Metal–Organic Framework-Derived CoWP@C Composite Nanowire Electrocatalyst for Efficient Water Splitting

Weng, Baicheng; Grice, Corey R.; Meng, Weiwei; Guan, Lei; Xu, Fenghua; Yu, Yue; Wang, Changlei; Zhao, Dewei; Yan, Yanfa

doi:10.1021/acsenergylett.8b00584

Metal–Organic Framework-Derived CoWP@C Composite Nanowire Electrocatalyst for Efficient Water Splitting

Journal Article · Thu May 17 04:00:00 EDT 2018 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.8b00584· OSTI ID:1543714

Weng, Baicheng ^[1]; Grice, Corey R. ^[1]; ^[1]; Guan, Lei ^[1]; Xu, Fenghua ^[1]; Yu, Yue ^[1]; Wang, Changlei ^[1]; Zhao, Dewei ^[1]; ^[1]

Univ. of Toledo, OH (United States). Wright Center for Photovoltaics Innovation and Commercialization (PVIC)

Practical application of electrochemical water splitting demands durable, efficient, and non-noble metal catalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Herein, we report a new hydrogen evolution nanowire electrocatalyst, consisting of S-doped CoWP nanoparticles embedded in S- and N-doped carbon matrix (S-CoWP@(S,N)-C), which is in situ transformed from Hofmann-type (Co, W)-based metal–organic framework (MOF) nanowires. Because of S and N doping to the carbon matrix and the S doping to CoWP nanoparticles, the obtained S-CoWP@(S,N)-C catalyst reaches a current density of -10 mA cm^–2 at -35 and -67 mV (vs RHE) in acidic and alkaline electrolytes, respectively. Powered by a lead halide perovskite solar cell, an unassisted two-electrode solar water-splitting device using MOF-derived S-CoWP@(S,N)-C HER electrocatalysts and S-CoW@(S,N)-C OER electrocatalysts displays a solar-to-hydrogen conversion efficiency of 10.98%. Our method is highly applicable for developing robust electrocatalysts toward efficient and low-cost solar-driven water splitting.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1543714

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 6 Vol. 3; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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