CO2 chirped-probe-pulse femtosecond CARS thermometry

Gu, Mingming; Satija, Aman; Lucht, Robert P.

doi:10.1016/j.proci.2020.06.134

CO₂ chirped-probe-pulse femtosecond CARS thermometry

Journal Article · Sat Aug 15 00:00:00 EDT 2020 · Proceedings of the Combustion Institute

DOI:https://doi.org/10.1016/j.proci.2020.06.134· OSTI ID:1849427

^[1]; Satija, Aman ^[2]; ^[2]

Purdue University, West Lafayette, IN (United States); OSTI
Purdue University, West Lafayette, IN (United States)

The application of CO₂ chirped-probe-pulse (CPP) fs coherent anti-Stokes Raman scattering (CARS) for flame thermometry is discussed. A phenomenological model for CO₂/O₂ CPP fs CARS was developed, and the simulations showed the potential for CO₂ temperature measurements free of interferences from O₂ and with no contribution from the nonresonant background by using a long-time delay for the chirped probe pulse. The accuracy and precision for CO₂ CPP fs CARS thermometry is compared with N₂ CPP fs CARS thermometry for temperatures between 295 K and 1420 K. The measurement accuracy for the CO₂ measurements is comparable with that for the N₂ measurements, while the precision for the CO₂ temperature measurements is significantly better at lower temperatures. In conclusion, we also demonstrate that accurate flame thermometry using a single set of laser parameters can be achieved using the delayed CPP approach.

View Accepted Manuscript (DOE)

Research Organization:: Purdue University, West Lafayette, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: FG02-03ER15391

OSTI ID:: 1849427

Journal Information:: Proceedings of the Combustion Institute, Journal Name: Proceedings of the Combustion Institute Journal Issue: 1 Vol. 38; ISSN 1540-7489

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (39)

Quantitative diagnostics of a methane/air mini-flame by Raman spectroscopy Fernández, J. M.; Punge, A.; Tejeda, G. Journal of Raman Spectroscopy, Vol. 37, Issue 1-3 https://doi.org/10.1002/jrs.1462	journal	January 2006
Single-beam coherent anti-Stokes Raman scattering (CARS) spectroscopy of gas-phase CO2 via phase and polarization shaping of a broadband continuum Roy, Sukesh; Wrzesinski, Paul J.; Pestov, Dmitry Journal of Raman Spectroscopy, Vol. 41, Issue 10 https://doi.org/10.1002/jrs.2587	journal	January 2010
Temperature and gas concentration measurements with vibrational ultra‐broadband two‐beam femtosecond/picosecond coherent anti‐Stokes Raman scattering and spontaneous Raman scattering Ran, Yang; Junghanns, Marcus; Boden, André Journal of Raman Spectroscopy, Vol. 50, Issue 9 https://doi.org/10.1002/jrs.5661	journal	October 2018
Impact of moderate pump–Stokes chirp on femtosecond coherent anti‐Stokes Raman scattering spectra Gu, Mingming; Satija, Aman; Lucht, Robert P. Journal of Raman Spectroscopy, Vol. 51, Issue 1 https://doi.org/10.1002/jrs.5754	journal	October 2019
Effects of O2–CO2 polarization beating on femtosecond coherent anti-Stokes Raman scattering (fs-CARS) spectroscopy of O2 Kulatilaka, W. D.; Gord, J. R.; Roy, S. Applied Physics B, Vol. 102, Issue 1 https://doi.org/10.1007/s00340-010-4188-2	journal	September 2010
Theoretical modeling of single-laser-shot, chirped-probe-pulse femtosecond coherent anti-Stokes Raman scattering thermometry Richardson, D. R.; Lucht, R. P.; Kulatilaka, W. D. Applied Physics B, Vol. 104, Issue 3 https://doi.org/10.1007/s00340-011-4489-0	journal	April 2011
Energy levels, intensities, and linewidths of atmospheric carbon dioxide bands Rothman, L. S.; Hawkins, R. L.; Wattson, R. B. Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 48, Issue 5-6 https://doi.org/10.1016/0022-4073(92)90119-O	journal	November 1992
Nitrogen and hydrogen CARS temperature measurements in a hydrogen/air flame using a near-adiabatic flat-flame burner Hancock, Robert D.; Bertagnolli, Kenneth E.; Lucht, Robert P. Combustion and Flame, Vol. 109, Issue 3 https://doi.org/10.1016/S0010-2180(96)00191-5	journal	May 1997
General anharmonic force constants of carbon dioxide Suzuki, Isao Journal of Molecular Spectroscopy, Vol. 25, Issue 4 https://doi.org/10.1016/S0022-2852(68)80018-9	journal	April 1968
Electric (hyper)polarizability derivatives for the symmetric stretching of carbon dioxide Maroulis, George Chemical Physics, Vol. 291, Issue 1 https://doi.org/10.1016/S0301-0104(03)00186-1	journal	June 2003
Temperature and CO2 concentration measurements in the exhaust stream of a liquid-fueled combustor using dual-pump coherent anti-Stokes Raman scattering (CARS) spectroscopy Roy, Sukesh; Meyer, Terrence R.; Lucht, Robert P. Combustion and Flame, Vol. 138, Issue 3 https://doi.org/10.1016/j.combustflame.2004.04.012	journal	August 2004
Dual-pump dual-broadband CARS for exhaust-gas temperature and CO2–O2–N2 mole-fraction measurements in model gas-turbine combustors Meyer, T. R.; Roy, S.; Lucht, R. P. Combustion and Flame, Vol. 142, Issue 1-2 https://doi.org/10.1016/j.combustflame.2005.02.007	journal	July 2005
Adiabatic burning velocity and cellular flame characteristics of H2–CO–CO2–air mixtures Ratna Kishore, V.; Ravi, M. R.; Ray, Anjan Combustion and Flame, Vol. 158, Issue 11 https://doi.org/10.1016/j.combustflame.2011.03.018	journal	November 2011
Dual-pump vibrational CARS measurements of temperature and species concentrations in turbulent premixed flames with CO2 addition Han, Dong; Satija, Aman; Kim, Jupyoung Combustion and Flame, Vol. 181 https://doi.org/10.1016/j.combustflame.2017.03.027	journal	July 2017
A study of the Raman spectrum of CO2 using an algebraic approach Sánchez-Castellanos, M.; Lemus, R.; Carvajal, M. Chemical Physics Letters, Vol. 554 https://doi.org/10.1016/j.cplett.2012.09.075	journal	December 2012
Recent advances in coherent anti-Stokes Raman scattering spectroscopy: Fundamental developments and applications in reacting flows Roy, Sukesh; Gord, James R.; Patnaik, Anil K. Progress in Energy and Combustion Science, Vol. 36, Issue 2 https://doi.org/10.1016/j.pecs.2009.11.001	journal	April 2010
Oxidation of H2/CO2 mixtures and effect of hydrogen initial concentration on the combustion of CH4 and CH4/CO2 mixtures: Experiments and modeling Le Cong, Tanh; Dagaut, Philippe Proceedings of the Combustion Institute, Vol. 32, Issue 1 https://doi.org/10.1016/j.proci.2008.05.079	journal	January 2009
Single-laser-shot femtosecond coherent anti-Stokes Raman scattering thermometry at 1000Hz in unsteady flames Richardson, Daniel R.; Lucht, Robert P.; Roy, Sukesh Proceedings of the Combustion Institute, Vol. 33, Issue 1 https://doi.org/10.1016/j.proci.2010.05.060	journal	January 2011
Chirped-probe-pulse femtosecond CARS thermometry in turbulent spray flames Lowe, A.; Thomas, L. M.; Satija, A. Proceedings of the Combustion Institute, Vol. 37, Issue 2 https://doi.org/10.1016/j.proci.2018.06.149	journal	January 2019
Direct Coherent Raman Temperature Imaging and Wideband Chemical Detection in a Hydrocarbon Flat Flame Bohlin, Alexis; Kliewer, Christopher J. The Journal of Physical Chemistry Letters, Vol. 6, Issue 4 https://doi.org/10.1021/acs.jpclett.5b00014	journal	February 2015
In-situ Measurement of Sodium and Potassium Release during Oxy-Fuel Combustion of Lignite using Laser-Induced Breakdown Spectroscopy: Effects of O ₂ and CO ₂ Concentration He, Yong; Zhu, Jiajian; Li, Bo Energy & Fuels, Vol. 27, Issue 2 https://doi.org/10.1021/ef301750h	journal	January 2013
Raman Scattering Cross Sections Penney, C. M.; Goldman, L. M.; Lapp, M. Nature Physical Science, Vol. 235, Issue 58 https://doi.org/10.1038/physci235110b0	journal	February 1972
On the Rotational Diffusion of Molecules Gordon, R. G. The Journal of Chemical Physics, Vol. 44, Issue 5 https://doi.org/10.1063/1.1726949	journal	March 1966
Femtosecond coherent anti-Stokes Raman scattering measurement of gas temperatures from frequency-spread dephasing of the Raman coherence Lucht, Robert P.; Roy, Sukesh; Meyer, Terrence R. Applied Physics Letters, Vol. 89, Issue 25 https://doi.org/10.1063/1.2410237	journal	December 2006
Study of collisional effects on band shapes of the ν ₁ /2ν ₂ Fermi dyad in CO ₂ gas with stimulated Raman spectroscopy. I. Rotational and vibrational relaxation in the 2ν ₂ band Lavorel, B.; Millot, G.; Saint‐Loup, R. The Journal of Chemical Physics, Vol. 93, Issue 4 https://doi.org/10.1063/1.459049	journal	August 1990
Overtone Raman spectrum and molecular polarizability surface of CO ₂ Tejeda, G.; Maté, B.; Montero, S. The Journal of Chemical Physics, Vol. 103, Issue 2 https://doi.org/10.1063/1.470091	journal	July 1995
Simulation of the Raman spectra of CO ₂ : Bridging the gap between algebraic models and experimental spectra Lemus, R.; Sánchez-Castellanos, M.; Pérez-Bernal, F. The Journal of Chemical Physics, Vol. 141, Issue 5 https://doi.org/10.1063/1.4889995	journal	August 2014
Two-beam femtosecond coherent anti-Stokes Raman scattering for thermometry on CO ₂ Kerstan, M.; Makos, I.; Nolte, S. Applied Physics Letters, Vol. 110, Issue 2 https://doi.org/10.1063/1.4974030	journal	January 2017
Quantitative CARS spectroscopy of CO_2 and N_2O Hall, Robert J.; Stufflebeam, John H. Applied Optics, Vol. 23, Issue 23 https://doi.org/10.1364/AO.23.004319	journal	January 1984
Simultaneous and time-resolved temperature and relative CO_2–N_2 and O_2–CO_2–N_2 concentration measurements with pure rotational coherent anti-Stokes Raman scattering for pressures as great as 5 MPa Schenk, Martin; Seeger, Thomas; Leipertz, Alfred Applied Optics, Vol. 44, Issue 26 https://doi.org/10.1364/AO.44.005582	journal	January 2005
Time-resolved CO_2 thermometry for pressures as great as 5 MPa by use of pure rotational coherent anti-Stokes Raman scattering Schenk, Martin; Seeger, Thomas; Leipertz, Alfred Applied Optics, Vol. 44, Issue 31 https://doi.org/10.1364/AO.44.006526	journal	January 2005
Comparison of chirped-probe-pulse and hybrid femtosecond/picosecond coherent anti-Stokes Raman scattering for combustion thermometry Richardson, Daniel R.; Stauffer, Hans U.; Roy, Sukesh Applied Optics, Vol. 56, Issue 11 https://doi.org/10.1364/AO.56.000E37	journal	January 2017
Technique developments and performance analysis of chirped-probe-pulse femtosecond coherent anti-Stokes Raman scattering combustion thermometry Thomas, Levi M.; Satija, Aman; Lucht, Robert P. Applied Optics, Vol. 56, Issue 31 https://doi.org/10.1364/AO.56.008797	journal	January 2017
Direct measurement of CO ₂ S-branch Raman linewidths broadened by O ₂ , Ar, and C ₂ H ₄ Jiang, Naibo; Roy, Sukesh; Hsu, Paul S. Applied Optics, Vol. 58, Issue 10 https://doi.org/10.1364/AO.58.000C55	journal	January 2019
Chirped-probe-pulse femtosecond coherent anti-Stokes Raman scattering concentration measurements Richardson, Daniel R.; Lucht, Robert P.; Kulatilaka, Waruna D. Journal of the Optical Society of America B, Vol. 30, Issue 1 https://doi.org/10.1364/JOSAB.30.000188	journal	December 2012
Effects of self-phase modulation (SPM) on femtosecond coherent anti-Stokes Raman scattering spectroscopy Gu, Mingming; Satija, Aman; Lucht, Robert P. Optics Express, Vol. 27, Issue 23 https://doi.org/10.1364/OE.27.033954	journal	January 2019
Suppression of Raman-resonant interferences in rotational coherent anti-Stokes Raman spectroscopy using time-delayed picosecond probe pulses Seeger, Thomas; Kiefer, Johannes; Gao, Yi Optics Letters, Vol. 35, Issue 12 https://doi.org/10.1364/OL.35.002040	journal	January 2010
Coherent anti-Stokes Raman spectroscopy in the presence of strong resonant signal from background molecules Bitter, M.; Milner, V. Optics Letters, Vol. 38, Issue 12 https://doi.org/10.1364/OL.38.002050	journal	January 2013
Interference-free hybrid fs/ps vibrational CARS thermometry in high-pressure flames Stauffer, Hans U.; Rahman, K. Arafat; Slipchenko, Mikhail N. Optics Letters, Vol. 43, Issue 20 https://doi.org/10.1364/OL.43.004911	journal	January 2018