Synchrotron infrared nano-spectroscopy and -imaging

Bechtel, Hans A.; Johnson, Samuel C.; Khatib, Omar; Muller, Eric A.; Raschke, Markus B.

doi:10.1016/j.surfrep.2020.100493

Synchrotron infrared nano-spectroscopy and -imaging

Journal Article · Fri Apr 24 00:00:00 EDT 2020 · Surface Science Reports

DOI:https://doi.org/10.1016/j.surfrep.2020.100493· OSTI ID:1775406

Bechtel, Hans A. ^[1]; Johnson, Samuel C. ^[2]; Khatib, Omar ^[3]; Muller, Eric A. ^[2]; Raschke, Markus B. ^[2]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Univ. of Colorado, Boulder, CO (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Univ. of Colorado, Boulder, CO (United States)

Infrared (IR) spectroscopy has evolved into a powerful analytical technique to probe molecular and lattice vibrations, low-energy electronic excitations and correlations, and related collective surface plasmon, phonon, or other polaritonic resonances. In combination with scanning probe microscopy, near-field infrared nano-spectroscopy and -imaging techniques have recently emerged as a frontier in imaging science, enabling the study of complex heterogeneous materials with simultaneous nanoscale spatial resolution and chemical and quantum state spectroscopic specificity. Here, we describe synchrotron infrared nano-spectroscopy (SINS), which takes advantage of the low-noise, broadband, high spectral irradiance, and coherence of synchrotron infrared radiation for near-field infrared measurements across the mid- to far-infrared with nanometer spatial resolution. This powerful combination provides a qualitatively new form of broadband spatio-spectral analysis of nanoscale, mesoscale, and surface phenomena that were previously difficult to study with IR techniques, or even any form of micro-spectroscopy in general. We review the development of SINS, describe its technical implementations, and highlight selected examples representative of the rapidly growing range of applications in physics, chemistry, biology, materials science, geology, and atmospheric and space sciences.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1775406

Alternate ID(s):: OSTI ID: 1643218

Journal Information:: Surface Science Reports, Journal Name: Surface Science Reports Journal Issue: 3 Vol. 75; ISSN 0167-5729

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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