126082· OSTI ID:1788245

Tang, Lina ^[1]; Chen, Zhou ^[2]; Zuo, Fan ^[3]; Hua, Bin ^[4]; Zhou, Hua ^[5]; Li, Meng ^[4]; Li, Jianhui ^[2]; Sun, Yifei ^[5]

Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Changji Univ., Changji (China)
Xiamen Univ., Xiamen (China). National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters
Indiana State Univ., Terre Haute, IN (United States)
Univ. of Alberta, Edmonton, AB (Canada)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

The family of perovskite oxides is a promising class of catalysts for diverse energy conversion processes including water splitting. In this work, a facile two-step manipulation (in-situ exsolution and post-sulfurization) strategy was proposed and applied to LaCo_0.2Fe_0.8O₃ (LCF) perovskite parent, through which, the electronic state, spatial immersion and intrinsic activity of B-site cobalt (Co) were stepwise tuned at nanoscale proximity accordingly (i.e., lattice Co ions segregated Co⁰→ embedded CoS₂). Impressively, the as-prepared catalyst (S-LCF) obtains an emergent oxygen deficient microstructure seamlessly pinned with uniformly distributed CoS₂ nanoparticles (NPs), which demonstrates enhanced performance toward both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), and shows good stability in overall water splitting. The density functional theory (DFT) calculations illustrate the optimized metal-oxygen covalency and hydrogen adsorption Gibbs free energy (Δ G_H*) on S-LCF, which further buttresses the prominence of our B-site cation engineering tactics.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Indiana State University; National Natural Science Foundation of China (NSFC); USDOE; USDOE Office of Science (SC); Xiamen University

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1788245

Alternate ID(s):: OSTI ID: 1779520

Journal Information:: Chemical Engineering Journal, Journal Name: Chemical Engineering Journal Vol. 401; ISSN 1385-8947

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (71)

The Excellence of Both Worlds: Developing Effective Double Perovskite Oxide Catalyst of Oxygen Reduction Reaction for Room and Elevated Temperature Applications Hua, Bin; Zhang, Ya-Qian; Yan, Ning Advanced Functional Materials, Vol. 26, Issue 23 https://doi.org/10.1002/adfm.201600339	journal	April 2016
When Cubic Cobalt Sulfide Meets Layered Molybdenum Disulfide: A Core-Shell System Toward Synergetic Electrocatalytic Water Splitting Zhu, Han; Zhang, Junfeng; Yanzhang, Ruoping Advanced Materials, Vol. 27, Issue 32 https://doi.org/10.1002/adma.201501969	journal	July 2015
An Amorphous Nickel–Iron‐Based Electrocatalyst with Unusual Local Structures for Ultrafast Oxygen Evolution Reaction Chen, Gao; Zhu, Yanping; Chen, Hao Ming Advanced Materials, Vol. 31, Issue 28 https://doi.org/10.1002/adma.201900883	journal	May 2019
In Situ Investigation of Reversible Exsolution/Dissolution of CoFe Alloy Nanoparticles in a Co‐Doped Sr ₂ Fe _1.5 Mo _0.5 O ₆₋ _δ Cathode for CO ₂ Electrolysis Lv, Houfu; Lin, Le; Zhang, Xiaomin Advanced Materials, Vol. 32, Issue 6 https://doi.org/10.1002/adma.201906193	journal	December 2019
All-In-One Perovskite Catalyst: Smart Controls of Architecture and Composition toward Enhanced Oxygen/Hydrogen Evolution Reactions Hua, Bin; Li, Meng; Zhang, Ya-Qian Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201700666	journal	July 2017
Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH) ₂ /Metal Catalysts Danilovic, N.; Subbaraman, Ram; Strmcnik, D. Angewandte Chemie, Vol. 124, Issue 50 https://doi.org/10.1002/ange.201204842	journal	November 2012
SrNb _0.1 Co _0.7 Fe _0.2 O _{3− δ} Perovskite as a Next-Generation Electrocatalyst for Oxygen Evolution in Alkaline Solution Zhu, Yinlong; Zhou, Wei; Chen, Zhi-Gang Angewandte Chemie International Edition, Vol. 54, Issue 13 https://doi.org/10.1002/anie.201408998	journal	February 2015
Oxygen-Containing Amorphous Cobalt Sulfide Porous Nanocubes as High-Activity Electrocatalysts for the Oxygen Evolution Reaction in an Alkaline/Neutral Medium Cai, Pingwei; Huang, Junheng; Chen, Junxiang Angewandte Chemie International Edition, Vol. 56, Issue 17 https://doi.org/10.1002/anie.201701280	journal	March 2017
Oxygen Evolution Reaction on Perovskite Electrocatalysts with Localized Spins and Orbital Rotation Symmetry Sharpe, Ryan; Lim, Tingbin; Jiao, Yunzhe ChemCatChem, Vol. 8, Issue 24 https://doi.org/10.1002/cctc.201600835	journal	November 2016
A Composite Catalyst Based on Perovskites for Overall Water Splitting in Alkaline Conditions Bu, Yunfei; Kim, Seona; Kwon, Ohhun ChemElectroChem, Vol. 6, Issue 5 https://doi.org/10.1002/celc.201801775	journal	January 2019
A Tailored Bifunctional Electrocatalyst: Boosting Oxygen Reduction/Evolution Catalysis via Electron Transfer Between N-Doped Graphene and Perovskite Oxides Bu, Yunfei; Nam, Gyutae; Kim, Seona Small, Vol. 14, Issue 48 https://doi.org/10.1002/smll.201802767	journal	September 2018
Noble-Metal-Free Electrocatalysts for Oxygen Evolution Lyu, Fenglei; Wang, Qingfa; Choi, Sung Mook Small, Vol. 15, Issue 1 https://doi.org/10.1002/smll.201804201	journal	November 2018
Engineering highly active oxygen sites in perovskite oxides for stable and efficient oxygen evolution Xiong, Jie; Zhong, Hong; Li, Jing Applied Catalysis B: Environmental, Vol. 256 https://doi.org/10.1016/j.apcatb.2019.117817	journal	November 2019
An effective method for enhancing oxygen evolution kinetics of LaMO3 (M = Ni, Co, Mn) perovskite catalysts and its application to a rechargeable zinc–air battery Li, Zhishan; Lv, Lin; Ao, Xiang Applied Catalysis B: Environmental, Vol. 262 https://doi.org/10.1016/j.apcatb.2019.118291	journal	March 2020
Perovskites SrxLa1-xMnyCo1-yO3-δ coated on Ti as stable non-noble anode for efficient electrocatalytic oxidation of organic wastewater containing ammonia nitrogen Chen, Lijun; Zhang, Yuqing; Ma, Chengbo Chemical Engineering Journal, Vol. 393 https://doi.org/10.1016/j.cej.2020.124514	journal	August 2020
Decorating CoNi layered double hydroxides nanosheet arrays with fullerene quantum dot anchored on Ni foam for efficient electrocatalytic water splitting and urea electrolysis Feng, Yongqiang; Wang, Xiao; Huang, Jianfeng Chemical Engineering Journal, Vol. 390 https://doi.org/10.1016/j.cej.2020.124525	journal	June 2020
Hollow nanosheet array of phosphorus-anion-decorated cobalt disulfide as an efficient electrocatalyst for overall water splitting Li, Yuanjian; Mao, Zhifei; Wang, Qiang Chemical Engineering Journal, Vol. 390 https://doi.org/10.1016/j.cej.2020.124556	journal	June 2020
Highly efficient CoMoS heterostructure derived from vertically anchored Co5Mo10 polyoxometalate for electrocatalytic overall water splitting Lu, Yukun; Guo, Xinxin; Yang, Lingyu Chemical Engineering Journal, Vol. 394 https://doi.org/10.1016/j.cej.2020.124849	journal	August 2020
Mini-review of perovskite oxides as oxygen electrocatalysts for rechargeable zinc–air batteries Dai, Yawen; Yu, Jie; Cheng, Chun Chemical Engineering Journal, Vol. 397 https://doi.org/10.1016/j.cej.2020.125516	journal	October 2020
Assessment of LnBaCo1.6Ni0.4O5+δ (Ln=Pr, Nd, and Sm) double-perovskites as cathodes for intermediate-temperature solid-oxide fuel cells Che, Xiangli; Shen, Yu; Li, Hang Journal of Power Sources, Vol. 222 https://doi.org/10.1016/j.jpowsour.2012.08.044	journal	January 2013
Calcium-doped lanthanum nickelate layered perovskite and nickel oxide nano-hybrid for highly efficient water oxidation Liu, Ruochen; Liang, Fengli; Zhou, Wei Nano Energy, Vol. 12 https://doi.org/10.1016/j.nanoen.2014.12.025	journal	March 2015
A coupling for success: Controlled growth of Co/CoOx nanoshoots on perovskite mesoporous nanofibres as high-performance trifunctional electrocatalysts in alkaline condition Hua, Bin; Li, Meng; Sun, Yi-Fei Nano Energy, Vol. 32 https://doi.org/10.1016/j.nanoen.2016.12.044	journal	February 2017
Recent progress and perspectives of bifunctional oxygen reduction/evolution catalyst development for regenerative anion exchange membrane fuel cells Zhao, Shuai; Yan, Litao; Luo, Hongmei Nano Energy, Vol. 47 https://doi.org/10.1016/j.nanoen.2018.02.015	journal	May 2018
Engineering phosphorus-doped LaFeO3-δ perovskite oxide as robust bifunctional oxygen electrocatalysts in alkaline solutions Li, Zhishan; Lv, Lin; Wang, Jinsong Nano Energy, Vol. 47 https://doi.org/10.1016/j.nanoen.2018.02.051	journal	May 2018
Bifunctional sulfur-doped cobalt phosphide electrocatalyst outperforms all-noble-metal electrocatalysts in alkaline electrolyzer for overall water splitting Anjum, Mohsin Ali Raza; Okyay, Mahmut Sait; Kim, Minkyung Nano Energy, Vol. 53 https://doi.org/10.1016/j.nanoen.2018.08.064	journal	November 2018
Enhancing Electrocatalytic Activity of Perovskite Oxides by Tuning Cation Deficiency for Oxygen Reduction and Evolution Reactions Zhu, Yinlong; Zhou, Wei; Yu, Jie Chemistry of Materials, Vol. 28, Issue 6 https://doi.org/10.1021/acs.chemmater.5b04457	journal	February 2016
Designing Fe-Based Oxygen Catalysts by Density Functional Theory Calculations Chen, Chi; Ciucci, Francesco Chemistry of Materials, Vol. 28, Issue 19 https://doi.org/10.1021/acs.chemmater.6b02953	journal	September 2016
Tailoring the Co 3d-O 2p Covalency in LaCoO ₃ by Fe Substitution To Promote Oxygen Evolution Reaction Duan, Yan; Sun, Shengnan; Xi, Shibo Chemistry of Materials, Vol. 29, Issue 24 https://doi.org/10.1021/acs.chemmater.7b04534	journal	November 2017
Ni ³⁺ -Induced Hole States Enhance the Oxygen Evolution Reaction Activity of Ni _x Co _{3– x} O ₄ Electrocatalysts Cui, Meiyan; Ding, Xingyu; Huang, Xiaochun Chemistry of Materials, Vol. 31, Issue 18 https://doi.org/10.1021/acs.chemmater.9b02453	journal	August 2019
Switch of the Rate-Determining Step of Water Oxidation by Spin-Selected Electron Transfer in Spinel Oxides Sun, Shengnan; Sun, Yuanmiao; Zhou, Ye Chemistry of Materials, Vol. 31, Issue 19 https://doi.org/10.1021/acs.chemmater.9b02737	journal	September 2019
New Opportunity for in Situ Exsolution of Metallic Nanoparticles on Perovskite Parent Sun, Yi-Fei; Zhang, Ya-Qian; Chen, Jian Nano Letters, Vol. 16, Issue 8 https://doi.org/10.1021/acs.nanolett.6b02757	journal	July 2016
Nanoporous Sulfur-Doped Copper Oxide (Cu ₂ O _x S _{1– x} ) for Overall Water Splitting Zhang, Xiaolin; Cui, Xiaoqiang; Sun, Yuanhui ACS Applied Materials & Interfaces, Vol. 10, Issue 1 https://doi.org/10.1021/acsami.7b16280	journal	December 2017
Revealing the Impact of Electrolyte Composition for Co-Based Water Oxidation Catalysts by the Study of Reaction Kinetics Parameters Duan, Yan; Dubouis, Nicolas; Huang, Jiaqiang ACS Catalysis, Vol. 10, Issue 7 https://doi.org/10.1021/acscatal.0c00490	journal	March 2020
Cobalt Sulfide Nanoparticles Grown on Nitrogen and Sulfur Codoped Graphene Oxide: An Efficient Electrocatalyst for Oxygen Reduction and Evolution Reactions Ganesan, Pandian; Prabu, Moni; Sanetuntikul, Jakkid ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00154	journal	May 2015
Integrated Three-Dimensional Carbon Paper/Carbon Tubes/Cobalt-Sulfide Sheets as an Efficient Electrode for Overall Water Splitting Wang, Jun; Zhong, Hai-xia; Wang, Zhong-li ACS Nano, Vol. 10, Issue 2 https://doi.org/10.1021/acsnano.5b07126	journal	January 2016
A Highly Efficient and Robust Cation Ordered Perovskite Oxide as a Bifunctional Catalyst for Rechargeable Zinc-Air Batteries Bu, Yunfei; Gwon, Ohhun; Nam, Gyutae ACS Nano, Vol. 11, Issue 11 https://doi.org/10.1021/acsnano.7b06595	journal	September 2017
Electrocatalytic Oxygen Evolution Reaction (OER) on Ru, Ir, and Pt Catalysts: A Comparative Study of Nanoparticles and Bulk Materials Reier, Tobias; Oezaslan, Mehtap; Strasser, Peter ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs3003098	journal	July 2012
Electrochemistry at Single-Walled Carbon Nanotubes: The Role of Band Structure and Quantum Capacitance Heller, Iddo; Kong, Jing; Williams, Keith A. Journal of the American Chemical Society, Vol. 128, Issue 22 https://doi.org/10.1021/ja061212k	journal	June 2006
Metal–Organic Framework Derived Hybrid Co ₃ O ₄ -Carbon Porous Nanowire Arrays as Reversible Oxygen Evolution Electrodes Ma, Tian Yi; Dai, Sheng; Jaroniec, Mietek Journal of the American Chemical Society, Vol. 136, Issue 39 https://doi.org/10.1021/ja5082553	journal	September 2014
Ultrathin Cobalt–Manganese Layered Double Hydroxide Is an Efficient Oxygen Evolution Catalyst Song, Fang; Hu, Xile Journal of the American Chemical Society, Vol. 136, Issue 47 https://doi.org/10.1021/ja5096733	journal	November 2014
Operando Spectroscopic Analysis of an Amorphous Cobalt Sulfide Hydrogen Evolution Electrocatalyst Kornienko, Nikolay; Resasco, Joaquin; Becknell, Nigel Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b03545	journal	June 2015
Structural Changes of Cobalt-Based Perovskites upon Water Oxidation Investigated by EXAFS Risch, Marcel; Grimaud, Alexis; May, Kevin J. The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp3126768	journal	April 2013
Estimating Hybridization of Transition Metal and Oxygen States in Perovskites from O K -edge X-ray Absorption Spectroscopy Suntivich, Jin; Hong, Wesley T.; Lee, Yueh-Lin The Journal of Physical Chemistry C, Vol. 118, Issue 4 https://doi.org/10.1021/jp410644j	journal	January 2014
Switching on electrocatalytic activity in solid oxide cells Myung, Jae-ha; Neagu, Dragos; Miller, David N. Nature, Vol. 537, Issue 7621 https://doi.org/10.1038/nature19090	journal	August 2016
In situ growth of nanoparticles through control of non-stoichiometry Neagu, Dragos; Tsekouras, George; Miller, David N. Nature Chemistry, Vol. 5, Issue 11 https://doi.org/10.1038/nchem.1773	journal	October 2013
Separating hydrogen and oxygen evolution in alkaline water electrolysis using nickel hydroxide Chen, Long; Dong, Xiaoli; Wang, Yonggang Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11741	journal	May 2016
Precise tuning in platinum-nickel/nickel sulfide interface nanowires for synergistic hydrogen evolution catalysis Wang, Pengtang; Zhang, Xu; Zhang, Jin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14580	journal	February 2017
A tailored double perovskite nanofiber catalyst enables ultrafast oxygen evolution Zhao, Bote; Zhang, Lei; Zhen, Dongxing Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14586	journal	February 2017
Exsolution trends and co-segregation aspects of self-grown catalyst nanoparticles in perovskites Kwon, Ohhun; Sengodan, Sivaprakash; Kim, Kyeounghak Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15967	journal	June 2017
Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution Grimaud, Alexis; May, Kevin J.; Carlton, Christopher E. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3439	journal	September 2013
Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis Song, Fang; Hu, Xile Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5477	journal	July 2014
Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers Irvine, John T. S.; Neagu, Dragos; Verbraeken, Maarten C. Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.14	journal	January 2016
In situ growth of cobalt sulfide hollow nanospheres embedded in nitrogen and sulfur co-doped graphene nanoholes as a highly active electrocatalyst for oxygen reduction and evolution Qiao, Xiaochang; Jin, Jutao; Fan, Hongbo Journal of Materials Chemistry A, Vol. 5, Issue 24 https://doi.org/10.1039/C7TA00993C	journal	January 2017
Operando X-ray spectroscopic tracking of self-reconstruction for anchored nanoparticles as high-performance electrocatalysts towards oxygen evolution Song, Sanzhao; Zhou, Jing; Su, Xiaozhi Energy & Environmental Science, Vol. 11, Issue 10 https://doi.org/10.1039/C8EE00773J	journal	January 2018
Synergistically enhanced hydrogen evolution electrocatalysis by in situ exsolution of metallic nanoparticles on perovskites Zhu, Yinlong; Dai, Jie; Zhou, Wei Journal of Materials Chemistry A, Vol. 6, Issue 28 https://doi.org/10.1039/C8TA02347F	journal	January 2018
Ultrahigh-performance tungsten-doped perovskites for the oxygen evolution reaction Chen, Gao; Hu, Zhiwei; Zhu, Yanping Journal of Materials Chemistry A, Vol. 6, Issue 21 https://doi.org/10.1039/C8TA02864H	journal	January 2018
Synergistic interaction of perovskite oxides and N-doped graphene in versatile electrocatalyst Bu, Yunfei; Jang, Haeseong; Gwon, Ohhun Journal of Materials Chemistry A, Vol. 7, Issue 5 https://doi.org/10.1039/C8TA09919G	journal	January 2019
In situ exsolved FeNi ₃ nanoparticles on nickel doped Sr ₂ Fe _1.5 Mo _0.5 O _6−δ perovskite for efficient electrochemical CO ₂ reduction reaction Lv, Houfu; Lin, Le; Zhang, Xiaomin Journal of Materials Chemistry A, Vol. 7, Issue 19 https://doi.org/10.1039/C9TA03065D	journal	January 2019
In situ grown cobalt phosphide (CoP) on perovskite nanofibers as an optimized trifunctional electrocatalyst for Zn–air batteries and overall water splitting Zhang, Ya-Qian; Tao, Hong-Biao; Chen, Zhou Journal of Materials Chemistry A, Vol. 7, Issue 46 https://doi.org/10.1039/C9TA08936E	journal	January 2019
Construction of tetrahedral CoO ₄ vacancies for activating the high oxygen evolution activity of Co _3−x O _4−δ porous nanosheet arrays Ye, Shenghua; Zhang, Yu; Xiong, Wei Nanoscale, Vol. 12, Issue 20 https://doi.org/10.1039/D0NR00744G	journal	January 2020
Oxidation states of the transition metal cations in the highly nonstoichiometric perovskite-type oxide Ba0.1Sr0.9Co0.8Fe0.2O3−δ Mueller, David N.; De Souza, Roger A.; Brendt, Jochen Journal of Materials Chemistry, Vol. 19, Issue 14 https://doi.org/10.1039/b819415g	journal	January 2009
Key to control and advance myriad technologies Yates, J. T.; Campbell, C. T. Proceedings of the National Academy of Sciences, Vol. 108, Issue 3 https://doi.org/10.1073/pnas.1006671107	journal	January 2011
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Oxidation energies of transition metal oxides within the GGA + U framework Wang, Lei; Maxisch, Thomas; Ceder, Gerbrand Physical Review B, Vol. 73, Issue 19 https://doi.org/10.1103/PhysRevB.73.195107	journal	May 2006
Ab initio energetics of La B O 3 ( 001 ) ( B = Mn , Fe, Co, and Ni) for solid oxide fuel cell cathodes Lee, Yueh-Lin; Kleis, Jesper; Rossmeisl, Jan Physical Review B, Vol. 80, Issue 22 https://doi.org/10.1103/PhysRevB.80.224101	journal	December 2009
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Two orders of magnitude enhancement in oxygen evolution reactivity on amorphous Ba _0.5 Sr _0.5 Co _0.8 Fe _0.2 O _3−δ nanofilms with tunable oxidation state Chen, Gao; Zhou, Wei; Guan, Daqin Science Advances, Vol. 3, Issue 6 https://doi.org/10.1126/sciadv.1603206	journal	June 2017
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles Suntivich, J.; May, K. J.; Gasteiger, H. A. Science, Vol. 334, Issue 6061 https://doi.org/10.1126/science.1212858	journal	October 2011
A highly active and stable IrO _x /SrIrO ₃ catalyst for the oxygen evolution reaction Seitz, Linsey C.; Dickens, Colin F.; Nishio, Kazunori Science, Vol. 353, Issue 6303 https://doi.org/10.1126/science.aaf5050	journal	September 2016
Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes Sheng, Wenchao; Gasteiger, Hubert A.; Shao-Horn, Yang Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3483106	journal	January 2010

Similar Records

Transition-metal single atoms in nitrogen-doped graphenes as efficient active centers for water splitting: a theoretical study

Journal Article · Tue Jan 08 19:00:00 EST 2019 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1543800

Metal–Organic Framework-Derived CoWP@C Composite Nanowire Electrocatalyst for Efficient Water Splitting

Journal Article · Wed May 16 20:00:00 EDT 2018 · ACS Energy Letters · OSTI ID:1543714

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
B-site cation engineering
Density Functional Theory (DFT)
In-situ exsolution
Perovskite oxides
Water splitting

Enhancing perovskite electrocatalysis through synergistic functionalization of B-site cation for efficient water splitting

Citation Formats

References (71)

Similar Records

Related Subjects